A paradox: The thermal rate coefficient for the H+DCl → HCl+D exchange reaction
International Nuclear Information System (INIS)
Thompson, D.L.; Suzukawa, H.H. Jr.; Raff, L.M.
1975-01-01
Previously reported photolysis experiments indicate that the frequency factors associated with the hydrogen-exchange reactions H+DCl → HCl+D and D+HCl → DCl+H are on the order of 10 10 cm 3 /molcenter-dotsec. A series of unadjusted, quasiclassical trajectory calculations were been carried out to compute the thermal rate coefficients and activation parameters for a series of 13 thermal processes of the type A+BC → AB+C, where A=H, D, or Cl and BC=H 2 , D 2 , HCl, DCl, or Cl 2 . In addition, hot-atom yield ratios have been computed from the IRP equation for the reactions D*+DCl → D 2 +Cl, D*+Cl 2 → DCl + Cl as a function of the initial D* laboratory energy. The computations yield (1) hot-atom DCl/D 2 yield ratios within a factor of 2 of the experimental values; (2) thermal activation energies in satisfactory agreement with experiment for all processes investigated; and (3) frequency factors in reasonable accord with experiment for all the reactions except the hydrogen exchange reactions
Bisetti, Fabrizio
2014-01-02
The effects of an electric field on the collision rates, energy exchanges and transport properties of electrons in premixed flames are investigated via solutions to the Boltzmann kinetic equation. The case of high electric field strength, which results in high-energy, non-thermal electrons, is analysed in detail at sub-breakdown conditions. The rates of inelastic collisions and the energy exchange between electrons and neutrals in the reaction zone of the flame are characterised quantitatively. The analysis includes attachment, ionisation, impact dissociation, and vibrational and electronic excitation processes. Our results suggest that Townsend breakdown occurs for E/N = 140 Td. Vibrational excitation is the dominant process up to breakdown, despite important rates of electronic excitation of CO, CO2 and N2 as well as impact dissociation of O2 being apparent from 50 Td onwards. Ohmic heating in the reaction zone is found to be negligible (less than 2% of peak heat release rate) up to breakdown field strengths for realistic electron densities equal to 1010 cm-3. The observed trends are largely independent of equivalence ratio. In the non-thermal regime, electron transport coefficients are insensitive to mixture composition and approximately constant across the flame, but are highly dependent on the electric field strength. In the thermal limit, kinetic parameters and transport coefficients vary substantially across the flame due to the spatially inhomogeneous concentration of water vapour. A practical approach for identifying the plasma regime (thermal versus non-thermal) in studies of electric field effects on flames is proposed. © 2014 Taylor & Francis.
The HD+ dissociative recombination rate coefficient at low temperature
Directory of Open Access Journals (Sweden)
Wolf A.
2015-01-01
Full Text Available The effect of the rotational temperature of the ions is considered for low-energy dissociative recombination (DR of HD+. Merged beams measurements with HD+ ions of a rotational temperature near 300 K are compared to multichannel quantum defect theory calculations. The thermal DR rate coefficient for a Maxwellian electron velocity distribution is derived from the merged-beams data and compared to theoretical results for a range of rotational temperatures. Good agreement is found for the theory with 300 K rotational temperature. For a low-temperature plasma environment where also the rotational temperature assumes 10 K, theory predicts a considerably higher thermal DR rate coefficient. The origin of this is traced to predicted resonant structures of the collision-energy dependent DR cross section at few-meV collision energies for the particular case of HD+ ions in the rotational ground state.
Accurate Determination of Tunneling-Affected Rate Coefficients: Theory Assessing Experiment.
Zuo, Junxiang; Xie, Changjian; Guo, Hua; Xie, Daiqian
2017-07-20
The thermal rate coefficients of a prototypical bimolecular reaction are determined on an accurate ab initio potential energy surface (PES) using ring polymer molecular dynamics (RPMD). It is shown that quantum effects such as tunneling and zero-point energy (ZPE) are of critical importance for the HCl + OH reaction at low temperatures, while the heavier deuterium substitution renders tunneling less facile in the DCl + OH reaction. The calculated RPMD rate coefficients are in excellent agreement with experimental data for the HCl + OH reaction in the entire temperature range of 200-1000 K, confirming the accuracy of the PES. On the other hand, the RPMD rate coefficients for the DCl + OH reaction agree with some, but not all, experimental values. The self-consistency of the theoretical results thus allows a quality assessment of the experimental data.
Structural relaxation and thermal conductivity coefficient of liquids
International Nuclear Information System (INIS)
Abdurasulov, A.
1992-01-01
Present article is devoted to structural relaxation and thermal conductivity coefficient of liquids. The thermoelastic properties of liquids were studied taking into account the contribution of translational and structural relaxation. The results of determination of dynamic coefficient of thermal conductivity of liquids taking into account the contribution of translational and structural relaxation are presented.
International Nuclear Information System (INIS)
Lee, Youho; Lee, Jeong Ik; Cheon, Hee
2015-01-01
Accurate modeling of thermal shock induced stresses has become ever most important to emerging accident-tolerant ceramic cladding concepts, such as silicon carbide (SiC) and SiC coated zircaloy. Since fractures of ceramic (entirely ceramic or coated) occur by excessive tensile stresses with linear elasticity, modeling transient stress distribution in the material provides a direct indication of the structural integrity. Indeed, even for the current zircaloy cladding material, the oxide layer formed on the surface - where cracks starts to develop upon water quenching - essentially behaves as a brittle ceramic. Hence, enhanced understanding of thermal shock fracture of a brittle material would fundamentally contribute to safety of nuclear reactors for both the current fuel design and that of the coming future. Understanding thermal shock fracture of a brittle material requires heat transfer rate between the solid and the fluid for transient temperature fields of the solid, and structural response of the solid under the obtained transient temperature fields. In water quenching, a solid experiences dynamic time-varying heat transfer rates with phase changes of the fluid over a short quenching period. Yet, such a dynamic change of heat transfer rates during the water quenching transience has been overlooked in assessments of mechanisms, predictability, and uncertainties for thermal shock fracture. Rather, a time-constant heat transfer coefficient, named 'effective heat transfer coefficient' has become a conventional input to thermal shock fracture analysis. No single constant heat transfer could suffice to depict the actual stress evolution subject to dynamic heat transfer coefficient changes with fluid phase changes. Use of the surface temperature dependent heat transfer coefficient will remarkably increase predictability of thermal shock fracture of brittle materials and complete the picture of stress evolution in the quenched solid. The presented result
Seal assembly for materials with different coefficients of thermal expansion
Minford, Eric [Laurys Station, PA
2009-09-01
Seal assembly comprising (a) two or more seal elements, each element having having a coefficient of thermal expansion; and (b) a clamping element having a first segment, a second segment, and a connecting segment between and attached to the first and second segments, wherein the two or more seal elements are disposed between the first and second segments of the clamping element. The connecting segment has a central portion extending between the first segment of the clamping element and the second segment of the clamping element, and the connecting segment is made of a material having a coefficient of thermal expansion. The coefficient of thermal expansion of the material of the connecting segment is intermediate the largest and smallest of the coefficients of thermal expansion of the materials of the two or more seal elements.
System to Measure Thermal Conductivity and Seebeck Coefficient for Thermoelectrics
Kim, Hyun-Jung; Skuza, Jonathan R.; Park, Yeonjoon; King, Glen C.; Choi, Sang H.; Nagavalli, Anita
2012-01-01
The Seebeck coefficient, when combined with thermal and electrical conductivity, is an essential property measurement for evaluating the potential performance of novel thermoelectric materials. However, there is some question as to which measurement technique(s) provides the most accurate determination of the Seebeck coefficient at elevated temperatures. This has led to the implementation of nonstandardized practices that have further complicated the confirmation of reported high ZT materials. The major objective of the procedure described is for the simultaneous measurement of the Seebeck coefficient and thermal diffusivity within a given temperature range. These thermoelectric measurements must be precise, accurate, and reproducible to ensure meaningful interlaboratory comparison of data. The custom-built thermal characterization system described in this NASA-TM is specifically designed to measure the inplane thermal diffusivity, and the Seebeck coefficient for materials in the ranging from 73 K through 373 K.
Nakanishi, Koichi; Kogure, Akinori; Fujii, Takenao; Kokawa, Ryohei; Deuchi, Keiji; Kuwana, Ritsuko; Takamatsu, Hiromu
2013-10-09
If a fixed stress is applied to the three-dimensional z-axis of a solid material, followed by heating, the amount of thermal expansion increases according to a fixed coefficient of thermal expansion. When expansion is plotted against temperature, the transition temperature at which the physical properties of the material change is at the apex of the curve. The composition of a microbial cell depends on the species and condition of the cell; consequently, the rate of thermal expansion and the transition temperature also depend on the species and condition of the cell. We have developed a method for measuring the coefficient of thermal expansion and the transition temperature of cells using a nano thermal analysis system in order to study the physical nature of the cells. The tendency was seen that among vegetative cells, the Gram-negative Escherichia coli and Pseudomonas aeruginosa have higher coefficients of linear expansion and lower transition temperatures than the Gram-positive Staphylococcus aureus and Bacillus subtilis. On the other hand, spores, which have low water content, overall showed lower coefficients of linear expansion and higher transition temperatures than vegetative cells. Comparing these trends to non-microbial materials, vegetative cells showed phenomenon similar to plastics and spores showed behaviour similar to metals with regards to the coefficient of liner thermal expansion. We show that vegetative cells occur phenomenon of similar to plastics and spores to metals with regard to the coefficient of liner thermal expansion. Cells may be characterized by the coefficient of linear expansion as a physical index; the coefficient of linear expansion may also characterize cells structurally since it relates to volumetric changes, surface area changes, the degree of expansion of water contained within the cell, and the intensity of the internal stress on the cellular membrane. The coefficient of linear expansion holds promise as a new index for
Energy Technology Data Exchange (ETDEWEB)
Lee, Youho; Lee, Jeong Ik; Cheon, Hee [KAIST, Daejeon (Korea, Republic of)
2015-05-15
Accurate modeling of thermal shock induced stresses has become ever most important to emerging accident-tolerant ceramic cladding concepts, such as silicon carbide (SiC) and SiC coated zircaloy. Since fractures of ceramic (entirely ceramic or coated) occur by excessive tensile stresses with linear elasticity, modeling transient stress distribution in the material provides a direct indication of the structural integrity. Indeed, even for the current zircaloy cladding material, the oxide layer formed on the surface - where cracks starts to develop upon water quenching - essentially behaves as a brittle ceramic. Hence, enhanced understanding of thermal shock fracture of a brittle material would fundamentally contribute to safety of nuclear reactors for both the current fuel design and that of the coming future. Understanding thermal shock fracture of a brittle material requires heat transfer rate between the solid and the fluid for transient temperature fields of the solid, and structural response of the solid under the obtained transient temperature fields. In water quenching, a solid experiences dynamic time-varying heat transfer rates with phase changes of the fluid over a short quenching period. Yet, such a dynamic change of heat transfer rates during the water quenching transience has been overlooked in assessments of mechanisms, predictability, and uncertainties for thermal shock fracture. Rather, a time-constant heat transfer coefficient, named 'effective heat transfer coefficient' has become a conventional input to thermal shock fracture analysis. No single constant heat transfer could suffice to depict the actual stress evolution subject to dynamic heat transfer coefficient changes with fluid phase changes. Use of the surface temperature dependent heat transfer coefficient will remarkably increase predictability of thermal shock fracture of brittle materials and complete the picture of stress evolution in the quenched solid. The presented result
International Nuclear Information System (INIS)
Janev, R.K.; Kato, T.; Wang, J.G.
2001-05-01
The available experimental and theoretical cross section data on charge exchange processes in collisions of protons with hydrocarbon molecules have been collected and critically assessed. Using well established scaling relationships for the charge exchange cross sections at low and high collision energies, as well as the known rate coefficients for these reactions in the thermal energy region, a complete cross section database is constructed for proton-C x H y charge exchange reactions from thermal energies up to several hundreds keV for all C x H y molecules with x=1, 2, 3 and 1 ≤ y ≤ 2x + 2. Rate coefficients for these charge exchange reactions have also been calculated in the temperature range from 0.1 eV to 20 keV. (author)
Energy Technology Data Exchange (ETDEWEB)
Lagana, Antonio; Faginas Lago, Noelia; Rampino, Sergio [Dipartimento di Chimica, Universita di Perugia, 06123 Perugia (Italy); Huarte-Larranaga, FermIn [Computer Simulation and Modeling Lab (CoSMoLab), Parc CientIfic de Barcelona, 08028 Barcelona (Spain); GarcIa, Ernesto [Departamento de Quimica Fisica, Universidad del PaIs Vasco, 01006 Vitoria (Spain)], E-mail: lagana05@gmail.com, E-mail: fhuarte@pcb.ub.es, E-mail: e.garcia@ehu.es
2008-10-15
Zero total angular momentum exact quantum calculations of the probabilities of the N+N{sub 2} reaction have been performed on the L3 potential energy surface having a bent transition state. This has allowed us to work out J-shifting estimates of the thermal rate coefficient based on the calculation of either detailed (state-to-state) or cumulative (multiconfiguration) probabilities. The results obtained are used to compare the numerical outcomes and the concurrent computational machineries of both quantum and semiclassical approaches as well as to exploit the potentialities of the J-shifting model. The implications of moving the barrier to reaction from the previously proposed collinear geometry of the LEPS to the bent one of L3 are also investigated by comparing the related detailed reactive probabilities.
Li, Jun; Guo, Hua
2018-03-15
Thermal rate coefficients for the title reaction and its various isotopologues are computed using a tunneling-corrected transition-state theory on a global potential energy surface recently developed by fitting a large number of high-level ab initio points. The calculated rate coefficients are found to agree well with the measured ones in a wide temperature range, validating the accuracy of the potential energy surface. Strong non-Arrhenius effects are found at low temperatures. In addition, the calculations reproduced the primary and secondary kinetic isotope effects. These results confirm the strong influence of tunneling to this heavy-light-heavy hydrogen abstraction reaction.
Linear thermal expansion coefficient of MgAl2O4(s)
International Nuclear Information System (INIS)
Dash, A.; Samui, P.; Naik, Y.P.; Chaudhary, Z.S.
2011-01-01
The coefficient of linear thermal expansion (α av ) of MgAl 2 O 4 (s) has been determined using a Netzsch 402 PC dilatometer with Al 2 O 3 (s) as the push-rod. The change in length per unit length was recorded as a function of temperature between room temperature to 1273 K at a heating rate of 8 K.min /1 , in argon flowing atmosphere. The average of three measurements was quoted as the α av for MgAl 2 O 4 (s). The linear thermal expansion was measured to an accuracy of ±3%. (author)
Prediction and control of the coefficient of thermal expansion of concrete
International Nuclear Information System (INIS)
Ziegeldorf, S.; Kleiser, K.; Hilsdorf, H.K.
1979-01-01
Prediction and control of the coefficient of thermal expansion of concrete. In this report various procedures for the prediction of the coefficient of thermal expansion of concrete are summarized. The values predicted with these procedures are compared to experimental data. In the experimental investigation the coefficient of thermal expansion of various types of aggregates and types of concrete both in a dry and a moist state in the temperature range RT/180 0 C have been measured. The most significant result obtained is that for equal volume fractions the thermal properties of coarse aggregates have a more pronounced effect upon thermal expansion of concrete than those of fine aggregates. In the analysis an attempt has been made to estimate the thermal expansion of concrete from the properties of the concrete components by means of a finite element procedure. On the basis of the experimental data and of the analysis of internal temperature stresses in the concrete a simple relationship for the determination of the coefficient of thermal expansion of concrete has been deduced. In this relationship different thermal properties of coarse and fine aggregates may be taken into account. Compared to other methods this relationship yields, both for dry and for moist concrete, values which are in good agreement with the experimental data. (orig.) [de
Energy Technology Data Exchange (ETDEWEB)
Janev, R.K.; Kato, T. [National Inst. for Fusion Science, Toki, Gifu (Japan); Wang, J.G. [Department of Physics and Astronomy, University of Georgia, Athens (United States)
2001-05-01
The available experimental and theoretical cross section data on charge exchange processes in collisions of protons with hydrocarbon molecules have been collected and critically assessed. Using well established scaling relationships for the charge exchange cross sections at low and high collision energies, as well as the known rate coefficients for these reactions in the thermal energy region, a complete cross section database is constructed for proton-C{sub x}H{sub y} charge exchange reactions from thermal energies up to several hundreds keV for all C{sub x}H{sub y} molecules with x=1, 2, 3 and 1 {<=} y {<=} 2x + 2. Rate coefficients for these charge exchange reactions have also been calculated in the temperature range from 0.1 eV to 20 keV. (author)
Laboratory measurements of the coefficient of thermal expansion of Olkiluoto drill core samples
International Nuclear Information System (INIS)
Aakesson, U.
2012-04-01
The coefficient of thermal expansion and the wet density has been determined on 22 specimens from the ONKALO drillholes ONK-PP167, ONK-PP199, ONK-PP224, ONK-PP225 and ONK-PP226, Olkiluoto, Finland. The coefficient of thermal expansion has been determined in the temperature interval 20-60 deg C. The results indicated that the thermal expansion was almost linear, and the coefficient of thermal expansion for the investigated specimens range between 3.2 and 14.4 x 10 -6 mm/mm deg C, and the wet density between 2,610 and 2,820 kg/m 3 . The granite pegmatite has slightly lower coefficient of thermal expansion and wet density than gneissic rocks. (orig.)
Thermal expansion coefficient determination of polylactic acid using digital image correlation
Directory of Open Access Journals (Sweden)
Botean Adrian - Ioan
2018-01-01
Full Text Available This paper aims determining the linear thermal expansion coefficient (CTE of polylactic acid (PLA using an optical method for measuring deformations called digital image correlation method (DIC. Because PLA is often used in making many pieces with 3D printing technology, it is opportune to know this coefficient to obtain a higher degree of precision in the construction of parts and to monitor deformations when these parts are subjected to a thermal gradient. Are used two PLA discs with 20 and 40% degree of filling. In parallel with this approach was determined the linear thermal expansion coefficient (CTE for the copper cylinder on the surface of which are placed the two discs of PLA.
Thermal expansion coefficient determination of polylactic acid using digital image correlation
Botean, Adrian-Ioan
2018-02-01
This paper aims determining the linear thermal expansion coefficient (CTE) of polylactic acid (PLA) using an optical method for measuring deformations called digital image correlation method (DIC). Because PLA is often used in making many pieces with 3D printing technology, it is opportune to know this coefficient to obtain a higher degree of precision in the construction of parts and to monitor deformations when these parts are subjected to a thermal gradient. Are used two PLA discs with 20 and 40% degree of filling. In parallel with this approach was determined the linear thermal expansion coefficient (CTE) for the copper cylinder on the surface of which are placed the two discs of PLA.
Schwenke, David W.; Jaffe, Richard L.; Chaban, Galina M.
2016-01-01
We have generated accurate global potential energy surfaces for CO+Ar and CO+O that correlate with atom-diatom pairs in their ground electronic states based on extensive ab initio electronic structure calculations and used these potentials in quasi-classical trajectory nuclear dynamics calculations to predict the thermal dissociation rate coefficients over 5000- 35000 K. Our results are not compatible with the 20-45 year old experimental results. For CO + Ar we obtain fairly good agreement with the experimental rate coefficients of Appleton et al. (1970) and Mick and Roth (1993), but our computed rate coefficients exhibit a stronger temperature dependence. For CO + O our dissociation rate coefficient is in close agreement with the value from the Park model, which is an empirical adjustment of older experimental results. However, we find the rate coefficient for CO + O is only 1.5 to 3.3 times larger than CO + Ar over the temperature range of the shock tube experiments (8000-15,000 K). The previously accepted value for this rate coefficient ratio is 15, independent of temperature. We also computed the rate coefficient for the CO + O ex- change reaction which forms C + O2. We find this reaction is much faster than previously believed and is the dominant process in the removal of CO at temperatures up to 16,000 K. As a result, the dissociation of CO is accomplished in two steps (react to form C+O2 and then O2 dissociates) that are endothermic by 6.1 and 5.1 eV, instead of one step that requires 11.2 eV to break the CO bond.
International Nuclear Information System (INIS)
Kato, H.; Chen, H.-S.; Inoue, A.
2008-01-01
The thermal expansion coefficients of 13 metallic glasses were measured using a thermo-mechanical analyser. A unique correlation was found between the linear thermal expansion coefficient and the glass transition temperature-their product is nearly constant ∼8.24 x 10 -3 . If one assumes the Debye expression for thermal activation, the total linear thermal expansion up to glass transition temperature (T g ) is reduced to 6 x 10 -3 , nearly 25% of that at the fusion of pure metals
International Nuclear Information System (INIS)
Deev, V.I.; Sobolev, V.P.; Kruglov, A.B.; Pridantsev, A.I.
1984-01-01
Results of experimental investigation of heat conduction coefficient and coefficient of linear thermal expansion and thermal shrinkages of the STEF-1 textolite-glass widely used in superconducting magnetic systems as electric insulating and structural material are presented. Samples of two types have been died: sample axisa is perpendicular to a plae of fiberglass layers ad sample axis is parallel to a plane of fiberglass layers. Heat conduction coefficient was decreased almost a five times with temperature decrease from 300 up to 5K and was slightly dependent on a sample type. Temperature variation of linear dimensions in a sample of the first type occurs in twice as fast as compared to the sample of the second type
Corsetti, James A; Green, William E; Ellis, Jonathan D; Schmidt, Greg R; Moore, Duncan T
2016-10-10
Characterizing the thermal properties of optical materials is necessary for understanding how to design an optical system for changing environmental conditions. A method is presented for simultaneously measuring both the linear coefficient of thermal expansion and the temperature-dependent refractive index coefficient of a sample interferometrically in air. Both the design and fabrication of the interferometer is presented as well as a discussion of the results of measuring both a steel and a CaF2 sample.
Tian, Xiao-mei; Zeng, Li; Wei, Bin; Huang, Yi-feng
2015-12-01
To investigate the thermal expansion coefficient of different processing parameters upon the Co-Cr alloy prepared by selective laser melting (SLM) technique, in order to provide technical support for clinical application of SLM technology. The heating curve of self-made Co-Cr alloy was protracted from room temperature to 980°C centigrade with DIL402PC thermal analysis instrument, keeping temperature rise rate and cooling rate at 5 K/min, and then the thermal expansion coefficient of 9 groups of Co-Cr alloy was measured from 20°C centigrade to 500°C centigrade and 600°C centigrade. The 9 groups thermal expansion coefficient values of Co-Cr alloy heated from 20°C centigrade to 500°C centigrade were 13.9×10(-6)/K,13.6×10(-6)/K,13.9×10(-6)/K,13.7×10(-6)/K,13.5×10(-6)/K,13.8×10(-6)/K,13.7×10(-6)/K,13.7×10(-6)/K,and 13.9×10(-6)/K, respectively; when heated from 20°C centigrade to 600°C centigrade, they were 14.2×10(-6)/K,13.9×10(-6)/K,13.8×10(-6)/K,14.0×10(-6)/K,14.1×10(-6)/K,14.1×10(-6)/K,13.9×10(-6)/K,14.2×10(-6)/K, and 13.7×10(-6)/K, respectively. The results showed that the Co-Cr alloy has good matching with the VITA VMK 95 porcelain powder and can meet the requirement of clinic use.
Thermally induced lensing determination from the coefficient of defocus aberration
CSIR Research Space (South Africa)
Bell, Teboho
2014-07-01
Full Text Available The effects of a temperature gradient in a laser crystal in an end-pumped configuration in a solid-state laser resonator results in thermally induced aberrations. Of particular interest we measure the thermally induced lens from the coefficient...
Thermal Coefficient of Redox Potential of Alkali Metals
Fukuzumi, Yuya; Hinuma, Yoyo; Moritomo, Yutaka
2018-05-01
The thermal coefficient (α) of redox potential (V) is a significant physical quantity that converts the thermal energy into electric energy. In this short note, we carefully determined α of alkali metals (A = Li and Na) against electrolyte solution. The obtained α is much larger than that expected from the specific heat (CpA) of solid A and depends on electrolyte solution. These observations indicate that the solvent has significant effect on α.
Rate coefficient for the reaction N + NO
Fox, J. L.
1994-01-01
Evidence has been advanced that the rate coefficient for the reaction N + NO right arrow N2 + O has a small positive temperature dependence at the high temperatures (900 to 1500 K) that prevail in the terrestrial middle and upper thermosphere by Siskind and Rusch (1992), and at the low temperatures (100 to 200 K) of the Martian lower thermosphere by Fox (1993). Assuming that the rate coefficient recommended by the Jet Propulsion Laboratory evaluation (DeMore et al., 1992) is accurate at 300 K, we derive here the low temperature value of the activation energy for this reaction and thus the rate coefficient that best fits the Viking 1 measured NO densities. We find that the fit is acceptable for a rate coefficient of about 1.3 x 10(exp -10)(T/300)(exp 0.5)exp(-400/T) and better for a value of about 2.5 x 10(exp -10)(T/300)(exp 0.5)exp(-600/T)cu cm/s.
Nuclear data for the calculation of thermal reactor reactivity coefficients
International Nuclear Information System (INIS)
1989-01-01
On its 15th meeting in Vienna, 16-20 June 1986, the International Nuclear Data Committee (INDC) considered it important to review the accuracy with which changes in thermal reactor reactivity resulting from changes in temperature and coolant density can be predicted. It was noted that reactor physicists in several countries had to adjust the thermal neutron cross-section data base in order to reproduce measured reactivity coefficients. Consequently, it appeared to be essential to examine the consistency of the integral and differential cross-section data and to make all the information available which has a bearing on reactivity coefficient prediction. Following the recommendation of the INDC, the Nuclear Data Section of the International Atomic Energy Agency, therefore, convened the Advisory Group Meeting on Nuclear Data for the Calculation of Thermal Reaction Reactivity Coefficients, in Vienna, Austria, 7-10 Dec. 1987. The Conclusions and Recommendations of the meeting together with the papers presented, are submitted in the present document. A separate abstract was prepared for each of these 12 papers. Refs, figs and tabs
Directory of Open Access Journals (Sweden)
B. Stojanovic
2009-06-01
Full Text Available The paper presents experimental research of thermal conductivity coefficients of the siliceous sand bed fluidized by air and an experimental investigation of the particle size influence on the heat transfer coefficient between fluidized bed and inclined exchange surfaces. The measurements were performed for the specific fluidization velocity and sand particle diameters d p=0.3, 0.5, 0.9 mm. The industrial use of fluidized beds has been increasing rapidly in the past 20 years owing to their useful characteristics. One of the outstanding characteristics of a fluidized bed is that it tends to maintain a uniform temperature even with nonuniform heat release. On the basis of experimental research, the influence of the process's operational parameters on the obtained values of the bed's thermal conductivity has been analyzed. The results show direct dependence of thermal conductivity on the intensity of mixing, the degree of fluidization, and the size of particles. In the axial direction, the coefficients that have been treated have values a whole order higher than in the radial direction. Comparison of experimental research results with experimental results of other authors shows good agreement and the same tendency of thermal conductivity change. It is well known in the literature that the value of the heat transfer coefficient is the highest in the horizontal and the smallest in the vertical position of the heat exchange surface. Variation of heat transfer, depending on inclination angle is not examined in detail. The difference between the values of the relative heat transfer coefficient between vertical and horizontal heater position for all particle sizes reduces by approximately 15% with the increase of fluidization rate.
Ceramic materials with low thermal conductivity and low coefficients of thermal expansion
Brown, Jesse; Hirschfeld, Deidre; Liu, Dean-Mo; Yang, Yaping; Li, Tingkai; Swanson, Robert E.; Van Aken, Steven; Kim, Jin-Min
1992-01-01
Compositions having the general formula (Ca.sub.x Mg.sub.1-x)Zr.sub.4 (PO.sub.4).sub.6 where x is between 0.5 and 0.99 are produced by solid state and sol-gel processes. In a preferred embodiment, when x is between 0.5 and 0.8, the MgCZP materials have near-zero coefficients of thermal expansion. The MgCZPs of the present invention also show unusually low thermal conductivities, and are stable at high temperatures. Macrostructures formed from MgCZP are useful in a wide variety of high-temperature applications. In a preferred process, calcium, magnesium, and zirconium nitrate solutions have their pH adjusted to between 7 and 9 either before or after the addition of ammonium dihydrogen phosphate. After dehydration to a gel, and calcination at temperatures in excess of 850.degree. C. for approximately 16 hours, single phase crystalline MgCZP powders with particle sizes ranging from approximately 20 nm to 50 nm result. The MgCZP powders are then sintered at temperatures ranging from 1200.degree. C. to 1350.degree. C. to form solid macrostructures with near-zero bulk coefficients of thermal expansion and low thermal conductivities. Porous macrostructures of the MgCZP powders of the present invention are also formed by combination with a polymeric powder and a binding agent, and sintering at high temperatures. The porosity of the resulting macrostructures can be adjusted by varying the particle size of the polymeric powder used.
Effect of graphene nanoplatelets on coefficient of thermal expansion of polyetherimide composite
International Nuclear Information System (INIS)
Wu, Huang; Drzal, Lawrence T.
2014-01-01
Thermal expansion is one of the major concerns for polymer composites. In this research, graphene nanoplatelets (GNPs) were added to polyetherimide (PEId) thermoplastic polymer in order to reduce the coefficient of thermal expansion (CTE) of the injection molded composite. First, the coefficient of linear thermal expansion (LTE) was measured in three directions in the anisotropic coupon: 0°, 90° and the out of plane Z direction. It is found that the GNP particles are very effective in terms of reducing the LTE in 0° direction due to high degree of alignment. After annealing above glass transition temperature, significant increase of 0° LTE and decrease of Z° LTE were observed. The bulk CTE was calculated by adding up the LTEs in all three directions and is found to be independent of annealing. Second, several models were applied to predict both CTE and LTE. It is found that Schapery's lower limit model fits the experimental CTE very well. Chow's model was applied for LTEs in three directions. The behavior of GNP-5/PEId composites is explained by the combination of Chow's model and morphology obtained by scanning electron microscope (SEM). - Highlights: • Coefficient of thermal expansion (CTE) of polymer composite is characterized. • Reduction of linear thermal expansion depends on filler orientation. • Filler orientation is characterized based on the location of the specimen. • Filler orientation is changed by annealing, causing subsequent change in CTE. • CTE and linear thermal expansion coefficient are modeled
Thermal conductivity coefficients of water and heavy water in the liquid state up to 3700C
International Nuclear Information System (INIS)
Le Neindre, B.; Bury, P.; Tufeu, R.; Vodar, B.
1976-01-01
The thermal conductivity coefficients of water and heavy water of 99.75 percent isotopic purity were measured using a coaxial cylinder apparatus, covering room temperature to their critical temperatures, and pressures from 1 to 500 bar for water, and from 1 to 1000 bar for heavy water. Following the behavior of the thermal conductivity coefficient of water, which shows a maximum close to 135 0 C, the thermal conductivity coefficient of heavy water exhibits a maximum near 95 0 C and near saturation pressures. This maximum is displaced to higher temperatures when the pressure is increased. Under the same temperature and pressure conditions the thermal conductivity coefficient of heavy water was lower than for water. The pressure effect was similar for water and heavy water. In the temperature range of our experiments, isotherms of thermal conductivity coefficients were almost linear functions of density
Thermal expansion coefficient measurement from electron diffraction of amorphous films in a TEM.
Hayashida, Misa; Cui, Kai; Malac, Marek; Egerton, Ray
2018-05-01
We measured the linear thermal expansion coefficients of amorphous 5-30 nm thick SiN and 17 nm thick Formvar/Carbon (F/C) films using electron diffraction in a transmission electron microscope. Positive thermal expansion coefficient (TEC) was observed in SiN but negative coefficients in the F/C films. In case of amorphous carbon (aC) films, we could not measure TEC because the diffraction radii required several hours to stabilize at a fixed temperature. Crown Copyright © 2018. Published by Elsevier B.V. All rights reserved.
FORTRAN program for calculating liquid-phase and gas-phase thermal diffusion column coefficients
International Nuclear Information System (INIS)
Rutherford, W.M.
1980-01-01
A computer program (COLCO) was developed for calculating thermal diffusion column coefficients from theory. The program, which is written in FORTRAN IV, can be used for both liquid-phase and gas-phase thermal diffusion columns. Column coefficients for the gas phase can be based on gas properties calculated from kinetic theory using tables of omega integrals or on tables of compiled physical properties as functions of temperature. Column coefficients for the liquid phase can be based on compiled physical property tables. Program listings, test data, sample output, and users manual are supplied for appendices
Thermal expansion coefficient determination by CBED
International Nuclear Information System (INIS)
Angelini, P.; Bentley, J.
1984-01-01
The present application of CBED involves measurements of thermal-expansion coefficients by measurement of changes in HOLZ line positions as a function of temperature. Previous work on this subject was performed on Si at a constant accelerating voltage of 100 kV between about 90 and 600 K. Diffraction patterns were recorded and line shifts correlated to lattice parameter changes. Differences were noted between values determined by CBED and accepted thermal expansion values. Significant HOLZ line interactions and splitting occurring in the (111) patterns were noted to contribute to the differences. Preliminary measurements have been made on Al, Al 2 O 3 , and single-crystal tau (Ni/sub 20.3/Ti/sub 2.7/B 6 ). An example of changes in HOLZ lines present in (114) patterns for Al are shown and the effect of temperature on the position of lines in the pattern illustrated
Thermal lensing measurement from the coefficient of defocus aberration
CSIR Research Space (South Africa)
Bell, Teboho
2016-03-01
Full Text Available We measured the thermally induced lens from the coefficient of defocus aberration using a Shack-Hartmann wavefront sensor (SHWFS). As a calibration technique, we infer the focal length of standard lenses probed by a collimated Gaussian beam...
International Nuclear Information System (INIS)
Volkov, A.G.; Kortov, S.V.; Povzner, A.A.
1996-01-01
The low temperature measurements of thermal coefficient of linear expansion of strong paramagnet FeSi are carried out. The results obtained are discussed with in the framework of spin-fluctuation theory. It is shown that electronic part of the thermal coefficient of linear expansion is negative in the range of temperatures lower that of the semiconductor-metal phase transition. In metal phase it becomes positive. This specific features of the thermal coefficient is explained by the spin-fluctuation renormalization of d-electronic states density
Mapping Thermal Expansion Coefficients in Freestanding 2D Materials at the Nanometer Scale
Hu, Xuan; Yasaei, Poya; Jokisaari, Jacob; Öǧüt, Serdar; Salehi-Khojin, Amin; Klie, Robert F.
2018-02-01
Two-dimensional materials, including graphene, transition metal dichalcogenides and their heterostructures, exhibit great potential for a variety of applications, such as transistors, spintronics, and photovoltaics. While the miniaturization offers remarkable improvements in electrical performance, heat dissipation and thermal mismatch can be a problem in designing electronic devices based on two-dimensional materials. Quantifying the thermal expansion coefficient of 2D materials requires temperature measurements at nanometer scale. Here, we introduce a novel nanometer-scale thermometry approach to measure temperature and quantify the thermal expansion coefficients in 2D materials based on scanning transmission electron microscopy combined with electron energy-loss spectroscopy to determine the energy shift of the plasmon resonance peak of 2D materials as a function of sample temperature. By combining these measurements with first-principles modeling, the thermal expansion coefficients (TECs) of single-layer and freestanding graphene and bulk, as well as monolayer MoS2 , MoSe2 , WS2 , or WSe2 , are directly determined and mapped.
Asua, J.M.; Beuermann, S.; Buback, M.; Castignolles, P.; Charleux, B.; Gilbert, R.G.; Hutchinson, R.A.; Leiza, J.R.; Nikitin, A.N.; Vairon, J.P.; Herk, van A.M.
2004-01-01
Propagation rate coefficients, kp, for free-radical polymerization of butyl acrylate (BA) previously reported by several groups are critically evaluated. All data were determined by the combination of pulsed-laser polymerization (PLP) and subsequent polymer analysis by size exclusion (SEC)
Energy Technology Data Exchange (ETDEWEB)
Bretscher, M M [Argonne National Laboratory, Argonne, IL 60439 (United States)
1985-07-01
Simple diffusion theory cannot be used to evaluate control rod worths in thermal neutron reactors because of the strongly absorbing character of the control material. However, reliable control rod worths can be obtained within the framework of diffusion theory if the control material is characterized by a set of mesh-dependent effective diffusion parameters. For thin slab absorbers the effective diffusion parameters can be expressed as functions of a suitably-defined pair of 'blackness coefficients'. Methods for calculating these blackness coefficients in the P1, P3, and P5 approximations, with and without scattering, are presented. For control elements whose geometry does not permit a thin slab treatment, other methods are needed for determining the effective diffusion parameters. One such method, based on reaction rate ratios, is discussed. (author)
Effective dose rate coefficients for exposure to contaminated soil
Energy Technology Data Exchange (ETDEWEB)
Veinot, K.G. [Easterly Scientific, Knoxville, TN (United States); Y-12 National Security Complex, Oak Ridge, TN (United States); Eckerman, K.F.; Easterly, C.E. [Easterly Scientific, Knoxville, TN (United States); Bellamy, M.B.; Hiller, M.M.; Dewji, S.A. [Oak Ridge National Laboratory, Center for Radiation Protection Knowledge, Oak Ridge, TN (United States); Hertel, N.E. [Oak Ridge National Laboratory, Center for Radiation Protection Knowledge, Oak Ridge, TN (United States); Georgia Institute of Technology, Atlanta, GA (United States); Manger, R. [University of California San Diego, Department of Radiation Medicine and Applied Sciences, La Jolla, CA (United States)
2017-08-15
The Oak Ridge National Laboratory Center for Radiation Protection Knowledge has undertaken calculations related to various environmental exposure scenarios. A previous paper reported the results for submersion in radioactive air and immersion in water using age-specific mathematical phantoms. This paper presents age-specific effective dose rate coefficients derived using stylized mathematical phantoms for exposure to contaminated soils. Dose rate coefficients for photon, electron, and positrons of discrete energies were calculated and folded with emissions of 1252 radionuclides addressed in ICRP Publication 107 to determine equivalent and effective dose rate coefficients. The MCNP6 radiation transport code was used for organ dose rate calculations for photons and the contribution of electrons to skin dose rate was derived using point-kernels. Bremsstrahlung and annihilation photons of positron emission were evaluated as discrete photons. The coefficients calculated in this work compare favorably to those reported in the US Federal Guidance Report 12 as well as by other authors who employed voxel phantoms for similar exposure scenarios. (orig.)
Kompan, T. A.; Korenev, A. S.; Lukin, A. Ya.
2008-10-01
The artificial material sitall CO-115M was developed purposely as a material with an extra-low thermal expansion. The controlled crystallization of an aluminosilicate glass melt leads to the formation of a mixture of β-spodumen, β-eucryptite, and β-silica anisotropic microcrystals in a matrix of residual glass. Due to the small size of the microcrystals, the material is homogeneous and transparent. Specific lattice anharmonism of these microcrystal materials results in close to zero average thermal linear expansion coefficient (TLEC) of the sitall material. The thermal expansion coefficient of this material was measured using an interferometric method in line with the classical approach of Fizeau. To obtain the highest accuracy, the registration of light intensity of the total interference field was used. Then, the parameters of the interference pattern were calculated. Due to the large amount of information in the interference pattern, the error of the calculated fringe position was less than the size of a pixel of the optical registration system. The thermal expansion coefficient of the sitall CO-115M and its temperature dependence were measured. The TLEC value of about 3 × 10-8 K-1 to 5 × 10-8 K-1 in the temperature interval from -20 °C to +60 °C was obtained. A special investigation was carried out to show the homogeneity of the material.
Thermal expansion coefficients of obliquely deposited MgF2 thin films and their intrinsic stress.
Jaing, Cheng-Chung
2011-03-20
This study elucidates the effects of columnar angles and deposition angles on the thermal expansion coefficients and intrinsic stress behaviors of MgF2 films with columnar microstructures. The behaviors associated with temperature-dependent stresses in the MgF2 films are measured using a phase-shifting Twyman-Green interferometer with a heating stage and the application of a phase reduction algorithm. The thermal expansion coefficients of MgF2 films at various columnar angles were larger than those of glass substrates. The intrinsic stress in the MgF2 films with columnar microstructures was compressive, while the thermal stress was tensile. The thermal expansion coefficients of MgF2 films with columnar microstructures and their intrinsic stress evidently depended on the deposition angle and the columnar angle.
Absorption coefficient of nearly transparent liquids measured using thermal lens spectrometry
Directory of Open Access Journals (Sweden)
H.Cabrera
2006-01-01
Full Text Available We use an optimized pump-probe mode-mismatched thermal lens scheme to determine the optical absorption coefficient and thermal diffusivity of ethanol, benzene, acetone, methanol, toluene and chloroform. In this scheme the excitation beam is focused in the presence of a collimated probe beam. The agreement between experimentally obtained results and values reported in the literature is good.
International Nuclear Information System (INIS)
Stiller, W.
1985-01-01
A classical collision theory is used to describe thermal bimolecular rate coefficeints for reaction between positive and negative ions and polar molecules in a carrier gas. Special attention is paid to ion-molecule reaction in which proton transfer occurs. These reactions play an important role in terrestrial plasma devices, in ionosphere, in planetary atmospheres and in interstellar matter. The equilibrium rate coefficients of the reactions are calculated based on a microscopic reactive cross section derived from a long distance polar molecule-ion potential. The results are compared with experimental values of afterglow measurements. (D.Gy.)
International Nuclear Information System (INIS)
Blagonravov, L A; Karchevskiy, O O; Ivannikov, P V; Soboleva, A V
2008-01-01
The first results of the thermal expansion coefficient measurement obtained for liquid conductors using a new modulation method are presented. The method is based on a superposition of two periodical influences on a liquid metal. The thermal expansion coefficient α P is determined by means of measuring the amplitudes of oscillations of electric current power w ∼ and pressure p ∼ . In the present work the K-Na alloy of the eutectic composition was used as a sample. Distinction of the experimental data obtained by authors from the literature data is 30 to 40%. Such a difference is in the range of error of determination of α P from the density data of K-Na alloy. The method allows direct determination of the thermal expansion coefficient of liquid conductors in absolute units
Quantum elasticity of graphene: Thermal expansion coefficient and specific heat
Burmistrov, I.S.; Gornyi, I.V.; Kachorovskii, V.Y.; Katsnelson, M.I.; Mirlin, A.D.
2016-01-01
We explore thermodynamics of a quantum membrane, with a particular application to suspended graphene membrane and with a particular focus on the thermal expansion coefficient. We show that an interplay between quantum and classical anharmonicity-controlled fluctuations leads to unusual elastic
International Nuclear Information System (INIS)
Alexander, J.E.
1978-06-01
The report describes a test which was conducted to determine the variation in thermal expansion coefficients of specimens from several material heats of Type 304 stainless steel. The purpose of this document is to identify the procedures, equipment, and analysis used in performing this test. From a review of the data which were used in establishing the values given for mean coefficient of thermal expansion in the 1968 ASME Boiler and Pressure Vessel Code, Section III, a +-3.3-percent maximum variation was determined for Type 304 CRES in the temperature range of interest. The results of the test reduced this variation to +-0.53 percent based on a 95/99-percent tolerance interval for the material tested. The testing equipment, procedure, and analysis are not complicated and this type of test is recommended for applications in which the variation in thermal expansion coefficients is desired for a limited number of material heats
Reaction rate calculations via transmission coefficients
International Nuclear Information System (INIS)
Feit, M.D.; Alder, B.J.
1985-01-01
The transmission coefficient of a wavepacket traversing a potential barrier can be determined by steady state calculations carried out in imaginary time instead of by real time dynamical calculations. The general argument is verified for the Eckart barrier potential by a comparison of transmission coefficients calculated from real and imaginary time solutions of the Schroedinger equation. The correspondence demonstrated here allows a formulation for the reaction rate that avoids difficulties due to both rare events and explicitly time dependent calculations. 5 refs., 2 figs
Directory of Open Access Journals (Sweden)
Monzavi A
2002-07-01
Full Text Available Waxes have a lot of applications in dentistry. Such materials are of thermoplastic type that undergoes deformation in different temperatures. Two important properties of base plate waxes are flow and their coefficient of linear thermal expansion. Recently, different institutions, inside the country, produce dentistry waxes, while they have not been standardized. Consequently, consumers' dissatisfaction are observed. In this research, the two above- mentioned factors were compared between three kinds of Iranian waxes with Cavex that is foreign production, based on test number 24 of ADA. To measure the flow rate in the temperatures of 23, 37 and 45°c, Wilcoxon statistical analysis was used. The results showed that in 23°c, the flow rate of Cavex and Azardent waxes met ADA standards; however, it was not true for two others types. In 37°c, the flow of none of the waxes was standardized and in 45°c their flow was acceptable, moreover, thermal expansion coefficient, for Cavex and Azardent types, was based on ADA standard.
The JPL Cryogenic Dilatometer: Measuring the Thermal Expansion Coefficient of Aerospace Materials
Halverson, Peter G.; Dudick, Matthew J.; Karlmann, Paul; Klein, Kerry J.; Levine, Marie; Marcin, Martin; Parker, Tyler J.; Peters, Robert D.; Shaklan, Stuart; VanBuren, David
2007-01-01
This slide presentation details the cryogenic dilatometer, which is used by JPL to measure the thermal expansion coefficient of materials used in Aerospace. Included is a system diagram, a picture of the dilatometer chamber and the laser source, a description of the laser source, pictures of the interferometer, block diagrams of the electronics and software and a picture of the electronics, and software. Also there is a brief review of the accurace.error budget. The materials tested are also described, and the results are shown in strain curves, JPL measured strain fits are described, and the coefficient of thermal expansion (CTE) is also shown for the materials tested.
Atomic rate coefficients in a degenerate plasma
Aslanyan, Valentin; Tallents, Greg
2015-11-01
The electrons in a dense, degenerate plasma follow Fermi-Dirac statistics, which deviate significantly in this regime from the usual Maxwell-Boltzmann approach used by many models. We present methods to calculate the atomic rate coefficients for the Fermi-Dirac distribution and present a comparison of the ionization fraction of carbon calculated using both models. We have found that for densities close to solid, although the discrepancy is small for LTE conditions, there is a large divergence from the ionization fraction by using classical rate coefficients in the presence of strong photoionizing radiation. We have found that using these modified rates and the degenerate heat capacity may affect the time evolution of a plasma subject to extreme ultraviolet and x-ray radiation such as produced in free electron laser irradiation of solid targets.
Thermal conductivity of sedimentary rocks as function of Biot’s coefficient
DEFF Research Database (Denmark)
Orlander, Tobias; Pasquinelli, Lisa; Asmussen, J.J.
2017-01-01
A theoretical model for prediction of effective thermal conductivity with application to sedimentary rocks is presented. Effective thermal conductivity of sedimentary rocks can be estimated from empirical relations or theoretically modelled. Empirical relations are limited to the empirical...... conductivity of solids is typically orders of magnitude larger than that of fluids, grain contacts constituting the solid connectivity governs the heat transfer of sedi-mentary rocks and hence should be the basis for modelling effective thermal con-ductivity. By introducing Biot’s coefficient, α, we propose (1...... – α) as a measure of the solid connectivity and show how effective thermal conductivity of water saturated and dry sandstones can be modelled....
International Nuclear Information System (INIS)
Zarkova, L.P.
1976-01-01
A general-purpose experimental setup is made to measure thermal conductivity coefficients lambda of inert gases and metal vapours in the range 1000-2500 K by means of the differential method. The setup can also be used to measure lambda of plasmas and reacting gases as well as the dependence of lambda on magnetic fields. A simple and reliable procedure to determine the filament temperature using values of the measured current and wire diameter is suggested. The influence of different factors such as the temperature jump at the boundary gas-filament, convective heat transfer, thermal expansion, excentricity and cold ends of filament on the measured values of the thermal conductivity is considered in details. A formula is deduced to calculate the temperature jump correction taking into account the dependence of the mean free path on the temperature. Expressions are also given to calculate the corrections for thermal expansion, eccentricity and cold ends of the filament. Thermal conductivity coefficients of inert gases are measured to check the method: Ne in the range 1100-2200 K, Ar in the range 1000-2200 K, Kr in the range 1300-2300 K and Xe in the range 1100-2200 K. The data for Ne and Xe in the range 1500 to 2200 K and for Kr at T=2000-2300 K are original. The thermal conductivity coefficient of monoatomic mercury vapour is measured in the range 1000-2300 K with 3% error. The thermal conductivity coefficient of monoatomic cesium vapour is also measured in the range 1000-1600 K with 4% error. (I.P.)
Benchmark calculations of thermal reaction rates. I - Quantal scattering theory
Chatfield, David C.; Truhlar, Donald G.; Schwenke, David W.
1991-01-01
The thermal rate coefficient for the prototype reaction H + H2 yields H2 + H with zero total angular momentum is calculated by summing, averaging, and numerically integrating state-to-state reaction probabilities calculated by time-independent quantum-mechanical scattering theory. The results are very carefully converged with respect to all numerical parameters in order to provide high-precision benchmark results for confirming the accuracy of new methods and testing their efficiency.
Directory of Open Access Journals (Sweden)
Guo Zerong
2016-01-01
Full Text Available To study the effect of variable heat transfer coefficient of fireworks and crackers on thermal explosion critical ambient temperature and time to ignition, considering the heat transfer coefficient as the power function of temperature, mathematical thermal explosion steady state and unsteady-state model of finite cylindrical fireworks and crackers with complex shell structures are established based on two-dimensional steady state thermal explosion theory. The influence of variable heat transfer coefficient on thermal explosion critical ambient temperature and time to ignition are analyzed. When heat transfer coefficient is changing with temperature and in the condition of natural convection heat transfer, critical ambient temperature lessen, thermal explosion time to ignition shorten. If ambient temperature is close to critical ambient temperature, the influence of variable heat transfer coefficient on time to ignition become large. For firework with inner barrel in example analysis, the critical ambient temperature of propellant is 463.88 K and the time to ignition is 4054.9s at 466 K, 0.26 K and 450.8s less than without considering the change of heat transfer coefficient respectively. The calculation results show that the influence of variable heat transfer coefficient on thermal explosion time to ignition is greater in this example. Therefore, the effect of variable heat transfer coefficient should be considered into thermal safety evaluation of fireworks to reduce potential safety hazard.
Dielectronic recombination rate coefficients of initially rubidium-like tungsten
International Nuclear Information System (INIS)
Wu, Z.; Zhang, Y.; Fu, Y.; Dong, C.; Surzhykov, A.; Fritzsche, S.
2015-01-01
Dielectric recombination (DR) is a dominant electron recombination process in plasmas. Tungsten ions are expected to be prominent impurities in fusion plasmas so the knowledge of DR rate coefficient of tungsten ions is important to model fusion plasmas. Ab initio calculations of DR rate coefficients of initially rubidium-like W 37+ ions have been performed for the electron temperatures from 1 eV to 5*10 4 eV, by using the Flexible Atomic Code based on the relativistic configuration-interaction method. Special attention has been paid to the partial contributions to total DR rate coefficients as associated with the excitation of individual subshells. A detailed comparison of the calculations shows that the excitation from 4p subshell dominates total DR rate coefficients followed by the excitations from 4s and 4d subshells, while the contribution of excitations from 3l (l = s, p, d) subshells becomes important only at high temperatures. Besides, it is found that the electron excitations associated with Δn = 0, 1 dominate at low-temperature plasmas, however, the excitations associated with Δn ≥ 2 become non-negligible at high-temperature ones
Transport coefficients for the plasma thermal energy and empirical scaling ''laws''
International Nuclear Information System (INIS)
Coppi, B.
1989-01-01
A set of transport coefficients has been identified for the electron and nuclei thermal energy of plasmas with temperatures in the multi-keV range, taking into account the available experimental information including the temperature spatial profiles and the inferred scaling ''laws'' for the measured energy replacement times. The specific form of these coefficients is suggested by the theory of a mode, so-called ''ubiquitous,'' that can be excited when a significant fraction of the electron population has magnetically trapped orbits. (author)
Dielectronic recombination rate coefficients to excited states of Be-like oxygen
Energy Technology Data Exchange (ETDEWEB)
Murakami, Izumi; Safronova, Ulyana I.; Kato, Takako
2001-05-01
We have calculated energy levels, radiative transition probabilities, and autoionization rates for Be-like oxygen (O{sup 4+}) including ls{sup 2}2lnl' (n=2 - 8, l {<=} n - 1) and 1s{sup 2}3l'nl (n=3 - 6, l {<=} n - l) states by multi-configurational Hartree-Fock method (Cowan code) and perturbation theory Z-expansion method (MZ code). The state selective dielectronic recombination rate coefficients to excited states of Be-like O ions are obtained. Configuration mixing plays an important role for the principal quantum number n distribution of the dielectronic recombination rate coefficients for 2snl (n {<=} 5) levels at low electron temperature. The orbital angular momentum quantum number l distribution of the rate coefficients shows a peak at l = 4. The total dielectronic recombination rate coefficient is derived as a function of electron temperature. (author)
International Nuclear Information System (INIS)
Jo, Hyu Sang; Kang, Hee Yong; Lee, Gyo Woo
2015-01-01
In this experimental study, the thermal stability values of micrometer-sized silica particle-reinforced epoxy composite specimens were evaluated by measuring their thermal expansion coefficients and Young's moduli. For all specimens used in this study (from the baseline specimen to that containing 70 wt% silica filler), the thermal expansion coefficients and Young's moduli were gradually reduced down to 25% and increased up to 51%, respectively. The results of the experiment were compared with those of certain empirical models. The experimental results of the measurement of thermal expansion coefficients corresponded well with those of Kerner's model, which considers the bulk and shear moduli of the matrix and silica filler. However, the results of the measurement of Young's moduli using the empirical Mori-Tanaka model were observed to match better with those of the experiment. The comparison of the results of the experiment with those of the empirical models demonstrated that a reliable model for measuring the thermal expansion coefficients and Young's moduli of composite specimens needs to consider certain property variations in the composites in addition to volume fraction changes in the filler and matrix
International Nuclear Information System (INIS)
Chae, Hee Taek; Lee, Kye Hong
1999-06-01
MATRA-h, a HANARO subchannel analysis computer code, is used to evaluate thermal margin of the HANARO fuel. It's capability includes the assessments of CHF, ONB margin, and fuel temperature. In this report, basic input data and core design parameters required to perform the subchannel analysis with MATRA-h code are collected. These data include the subchannel geometric data, thermal-hydraulic correlations, empirical constants and material properties. The friction and form loss coefficients of the fuel assemblies were determined based on the results of the pressure drop test. At the same time, different form loss coefficients at the end plates and spacers are evaluated for various subchannels. The adequate correlations are applied to the evaluation of the form loss coefficients for various subchannels, which are corrected by measured values in order to have a same pressure drop at each flow channel. These basic input data and design parameters described in this report will be applied usefully to evaluate the thermal margin of the HANARO fuel. (author). 11 refs., 13 tabs., 11 figs
Chen, X. W.; Zhao, C. Y.; Wang, B. X.
2018-05-01
Thermal barrier coatings are common porous materials coated on the surface of devices operating under high temperatures and designed for heat insulation. This study presents a comprehensive investigation on the microstructural effect on radiative scattering coefficient and asymmetry factor of anisotropic thermal barrier coatings. Based on the quartet structure generation set algorithm, the finite-difference-time-domain method is applied to calculate angular scattering intensity distribution of complicated random microstructure, which takes wave nature into account. Combining Monte Carlo method with Particle Swarm Optimization, asymmetry factor, scattering coefficient and absorption coefficient are retrieved simultaneously. The retrieved radiative properties are identified with the angular scattering intensity distribution under different pore shapes, which takes dependent scattering and anisotropic pore shape into account implicitly. It has been found that microstructure significantly affects the radiative properties in thermal barrier coatings. Compared with spherical shape, irregular anisotropic pore shape reduces the forward scattering peak. The method used in this paper can also be applied to other porous media, which designs a frame work for further quantitative study on porous media.
ROVIBRATIONAL QUENCHING RATE COEFFICIENTS OF HD IN COLLISIONS WITH He
International Nuclear Information System (INIS)
Nolte, J. L.; Stancil, P. C.; Lee, T.-G.; Balakrishnan, N.; Forrey, R. C.
2012-01-01
Along with H 2 , HD has been found to play an important role in the cooling of the primordial gas for the formation of the first stars and galaxies. It has also been observed in a variety of cool molecular astrophysical environments. The rate of cooling by HD molecules requires knowledge of collisional rate coefficients with the primary impactors, H, He, and H 2 . To improve knowledge of the collisional properties of HD, we present rate coefficients for the He-HD collision system over a range of collision energies from 10 –5 to 5 × 10 3 cm –1 . Fully quantum mechanical scattering calculations were performed for initial HD rovibrational states of j = 0 and 1 for v = 0-17 which utilized accurate diatom rovibrational wave functions. Rate coefficients of all Δv = 0, –1, and –2 transitions are reported. Significant discrepancies with previous calculations, which adopted a small basis and harmonic HD wave functions for excited vibrational levels, were found for the highest previously considered vibrational state of v = 3. Applications of the He-HD rate coefficients in various astrophysical environments are briefly discussed.
Determination of thermal reactivity coefficients for the first fuel loading of MO34
International Nuclear Information System (INIS)
Lueley, J.; Vrban, B.; Farkas, G.; Hascik, J.; Hinca, R.; Petriska, M.; Slugen, V.
2012-01-01
The article introduces determination of thermal reactivity coefficients, especially summarized (isothermal) and moderator (density) reactivity coefficients between 200 grad C and 260 grad C with 2 grad C step, - in compliance with the assignment - for the first fuel loading into the RC of NP Mochovce units using 2 nd generation fuel during the start-up using calculation code MCNP5 1.60. (authors)
Determination of coefficient of thermal expansion effects on Louisiana's PCC pavement design.
2011-12-01
With the development of the Mechanistic Empirical Pavement Design Guide (MEPDG) as a new pavement design tool, the : coefficient of thermal expansion (CTE) is now considered a more important design parameter in estimating pavement : performance inclu...
Thermal linear expansion coefficient of structural graphites
International Nuclear Information System (INIS)
Virgil'ev, Yu.S.
1995-01-01
The data now available on radiation induced changes of linear thermal expansion coefficients (CTE) for native structural carbon materials (SCM) irradiated with high fluences are summarized. For different types of native and foreign SCM dose dependences of CTE changes in the temperature range of 300...1600 K and at fluences up to (2...3)x10 22 n/cm 2 (E>0.18 meV) are compared. On the base of this comparison factors defined the CTE changes under neutron irradiation are revealed and the explanation of observed phenomena is offered. Large number of the factors revealed does not allowed to calculate CTE radiation induced changes. 39 refs.; 16 figs.; 5 tabs
Dielectronic and Trielectronic Recombination Rate Coefficients of Be-like Ar14+
Huang, Z. K.; Wen, W. Q.; Xu, X.; Mahmood, S.; Wang, S. X.; Wang, H. B.; Dou, L. J.; Khan, N.; Badnell, N. R.; Preval, S. P.; Schippers, S.; Xu, T. H.; Yang, Y.; Yao, K.; Xu, W. Q.; Chuai, X. Y.; Zhu, X. L.; Zhao, D. M.; Mao, L. J.; Ma, X. M.; Li, J.; Mao, R. S.; Yuan, Y. J.; Wu, B.; Sheng, L. N.; Yang, J. C.; Xu, H. S.; Zhu, L. F.; Ma, X.
2018-03-01
Electron–ion recombination of Be-like 40Ar14+ has been measured by employing the electron–ion merged-beams method at the cooler storage ring CSRm. The measured absolute recombination rate coefficients for collision energies from 0 to 60 eV are presented, covering all dielectronic recombination (DR) resonances associated with 2s 2 → 2s2p core transitions. In addition, strong trielectronic recombination (TR) resonances associated with 2s 2 → 2p 2 core transitions were observed. Both DR and TR processes lead to series of peaks in the measured recombination spectrum, which have been identified by the Rydberg formula. Theoretical calculations of recombination rate coefficients were performed using the state-of-the-art multi-configuration Breit–Pauli atomic structure code AUTOSTRUCTURE to compare with the experimental results. The plasma rate coefficients for DR+TR of Ar14+ were deduced from the measured electron–ion recombination rate coefficients in the temperature range from 103 to 107 K, and compared with calculated data from the literature. The experimentally derived plasma rate coefficients are 60% larger and 30% lower than the previously recommended atomic data for the temperature ranges of photoionized plasmas and collisionally ionized plasmas, respectively. However, good agreement was found between experimental results and the calculations by Gu and Colgan et al. The plasma rate coefficients deduced from experiment and calculated by the current AUTOSTRUCTURE code show agreement that is better than 30% from 104 to 107 K. The present results constitute a set of benchmark data for use in astrophysical modeling.
Nickel-base alloys having a low coefficient of thermal expansion
International Nuclear Information System (INIS)
Baldwin, J.F.; Maxwell, D.H.
1975-01-01
Alloy compositions consisting predominantly of nickel, chromium, molybdenum, carbon, and boron are disclosed. The alloys possess a duplex structure consisting of a nickel--chromium--molybdenum matrix and a semi-continuous network of refractory carbides and borides. A combination of desirable properties is provided by these alloys, including elevated temperature strength, resistance to oxidation and hot corrosion, and a very low coefficient of thermal expansion
Reilly, J.; Abdel-Jaber, H.; Yarnold, M.; Glisic, B.
2017-04-01
Structural Health Monitoring aims to characterize the performance of a structure from a combination of recorded sensor data and analytic techniques. Many methods are concerned with quantifying the elastic response of the structure, treating temperature changes as noise in the analysis. While these elastic profiles do demonstrate a portion of structural behavior, thermal loads on a structure can induce comparable strains to elastic loads. Understanding this relationship between the temperature of the structure and the resultant strain and displacement can provide in depth knowledge of the structural condition. A necessary parameter for this form of analysis is the Coefficient of Thermal Expansion (CTE). The CTE of a material relates the amount of expansion or contraction a material undergoes per degree change in temperature, and can be determined from temperature-strain relationship given that the thermal strain can be isolated. Many times with concrete, the actual amount of expansion with temperature in situ varies from the given values for the CTE due to thermally generated elastic strain, which complicates evaluation of the CTE. To accurately characterize the relationship between temperature and strain on a structure, the actual thermal behavior of the structure needs to be analyzed. This rate can vary for different parts of a structure, depending on boundary conditions. In a case of unrestrained structures, the strain in the structure should be linearly related to the temperature change. Thermal gradients in a structure can affect this relationship, as they induce curvature and deplanations in the cross section. This paper proposes a method that addresses these challenges in evaluating the CTE.
Energy Technology Data Exchange (ETDEWEB)
Jo, Hyu Sang; Kang, Hee Yong; Lee, Gyo Woo [Chonbuk National University, Jeonju (Korea, Republic of)
2015-02-15
In this experimental study, the thermal stability values of micrometer-sized silica particle-reinforced epoxy composite specimens were evaluated by measuring their thermal expansion coefficients and Young's moduli. For all specimens used in this study (from the baseline specimen to that containing 70 wt% silica filler), the thermal expansion coefficients and Young's moduli were gradually reduced down to 25% and increased up to 51%, respectively. The results of the experiment were compared with those of certain empirical models. The experimental results of the measurement of thermal expansion coefficients corresponded well with those of Kerner's model, which considers the bulk and shear moduli of the matrix and silica filler. However, the results of the measurement of Young's moduli using the empirical Mori-Tanaka model were observed to match better with those of the experiment. The comparison of the results of the experiment with those of the empirical models demonstrated that a reliable model for measuring the thermal expansion coefficients and Young's moduli of composite specimens needs to consider certain property variations in the composites in addition to volume fraction changes in the filler and matrix.
Efficient calculation of atomic rate coefficients in dense plasmas
Aslanyan, Valentin; Tallents, Greg J.
2017-03-01
Modelling electron statistics in a cold, dense plasma by the Fermi-Dirac distribution leads to complications in the calculations of atomic rate coefficients. The Pauli exclusion principle slows down the rate of collisions as electrons must find unoccupied quantum states and adds a further computational cost. Methods to calculate these coefficients by direct numerical integration with a high degree of parallelism are presented. This degree of optimization allows the effects of degeneracy to be incorporated into a time-dependent collisional-radiative model. Example results from such a model are presented.
Linear thermal expansion coefficient measurement technology in hot cell
International Nuclear Information System (INIS)
Park, Dae Gyu; Choo, Yong Sun; Ahn, Sang Bok; Hong, Kwon Pyo; Lee, K. S.
1998-06-01
To establish linear thermal expansion coefficient measurement technology in hot cell, we reviewed and evaluated various measuring technology by paper and these were compared with the data produced with pre-installed dilatometer in hot cell. Detailed contents are as follows; - The theory of test. - Review of characteristics for various measurement technology and compatibility with hot cell. - Review of standard testing regulations(ASTM). - System calibration of pre-installed dilatometer. - Performance test of pre-installed dilatometer. (author). 12 refs., 15 tabs., 8 figs
International Nuclear Information System (INIS)
Ku, Min Ye; Kim, Jung Hyun; Kang, Hee Yong; Lee, Gyo Woo
2013-01-01
By using shear mixing and ultrasonication, we fabricated specimens of well-dispersed multi-walled carbon nano tube composites. To confirm the proper dispersion of the filler, we used scanning electron microscopy images for quantitative evaluation and a tensile test for qualitative assessment. Furthermore, the coefficients of thermal expansion of several specimens having different filler contents were calculated from the measured thermal strains and temperatures of the specimens. Based on the microscopy images of the well-dispersed fillers and the small deviations in the measurements of the tensile strength and stiffness, we confirmed the proper dispersion of absentee in the epoxy. As the filler contents were increased, the values of tensile strength increased from 58.33 to 68.81 MPa, and those of stiffness increased from 2.93 to 3.27 GPa. At the same time, the coefficients of thermal expansion decreased. This implies better thermal stability of the specimen
Dielectronic recombination rate coefficients to the excited states of CI from CII
International Nuclear Information System (INIS)
Dubau, J.; Kato, T.; Safronova, U.I.
1998-01-01
The dielectronic recombination rate coefficients to the excited states for n=2-6 are calculated including 1s 2 2l 1 2l 2 2l 3 nl (n=2-6, l≤(n-1)) states. The values for the excited states higher than n=6 are extrapolated and the total dielectronic recombination rate coefficients are derived. The rate coefficients to the excited states are fitted to an analytical formula and the fit parameters are given. (author)
Dielectronic recombination rate coefficients to the excited states of CI from CII
Energy Technology Data Exchange (ETDEWEB)
Dubau, J. [Observatoire of Paris, 92 MEUDON (France); Kato, T.; Safronova, U.I.
1998-01-01
The dielectronic recombination rate coefficients to the excited states for n=2-6 are calculated including 1s{sup 2}2l{sub 1}2l{sub 2}2l{sub 3}nl (n=2-6, l{<=}(n-1)) states. The values for the excited states higher than n=6 are extrapolated and the total dielectronic recombination rate coefficients are derived. The rate coefficients to the excited states are fitted to an analytical formula and the fit parameters are given. (author)
The rate coefficients of unimolecular reactions in the systems with power-law distributions
Yin, Cangtao; Guo, Ran; Du, Jiulin
2014-08-01
The rate coefficient formulae of unimolecular reactions are generalized to the systems with the power-law distributions based on nonextensive statistics, and the power-law rate coefficients are derived in the high and low pressure limits, respectively. The numerical analyses are made of the rate coefficients as functions of the ν-parameter, the threshold energy, the temperature and the number of degrees of freedom. We show that the new rate coefficients depend strongly on the ν-parameter different from one (thus from a Boltzmann-Gibbs distribution). Two unimolecular reactions, CH3CO→CH3+CO and CH3NC→CH3CN, are taken as application examples to calculate their power-law rate coefficients, which obtained with the ν-parameters slightly different from one can be exactly in agreement with all the experimental studies on these two reactions in the given temperature ranges.
Organ and effective dose rate coefficients for submersion exposure in occupational settings
International Nuclear Information System (INIS)
Veinot, K.G.; Dewji, S.A.; Hiller, M.M.; Eckerman, K.F.; Easterly, C.E.
2017-01-01
External dose coefficients for environmental exposure scenarios are often computed using assumption on infinite or semi-infinite radiation sources. For example, in the case of a person standing on contaminated ground, the source is assumed to be distributed at a given depth (or between various depths) and extending outwards to an essentially infinite distance. In the case of exposure to contaminated air, the person is modeled as standing within a cloud of infinite, or semi-infinite, source distribution. However, these scenarios do not mimic common workplace environments where scatter off walls and ceilings may significantly alter the energy spectrum and dose coefficients. In this paper, dose rate coefficients were calculated using the International Commission on Radiological Protection (ICRP) reference voxel phantoms positioned in rooms of three sizes representing an office, laboratory, and warehouse. For each room size calculations using the reference phantoms were performed for photons, electrons, and positrons as the source particles to derive mono-energetic dose rate coefficients. Since the voxel phantoms lack the resolution to perform dose calculations at the sensitive depth for the skin, a mathematical phantom was developed and calculations were performed in each room size with the three source particle types. Coefficients for the noble gas radionuclides of ICRP Publication 107 (e.g., Ne, Ar, Kr, Xe, and Rn) were generated by folding the corresponding photon, electron, and positron emissions over the mono-energetic dose rate coefficients. Results indicate that the smaller room sizes have a significant impact on the dose rate per unit air concentration compared to the semi-infinite cloud case. For example, for Kr-85 the warehouse dose rate coefficient is 7% higher than the office dose rate coefficient while it is 71% higher for Xe-133. (orig.)
Organ and effective dose rate coefficients for submersion exposure in occupational settings
Energy Technology Data Exchange (ETDEWEB)
Veinot, K.G. [Easterly Scientific, Knoxville, TN (United States); Y-12 National Security Complex, Oak Ridge, TN (United States); Dewji, S.A.; Hiller, M.M. [Center for Radiation Protection Knowledge, Oak Ridge National Laboratory, Oak Ridge, TN (United States); Eckerman, K.F.; Easterly, C.E. [Easterly Scientific, Knoxville, TN (United States)
2017-11-15
External dose coefficients for environmental exposure scenarios are often computed using assumption on infinite or semi-infinite radiation sources. For example, in the case of a person standing on contaminated ground, the source is assumed to be distributed at a given depth (or between various depths) and extending outwards to an essentially infinite distance. In the case of exposure to contaminated air, the person is modeled as standing within a cloud of infinite, or semi-infinite, source distribution. However, these scenarios do not mimic common workplace environments where scatter off walls and ceilings may significantly alter the energy spectrum and dose coefficients. In this paper, dose rate coefficients were calculated using the International Commission on Radiological Protection (ICRP) reference voxel phantoms positioned in rooms of three sizes representing an office, laboratory, and warehouse. For each room size calculations using the reference phantoms were performed for photons, electrons, and positrons as the source particles to derive mono-energetic dose rate coefficients. Since the voxel phantoms lack the resolution to perform dose calculations at the sensitive depth for the skin, a mathematical phantom was developed and calculations were performed in each room size with the three source particle types. Coefficients for the noble gas radionuclides of ICRP Publication 107 (e.g., Ne, Ar, Kr, Xe, and Rn) were generated by folding the corresponding photon, electron, and positron emissions over the mono-energetic dose rate coefficients. Results indicate that the smaller room sizes have a significant impact on the dose rate per unit air concentration compared to the semi-infinite cloud case. For example, for Kr-85 the warehouse dose rate coefficient is 7% higher than the office dose rate coefficient while it is 71% higher for Xe-133. (orig.)
International Nuclear Information System (INIS)
Wang, Li; Eldridge, Jeffrey I.; Guo, S.M.
2014-01-01
The thermal radiative properties of thermal barrier coatings (TBCs) are becoming more important as the inlet temperatures of advanced gas-turbine engines are continuously being pushed higher in order to improve efficiency. To determine the absorption and scattering coefficients of TBCs, four-flux, two-flux and Kubelka–Munk models were introduced and used to characterize the thermal radiative properties of plasma-sprayed yttria-stabilized zirconia (YSZ) coatings. The results show that the absorption coefficient of YSZ is extremely low for wavelengths 200 μm suggests that when the coating thickness is larger than around twice the average scattering distance, the collimated flux can be simply treated as a diffuse flux inside the coating, and thus the two-flux model can be used to determine the absorption and scattering coefficients as a simplification of the four-flux model
Sinev, Leonid S.; Petrov, Ivan D.
2017-01-01
Processing results of measurements of linear thermal expansion coefficients and linear thermal expansion of two brands of borosilicate glasses --- LK5 and Borofloat 33 --- are presented. The linear thermal expansion of glass samples have been determined in the temperature range 130 to 800 K (minus 143 to 526 $\\deg$C) using thermomechanical analyzer TMA7100. Relative imprecision of indirectly measured linear thermal expansion coefficients and linear thermal expansion of both glass brands is le...
Dielectronic recombination rate coefficients to the excited states of CII from CIII
International Nuclear Information System (INIS)
Kato, Takako; Safronova, U.; Ohira, Mituhiko.
1996-02-01
Energy levels, radiative transition probabilities and autoionization rates for CII including 1s 2 2l2l'nl'' (n=2-6, l'≤(n-1)) states were calculated by using multi-configurational Hartree-Fock (Cowan code) method. Autoionizing levels above three thresholds: 1s 2 2s 2 ( 1 S), 1s 2 2s2p( 3 P), 1s 2 2s2p( 1 P) were considered. Branching ratios related to the first threshold and the intensity factor were calculated for satellite lines of CII ion. The dielectronic recombination rate coefficients to the excited states for n=2-6 are calculated with these atomic data. The rate coefficients are fitted to an analytical formula and the fit parameters are given. The values for higher excited states than n=6 are extrapolated and the total dielectronic recombination rate coefficients are derived. The effective recombination rate coefficient for different electron densities are also derived. (author)
Perturbative methods applied for sensitive coefficients calculations in thermal-hydraulic systems
International Nuclear Information System (INIS)
Andrade Lima, F.R. de
1993-01-01
The differential formalism and the Generalized Perturbation Theory (GPT) are applied to sensitivity analysis of thermal-hydraulics problems related to pressurized water reactor cores. The equations describing the thermal-hydraulic behavior of these reactors cores, used in COBRA-IV-I code, are conveniently written. The importance function related to the response of interest and the sensitivity coefficient of this response with respect to various selected parameters are obtained by using Differential and Generalized Perturbation Theory. The comparison among the results obtained with the application of these perturbative methods and those obtained directly with the model developed in COBRA-IV-I code shows a very good agreement. (author)
Bisetti, Fabrizio; El Morsli, Mbark
2012-01-01
Simulations of ion and electron transport in flames routinely adopt plasma fluid models, which require transport coefficients to compute the mass flux of charged species. In this work, the mobility and diffusion coefficient of thermal electrons
CFD simulation of simultaneous monotonic cooling and surface heat transfer coefficient
International Nuclear Information System (INIS)
Mihálka, Peter; Matiašovský, Peter
2016-01-01
The monotonic heating regime method for determination of thermal diffusivity is based on the analysis of an unsteady-state (stabilised) thermal process characterised by an independence of the space-time temperature distribution on initial conditions. At the first kind of the monotonic regime a sample of simple geometry is heated / cooled at constant ambient temperature. The determination of thermal diffusivity requires the determination rate of a temperature change and simultaneous determination of the first eigenvalue. According to a characteristic equation the first eigenvalue is a function of the Biot number defined by a surface heat transfer coefficient and thermal conductivity of an analysed material. Knowing the surface heat transfer coefficient and the first eigenvalue the thermal conductivity can be determined. The surface heat transport coefficient during the monotonic regime can be determined by the continuous measurement of long-wave radiation heat flow and the photoelectric measurement of the air refractive index gradient in a boundary layer. CFD simulation of the cooling process was carried out to analyse local convective and radiative heat transfer coefficients more in detail. Influence of ambient air flow was analysed. The obtained eigenvalues and corresponding surface heat transfer coefficient values enable to determine thermal conductivity of the analysed specimen together with its thermal diffusivity during a monotonic heating regime.
Mendoza, Sergio; Rothenberger, Michael; Hake, Alison; Fathy, Hosam
2016-03-01
This article presents a framework for optimizing the thermal cycle to estimate a battery cell's entropy coefficient at 20% state of charge (SOC). Our goal is to maximize Fisher identifiability: a measure of the accuracy with which a parameter can be estimated. Existing protocols in the literature for estimating entropy coefficients demand excessive laboratory time. Identifiability optimization makes it possible to achieve comparable accuracy levels in a fraction of the time. This article demonstrates this result for a set of lithium iron phosphate (LFP) cells. We conduct a 24-h experiment to obtain benchmark measurements of their entropy coefficients. We optimize a thermal cycle to maximize parameter identifiability for these cells. This optimization proceeds with respect to the coefficients of a Fourier discretization of this thermal cycle. Finally, we compare the estimated parameters using (i) the benchmark test, (ii) the optimized protocol, and (iii) a 15-h test from the literature (by Forgez et al.). The results are encouraging for two reasons. First, they confirm the simulation-based prediction that the optimized experiment can produce accurate parameter estimates in 2 h, compared to 15-24. Second, the optimized experiment also estimates a thermal time constant representing the effects of thermal capacitance and convection heat transfer.
Thermal properties and heat transfer coefficients in cryogenic cooling
Biddulph, M. W.; Burford, R. P.
This paper considers two aspects of the design of the cooling stage of the process known as cryogenic recycling. This process uses liquid nitrogen to embrittle certain materials before grinding and subsequent separation. It is being increasingly used in materials recycling. A simple method of establishing thermal diffusivity values of materials of interest by using cooling curves is described. These values are important for effective cooler design. In addition values of convective heat transfer coefficient have been determined in an operating inclined, rotating cylindrical cooler operating on scrap car tyres. These will also be useful for cooler design methods.
Energy Technology Data Exchange (ETDEWEB)
Donne, M.D.; Piazza, G. [Forschungszentrum Karlsruhe GmbH Technik und Umwelt (Germany). Inst. fuer Neutronenphysik und Reaktortechnik; Goraieb, A.; Sordon, G.
1998-01-01
The four ITER partners propose to use binary beryllium pebble bed as neutron multiplier. Recently this solution has been adopted for the ITER blanket as well. In order to study the heat transfer in the blanket the effective thermal conductivity and the wall heat transfer coefficient of the bed have to be known. Therefore at Forschungszentrum Karlsruhe heat transfer experiments have been performed with a binary bed of beryllium pebbles and the results have been correlated expressing thermal conductivity and wall heat transfer coefficients as a function of temperature in the bed and of the difference between the thermal expansion of the bed and of that of the confinement walls. The comparison of the obtained correlations with the data available from the literature show a quite good agreement. (author)
Surplus thermal energy model of greenhouses and coefficient analysis for effective utilization
Directory of Open Access Journals (Sweden)
Seung-Hwan Yang
2016-03-01
Full Text Available If a greenhouse in the temperate and subtropical regions is maintained in a closed condition, the indoor temperature commonly exceeds that required for optimal plant growth, even in the cold season. This study considered this excess energy as surplus thermal energy (STE, which can be recovered, stored and used when heating is necessary. To use the STE economically and effectively, the amount of STE must be estimated before designing a utilization system. Therefore, this study proposed an STE model using energy balance equations for the three steps of the STE generation process. The coefficients in the model were determined by the results of previous research and experiments using the test greenhouse. The proposed STE model produced monthly errors of 17.9%, 10.4% and 7.4% for December, January and February, respectively. Furthermore, the effects of the coefficients on the model accuracy were revealed by the estimation error assessment and linear regression analysis through fixing dynamic coefficients. A sensitivity analysis of the model coefficients indicated that the coefficients have to be determined carefully. This study also provides effective ways to increase the amount of STE.
Surplus thermal energy model of greenhouses and coefficient analysis for effective utilization
Energy Technology Data Exchange (ETDEWEB)
Yang, S.H.; Son, J.E.; Lee, S.D.; Cho, S.I.; Ashtiani-Araghi, A.; Rhee, J.Y.
2016-11-01
If a greenhouse in the temperate and subtropical regions is maintained in a closed condition, the indoor temperature commonly exceeds that required for optimal plant growth, even in the cold season. This study considered this excess energy as surplus thermal energy (STE), which can be recovered, stored and used when heating is necessary. To use the STE economically and effectively, the amount of STE must be estimated before designing a utilization system. Therefore, this study proposed an STE model using energy balance equations for the three steps of the STE generation process. The coefficients in the model were determined by the results of previous research and experiments using the test greenhouse. The proposed STE model produced monthly errors of 17.9%, 10.4% and 7.4% for December, January and February, respectively. Furthermore, the effects of the coefficients on the model accuracy were revealed by the estimation error assessment and linear regression analysis through fixing dynamic coefficients. A sensitivity analysis of the model coefficients indicated that the coefficients have to be determined carefully. This study also provides effective ways to increase the amount of STE. (Author)
Determination of the N2 recombination rate coefficient in the ionosphere
Orsini, N.; Torr, D. G.; Brinton, H. C.; Brace, L. H.; Hanson, W. B.; Hoffman, J. H.; Nier, A. O.
1977-01-01
Measurements of aeronomic parameters made by the Atmosphere Explorer-C satellite are used to determine the recombination rate coefficient of N2(+) in the ionosphere. The rate is found to increase significantly with decreasing electron density. Values obtained range from approximately 1.4 x 10 to the -7th to 3.8 x 10 to the -7th cu cm/sec. This variation is explained in a preliminary way in terms of an increase in the rate coefficient with vibrational excitation. Thus, high electron densities depopulate high vibrational levels reducing the effective recombination rate, whereas, low electron densities result in an enhancement in the population of high vibrational levels, thus, increasing the effective recombination rate.
International Nuclear Information System (INIS)
Fontheim, E.G.; Ong, R.S.B.; Roble, R.G.; Mayr, H.G.; Hoegy, W.H.; Baron, M.J.; Wickwar, V.B.
1978-01-01
By analyzing an observed storm time auroral electron temperature profile it is shown that anomalous transport effects strongly influence the thermal structure of the disturbed auroral ionosphere. Such anomalous transport effects are a consequence of plasma turbulence, the existence of which has been established by a large number of observations in the auroral ionosphere. The electron and composite ion energy equations are solved with anomalous electron thermal conductivity and parallel electrical resistivity coefficients. The solutions are parameterized with respect to a phenomenological altitude-dependent anomaly coefficient A and are compared with an observed storm time electron temperature profile above Chatanika. The calculated temperature profile for the classical case (A=1)disagrees considerably with the measured profile over most of the altitude range up to 450km. It is shown that an anomaly coefficient with a sharp peak of the order of 10 4 centered aroung the F 2 peak is consistent with observations
2012-10-01
The Coefficient of Thermal Expansion (CTE) is an important parameter in Portland Cement Concrete (PCC) pavement analysis and design as it is directly proportional to the magnitude of temperature-related pavement deformations throughout the pavement s...
Rate Coefficients for the OH + (CHO)2 (Glyoxal) Reaction Between 240 and 400 K
Feierabend, K. J.; Talukdar, R. K.; Zhu, L.; Ravishankara, A. R.; Burkholder, J. B.
2006-12-01
Glyoxal (CHO)2, the simplest dialdehyde, is an end product formed in the atmospheric oxidation of biogenic hydrocarbons, for example, isoprene. As such, glyoxal plays a role in regional air quality and ozone production in certain locations. Glyoxal is lost in the atmosphere via UV photolysis and reaction with OH. However, the currently available rate coefficient data for the OH + glyoxal reaction is limited to a single room- temperature measurement made using the relative rate method. A determination of the rate coefficient temperature dependence is therefore needed for a more complete interpretation of the atmospheric processing of glyoxal. This study reports the rate coefficient for the OH + (CHO)2 reaction measured under pseudo- first-order conditions in OH ([(CHO)2] > 1000 [OH]0). OH radicals were produced using 248 nm pulsed laser photolysis of H2O2 or HNO3 and detected by pulsed laser induced fluorescence. The concentration of glyoxal in the reactor was determined using three independent techniques; gas flow rates as well as in situ UV and IR absorption. The total pressure in the reactor was varied from 40 to 300 Torr (He), and the rate coefficient was found to be independent of pressure over the temperature range studied. The rate coefficient exhibits a negative temperature dependence between 240 and 400 K consistent with the dependence previously observed for many other aldehydes. Our room-temperature rate coefficient is smaller than the relative rate value that is currently recommended for use in atmospheric model calculations. Our measured rate coefficients are discussed with respect to those for other aldehydes. The atmospheric implications of our work will also be discussed.
Dielectronic recombination rate coefficients to the excited states of CIII from CIV
Energy Technology Data Exchange (ETDEWEB)
Safronova, U.; Kato, Takako; Ohira, Mituhiko
1996-07-01
Energy levels, radiative transition probabilities and autoionization rates for CIII including 1s{sup 2}2pnl` (n=2/6, l`{<=}(n-1)) and 1s{sup 2}3lnl` (n=3/6, l`{<=}(n-1)) states were calculated by using multi-configurational Hartree-Fock (Cowan code) method. Autoionizing levels above the 1s{sup 2}2s and 1s{sup 2}2p thresholds were considered and their contributions were computed. Branching ratios on the autoionization rate to the first threshold and intensity factor were calculated for satellite lines of CIII ion. The dielectronic recombination rate coefficients to the excited states for n=2-6 were calculated. The values for the excited states higher than n=6 were extrapolated and the total dielectronic recombination rate coefficients were also derived. The rate coefficients to the excited states were fitted to an analytical formula and the fitting parameters are given. (author)
Semiempirical method of determining flow coefficients for pitot rake mass flow rate measurements
Trefny, C. J.
1985-01-01
Flow coefficients applicable to area-weighted pitot rake mass flow rate measurements are presented for fully developed, turbulent flow in an annulus. A turbulent velocity profile is generated semiempirically for a given annulus hub-to-tip radius ratio and integrated numerically to determine the ideal mass flow rate. The calculated velocities at each probe location are then summed, and the flow rate as indicated by the rake is obtained. The flow coefficient to be used with the particular rake geometry is subsequently obtained by dividing the ideal flow rate by the rake-indicated flow rate. Flow coefficients ranged from 0.903 for one probe placed at a radius dividing two equal areas to 0.984 for a 10-probe area-weighted rake. Flow coefficients were not a strong function of annulus hub-to-tip radius ratio for rakes with three or more probes. The semiempirical method used to generate the turbulent velocity profiles is described in detail.
Efficiency analysis of straight fin with variable heat transfer coefficient and thermal conductivity
International Nuclear Information System (INIS)
Sadri, Somayyeh; Raveshi, Mohammad Reza; Amiri, Shayan
2012-01-01
In this study, one type of applicable analytical method, differential transformation method (DTM), is used to evaluate the efficiency and behavior of a straight fin with variable thermal conductivity and heat transfer coefficient. Fins are widely used to enhance heat transfer between primary surface and the environment in many industrial applications. The performance of such a surface is significantly affected by variable thermal conductivity and heat transfer coefficient, particularly for large temperature differences. General heat transfer equation related to the fin is derived and dimensionalized. The concept of differential transformation is briefly introduced, and then this method is employed to derive solutions of nonlinear equations. Results are evaluated for several cases such as: laminar film boiling or condensation, forced convection, laminar natural convection, turbulent natural convection, nucleate boiling, and radiation. The obtained results from DTM are compared with the numerical solution to verify the accuracy of the proposed method. The effects of design parameters on temperature and efficiency are evaluated by some figures. The major aim of the present study, which is exclusive for this article, is to find the effect of the modes of heat transfer on fin efficiency. It has been shown that for radiation heat transfer, thermal efficiency reaches its maximum value
International Nuclear Information System (INIS)
Zhou, X; Zhang, Z Y; Zhang, Q M; Liu, Q; Ding, Y Y; Zhou, L; Cao, J
2015-01-01
We report the measurements of the densities of linear alkylbenzene at three temperatures over 4 to 23 °C with pressures up to 10 MPa. The measurements have been analysed to yield the isobaric thermal expansion coefficients and, so far for the first time, isothermal compressibilities of linear alkylbenzene. Relevance of results for current generation (i.e., Daya Bay) and next generation (i.e. JUNO) large liquid scintillator neutrino detectors are discussed. (paper)
Determination of sedimentation rates and absorption coefficient of ...
African Journals Online (AJOL)
DR. MIKE HORSFALL
particles have pores that can absorb radiation. Gamma rays have been used to study the absorption coefficients of cobalt(II) insoluble compounds (Essien and Ekpe, 1998), densities of marine sediments. (Gerland and Villinger, 1995) and soil particle-size distribution (Vaz et al., 1992). In this study, sedimentation rates of ...
Thermally induced delamination of multilayers
DEFF Research Database (Denmark)
Sørensen, Bent F.; Sarraute, S.; Jørgensen, O.
1998-01-01
Steady-state delamination of multilayered structures, caused by stresses arising during processing due to thermal expansion mismatch, is analyzed by a fracture mechanics model based on laminate theory. It is found that inserting just a few interlayers with intermediate thermal expansion coefficie...... coefficients may be an effective way of reducing the delamination energy release rate. Uneven layer thickness and increasing elastic mismatch are shown to raise the energy release rate. Experimental work confirms important trends of the model.......Steady-state delamination of multilayered structures, caused by stresses arising during processing due to thermal expansion mismatch, is analyzed by a fracture mechanics model based on laminate theory. It is found that inserting just a few interlayers with intermediate thermal expansion...
Cold collisions of SH- with He: Potential energy surface and rate coefficients
Bop, C. T.; Trabelsi, T.; Hammami, K.; Mogren Al Mogren, M.; Lique, F.; Hochlaf, M.
2017-09-01
Collisional energy transfer under cold conditions is of great importance from the fundamental and applicative point of view. Here, we investigate low temperature collisions of the SH- anion with He. We have generated a three-dimensional potential energy surface (PES) for the SH-(X1Σ+)-He(1S) van der Waals complex. The ab initio multi-dimensional interaction PES was computed using the explicitly correlated coupled cluster approach with simple, double, and perturbative triple excitation in conjunction with the augmented-correlation consistent-polarized valence triple zeta Gaussian basis set. The PES presents two minima located at linear geometries. Then, the PES was averaged over the ground vibrational wave function of the SH- molecule and the resulting two-dimensional PES was incorporated into exact quantum mechanical close coupling calculations to study the collisional excitation of SH- by He. We have computed inelastic cross sections among the 11 first rotational levels of SH- for energies up to 2500 cm-1. (De-)excitation rate coefficients were deduced for temperatures ranging from 1 to 300 K by thermally averaging the cross sections. We also performed calculations using the new PES for a fixed internuclear SH- distance. Both sets of results were found to be in reasonable agreement despite differences existing at low temperatures confirming that accurate predictions require the consideration of all internal degrees of freedom in the case of molecular hydrides. The rate coefficients presented here may be useful in interpreting future experimental work on the SH- negative ion colliding with He as those recently done for the OH--He collisional system as well as for possible astrophysical applications in case SH- would be detected in the interstellar medium.
International Nuclear Information System (INIS)
Van Berkel, M; Hogeweij, G M D; Van den Brand, H; De Baar, M R; Zwart, H J; Vandersteen, G
2014-01-01
In this paper, the estimation of the thermal diffusivity from perturbative experiments in fusion plasmas is discussed. The measurements used to estimate the thermal diffusivity suffer from stochastic noise. Accurate estimation of the thermal diffusivity should take this into account. It will be shown that formulas found in the literature often result in a thermal diffusivity that has a bias (a difference between the estimated value and the actual value that remains even if more measurements are added) or have an unnecessarily large uncertainty. This will be shown by modeling a plasma using only diffusion as heat transport mechanism and measurement noise based on ASDEX Upgrade measurements. The Fourier coefficients of a temperature perturbation will exhibit noise from the circular complex normal distribution (CCND). Based on Fourier coefficients distributed according to a CCND, it is shown that the resulting probability density function of the thermal diffusivity is an inverse non-central chi-squared distribution. The thermal diffusivity that is found by sampling this distribution will always be biased, and averaging of multiple estimated diffusivities will not necessarily improve the estimation. Confidence bounds are constructed to illustrate the uncertainty in the diffusivity using several formulas that are equivalent in the noiseless case. Finally, a different method of averaging, that reduces the uncertainty significantly, is suggested. The methodology is also extended to the case where damping is included, and it is explained how to include the cylindrical geometry. (paper)
The Influence of Particle Charge on Heterogeneous Reaction Rate Coefficients
Aikin, A. C.; Pesnell, W. D.
2000-01-01
The effects of particle charge on heterogeneous reaction rates are presented. Many atmospheric particles, whether liquid or solid are charged. This surface charge causes a redistribution of charge within a liquid particle and as a consequence a perturbation in the gaseous uptake coefficient. The amount of perturbation is proportional to the external potential and the square of the ratio of debye length in the liquid to the particle radius. Previous modeling has shown how surface charge affects the uptake coefficient of charged aerosols. This effect is now included in the heterogeneous reaction rate of an aerosol ensemble. Extension of this analysis to ice particles will be discussed and examples presented.
Collisional excitation rate coefficients for lithium-like ions
International Nuclear Information System (INIS)
Cochrane, D.M.; McWhirter, R.W.P.
1982-11-01
This report takes all the available good quality quantal calculations of excitation cross-sections by electron collision for lithium-like ions and intercompares them. There is a comparison also with the small amount of experimental data of 2s 2 S - 2p 2 P cross-sections. On the basis of all of these data, a choice is made of the best cross-sections and these are integrated over Maxwellians to give excitation rate coefficients. In general data are available for up to seven transitions in five or six ions. When the results are compared along the iso-electronic sequence, trends are established which allow estimates to be made of the rate coefficients for these seven transitions for any lithium-like ion of nuclear charge greater than boron. The results are presented graphically and as simple formulae. The formulae reproduce the source data at various levels of accuracy from about +-1% for individual ions to universal formulae of accuracy better than +-15% in the relevant temperature ranges. (author)
Werfelli, Ghofran; Halvick, Philippe; Honvault, Pascal; Kerkeni, Boutheïna; Stoecklin, Thierry
2015-09-21
The observed abundances of the methylidyne cation, CH(+), in diffuse molecular clouds can be two orders of magnitude higher than the prediction of the standard gas-phase models which, in turn, predict rather well the abundances of neutral CH. It is therefore necessary to investigate all the possible formation and destruction processes of CH(+) in the interstellar medium with the most abundant species H, H2, and e(-). In this work, we address the destruction process of CH(+) by hydrogen abstraction. We report a new calculation of the low temperature rate coefficients for the abstraction reaction, using accurate time-independent quantum scattering and a new high-level ab initio global potential energy surface including a realistic model of the long-range interaction between the reactants H and CH(+). The calculated thermal rate coefficient is in good agreement with the experimental data in the range 50 K-800 K. However, at lower temperatures, the experimental rate coefficient takes exceedingly small values which are not reproduced by the calculated rate coefficient. Instead, the latter rate coefficient is close to the one given by the Langevin capture model, as expected for a reaction involving an ion and a neutral species. Several recent theoretical works have reported a seemingly good agreement with the experiment below 50 K, but an analysis of these works show that they are based on potential energy surfaces with incorrect long-range behavior. The experimental results were explained by a loss of reactivity of the lowest rotational states of the reactant; however, the quantum scattering calculations show the opposite, namely, a reactivity enhancement with rotational excitation.
Molecular dynamics study of the thermal expansion coefficient of silicon
Energy Technology Data Exchange (ETDEWEB)
Nejat Pishkenari, Hossein, E-mail: nejat@sharif.edu; Mohagheghian, Erfan; Rasouli, Ali
2016-12-16
Due to the growing applications of silicon in nano-scale systems, a molecular dynamics approach is employed to investigate thermal properties of silicon. Since simulation results rely upon interatomic potentials, thermal expansion coefficient (TEC) and lattice constant of bulk silicon have been obtained using different potentials (SW, Tersoff, MEAM, and EDIP) and results indicate that SW has a better agreement with the experimental observations. To investigate effect of size on TEC of silicon nanowires, further simulations are performed using SW potential. To this end, silicon nanowires of different sizes are examined and their TEC is calculated by averaging in different directions ([100], [110], [111], and [112]) and various temperatures. Results show that as the size increases, due to the decrease of the surface effects, TEC approaches its bulk value. - Highlights: • MD simulations of TEC and lattice constant of bulk silicon. • Effects of four potentials on the results. • Comparison to experimental data. • Investigating size effect on TEC of silicon nanowires.
Rate coefficients for hydrogen abstraction reaction of pinonaldehyde
Indian Academy of Sciences (India)
The H abstraction reaction from the –CHO group was found to be the most dominant reaction channelamong all the possible reaction pathways and its corresponding rate coefficient at 300 K is kEckart's unsymmetrical= 3.86 ×10-10 cm3 molecule-1 s-1. Whereas the channel with immediate lower activation energy is the ...
Rate Coefficients of the Reaction of OH with Allene and Propyne at High Temperatures
Es-sebbar, Et-touhami
2016-09-28
Allene (H2C═C═CH2; a-C3H4) and propyne (CH3C≡CH; p-C3H4) are important species in various chemical environments. In combustion processes, the reactions of hydroxyl radicals with a-C3H4 and p-C3H4 are critical in the overall fuel oxidation system. In this work, rate coefficients of OH radicals with allene (OH + H2C═C═CH2 → products) and propyne (OH + CH3C≡CH → products) were measured behind reflected shock waves over the temperature range of 843–1352 K and pressures near 1.5 atm. Hydroxyl radicals were generated by rapid thermal decomposition of tert-butyl hydroperoxide ((CH3)3–CO–OH), and monitored by narrow line width laser absorption of the well-characterized R1(5) electronic transition of the OH A–X (0,0) electronic system near 306.7 nm. Results show that allene reacts faster with OH radicals than propyne over the temperature range of this study. Measured rate coefficients can be expressed in Arrhenius form as follows: kallene+OH(T) = 8.51(±0.03) × 10–22T3.05 exp(2215(±3)/T), T = 843–1352 K; kpropyne+OH(T) = 1.30(±0.07) × 10–21T3.01 exp(1140(±6)/T), T = 846–1335 K.
Thermal performances of molten salt steam generator
International Nuclear Information System (INIS)
Yuan, Yibo; He, Canming; Lu, Jianfeng; Ding, Jing
2016-01-01
Highlights: • Thermal performances of molten salt steam generator were experimentally studied. • Overall heat transfer coefficient reached maximum with optimal molten salt flow rate. • Energy efficiency first rose and then decreased with salt flow rate and temperature. • Optimal molten salt flow rate and temperature existed for good thermal performance. • High inlet water temperature benefited steam generating rate and energy efficiency. - Abstract: Molten salt steam generator is the key technology for thermal energy conversion from high temperature molten salt to steam, and it is used in solar thermal power station and molten salt reactor. A shell and tube type molten salt steam generator was set up, and its thermal performance and heat transfer mechanism were studied. As a coupling heat transfer process, molten salt steam generation is mainly affected by molten salt convective heat transfer and boiling heat transfer, while its energy efficiency is also affected by the heat loss. As molten salt temperature increased, the energy efficiency first rose with the increase of heat flow absorbed by water/steam, and then slightly decreased for large heat loss as the absorbed heat flow still rising. At very high molten salt temperature, the absorbed heat flow decreased as boiling heat transfer coefficient dropping, and then the energy efficiency quickly dropped. As the inlet water temperature increased, the boiling region in the steam generator remarkably expanded, and then the steam generation rate and energy efficiency both rose with the overall heat transfer coefficient increasing. As the molten salt flow rate increased, the wall temperature rose and the boiling heat transfer coefficient first increased and then decreased according to the boiling curve, so the overall heat transfer coefficient first increased and then decreased, and then the steam generation rate and energy efficiency of steam generator both had maxima.
Modeling of thermal expansion coefficient of perovskite oxide for solid oxide fuel cell cathode
Heydari, F.; Maghsoudipour, A.; Alizadeh, M.; Khakpour, Z.; Javaheri, M.
2015-09-01
Artificial intelligence models have the capacity to eliminate the need for expensive experimental investigation in various areas of manufacturing processes, including the material science. This study investigates the applicability of adaptive neuro-fuzzy inference system (ANFIS) approach for modeling the performance parameters of thermal expansion coefficient (TEC) of perovskite oxide for solid oxide fuel cell cathode. Oxides (Ln = La, Nd, Sm and M = Fe, Ni, Mn) have been prepared and characterized to study the influence of the different cations on TEC. Experimental results have shown TEC decreases favorably with substitution of Nd3+ and Mn3+ ions in the lattice. Structural parameters of compounds have been determined by X-ray diffraction, and field emission scanning electron microscopy has been used for the morphological study. Comparison results indicated that the ANFIS technique could be employed successfully in modeling thermal expansion coefficient of perovskite oxide for solid oxide fuel cell cathode, and considerable savings in terms of cost and time could be obtained by using ANFIS technique.
Corsetti, James A.; Green, William E.; Ellis, Jonathan D.; Schmidt, Greg R.; Moore, Duncan T.
2017-01-01
A system combining an interferometer with an environmental chamber for measuring both coefficient of thermal expansion (CTE) and temperature-dependent refractive index (dn/dT) simultaneously is presented. The operation and measurement results of this instrument are discussed.
2009-01-01
PROBLEM: The coefficient of thermal expansion (CTE) is a fundamental property of construction : materials such as steel and concrete. Although the CTE of steel is a well-defined : constant, the CTE of concrete varies substantially with aggregate type...
2011-12-01
The coefficient of thermal expansion (CTE) has been widely considered as a fundamental property of : Portland cement concrete (PCC) pavement but has never played an important role in the thickness design : procedure for PCC pavement until recently. I...
Rate Coefficient Measurements of the Reaction CH3 + O2 = CH3O + O
Hwang, S. M.; Ryu, Si-Ok; DeWitt, K. J.; Rabinowitz, M. J.
1999-01-01
Rate coefficients for the reaction CH3 + O2 = CH3O + O were measured behind reflected shock waves in a series of lean CH4-O2-Ar mixtures using hydroxyl and methyl radical diagnostics. The rate coefficients are well represented by an Arrhenius expression given as k = (1.60(sup +0.67, sub -0.47 ) x 10(exp 13) e(-15813 +/- 587 K/T)/cubic cm.mol.s. This expression, which is valid in the temperature range 1575-1822 K, supports the downward trend in the rate coefficients that has been reported in recent determinations. All measurements to date, including the present study, have been to some extent affected by secondary reactions. The complications due to secondary reactions, choice of thermochemical data, and shock-boundary layer interactions that affect the determination of the rate coefficients are examined.
Rate Coefficient Measurements of the Reaction CH3+O2+CH3O+O
Hwang, S. M.; Ryu, Si-Ok; DeWitt, K. J.; Rabinowitz, M. J.
1999-01-01
Rate coefficients for the reaction CH3 + O2 = CH3O + O were measured behind reflected shock waves in a series of lean CH4-O2-Ar mixtures using hydroxyl and methyl radical diagnostics. The rate coefficients are well represented by an Arrhenius expression given as k = (1.60(sup +0.67, -0.47)) X 10(exp 13) exp(- 15813 +/- 587 K/T)cc/mol s. This expression, which is valid in the temperature range 1575-1822 K, supports the downward trend in the rate coefficients that has been reported in recent determinations. All measurements to date, including the present study, have been to some extent affected by secondary reactions. The complications due to secondary reactions, choice of thermochemical data, and shock-boundary layer interactions that affect the determination of the rate coefficients are examined.
Net emission coefficient for CO–H2 thermal plasmas with the consideration of molecular systems
International Nuclear Information System (INIS)
Billoux, T.; Cressault, Y.; Gleizes, A.
2015-01-01
This paper deals with the calculation of net emission coefficients (NECs) for CO–H 2 thermal plasmas. This task required the elaboration of a complete spectroscopic database including atoms and molecules formed by carbon, oxygen and hydrogen elements. We have used a systematic line by line method to calculate all the main radiative contributions which are the atomic and molecular continua, the atomic lines and the molecular (diatomic and polyatomic) lines. The main diatomic electronic systems for CO–H 2 plasmas and the triatomic molecular bands were considered. We present some variations of the net emission coefficient versus temperature, for various pressures and for two relative proportions of the components. The role of the diatomic molecules is important at temperatures lower than 5000 K whereas the net emission coefficient presents an unusual peak at temperature around 1000 K, due to the presence of the CO 2 molecule presenting a strong infrared radiation. Finally, the results show that the NEC slightly depends on the relative proportion of CO and H 2 . - highlights: • We calculate radiative losses from CO–H 2 thermal plasmas. • We use the up-to-date atomic and molecular databases. • The influence of CO 2 molecule is very important at low temperature. • The relative maximum of the net emission coefficient at low temperature is unusual
Directory of Open Access Journals (Sweden)
Z. EZZOUINE
2015-07-01
Full Text Available In this study, we present a newly designed electromagnetic dilatometer with micrometer accuracy for the measurement of the coefficient of thermal expansion of a solid in the 30 °C – 96 °C temperature range .The device has a graphical user interface to view real time data measurement. Iron and copper were subjected to temperature change in the thermal expansion experiment causing them to expand linearly. The voltage delivered in the electromagnetic dilatometer system, which includes the information about linear expansion and temperature change were transferred to a computer via a data acquisition card, presented by a program created in the LabVIEW environment, and the amount of linear expansion was detected in real time. The minimal change in length of the sample that can be resolved is 5µm, which yields the sensitivity comprised between 10-4 µm and 10-5 µm. In order to calibrate the electromagnetic dilatometer, thermal expansion coefficients of copper and Iron have been measured. By this technique, the thermal expansion coefficient can be determined with an acceptable accuracy. The present results appear also to agree well with those reported previously in the literature.
Thermal Coefficient of Linear Expansion Modified by Dendritic Segregation in Nickel-Iron Alloys
Ogorodnikova, O. M.; Maksimova, E. V.
2018-05-01
The paper presents investigations of thermal properties of Fe-Ni and Fe-Ni-Co casting alloys affected by the heterogeneous distribution of their chemical elements. It is shown that nickel dendritic segregation has a negative effect on properties of studied invars. A mathematical model is proposed to explore the influence of nickel dendritic segregation on the thermal coefficient of linear expansion (TCLE) of the alloy. A computer simulation of TCLE of Fe-Ni-Co superinvars is performed with regard to a heterogeneous distribution of their chemical elements over the whole volume. The ProLigSol computer software application is developed for processing the data array and results of computer simulation.
Zhang, Richard X; Fisher, Timothy; Raman, Arvind; Sands, Timothy D
2009-01-01
In this article, a precise and convenient technique based on the atomic force microscope (AFM) is developed to measure the linear coefficient of thermal expansion of a porous anodic alumina thin film. A stage was used to heat the sample from room temperature up to 450 K. Thermal effects on AFM probes and different operation modes at elevated temperatures were also studied, and a silicon AFM probe in the tapping mode was chosen for the subsequent measurements due to its temperature insensitivi...
Thermal expansion and cooling rate dependence of transition temperature in ZrTiO4 single crystal
International Nuclear Information System (INIS)
Park, Y.
1998-01-01
Thermal expansion in ZrTiO 4 single crystal was investigated in the temperature range covering the normal, incommensurate, and commensurate phases. Remarkable change was found at the normal-incommensurate phase transition (T I ) in all thermal expansion coefficients a, b, and c. The spontaneous strains χ as and χ bs along the a and b axes show linear temperature dependence, while the spontaneous strain χ cs along the c axis shows a nonlinear temperature dependence. Small discontinuity along the c direction was observed at the incommensurate-commensurate transition temperature, T c = 845 C. dT I /dP and dT c /dP depend on the cooling rate
International Nuclear Information System (INIS)
Khattab, K.; Khamis, I.
2007-01-01
Measurement of the thermal self shielding coefficient ( Gth ) in the Syrian Miniature Neutron Source Reactor (MNSR) inner irradiation site using Dy foils is presented in this paper. The thermal self shielding coefficient is measured as a function of the foil thickness or numbers. The mathematical equation which calculates the average relative radioactivity (Bq/g) versus the foil number is found as well.
Study for discharge coefficient of flow nozzles. Prediction by using numerical simulation
International Nuclear Information System (INIS)
Ikeda, Hiroshi; Sakai, Norio; Yamamoto, Yasushi; Arai, Kenji; Matsumoto, Masaaki
2008-01-01
In nuclear plant, as water feeding into reactor have much effect on thermal power of plant, it is important to measure accurately the flow rate of water. Flow nozzle is on of typical differential pressure type flow meters and the discharge coefficient is used to calculate the flow rate. This coefficient is given by actual experiment and theory. We studied the theoretical assumption of the discharge coefficient curve using numerical simulation and evaluated the effect of flow nozzle configuration on the coefficient numerically and experimentally. As the result, numerical simulation can predict the discharge coefficient of theoretical curve within 0.3%. And we found that the throat length and throat tapping location of flow nozzle have much effect on the coefficient. (author)
International Nuclear Information System (INIS)
Um, Dall Sun
2004-01-01
In real design of the high and interim pressure turbine casing, it is one of the important things to figure out its thermal strain exactly. In this paper, with the establishment of the new concept for the heat transfer coefficient of steam that is one of the factors in analysis of the thermal stress for turbine casing, an analysis was done for one of the high and interim pressure turbine casings in operating domestically. The sensitivity analysis of the heat transfer coefficient of steam to the thermal strain of the turbine casing was done with a 2-D simple model. The analysis was also done with switching of the material properties of the turbine casing and resulted in that the thermal strain of the turbine casing was not so sensitive to the heat transfer coefficient of steam. On the basis of this, 3-D analysis of the thermal strain for the high and interim pressure turbine casing was done
Rate coefficients of open shell molecules and radicals: R-matrix ...
Indian Academy of Sciences (India)
2017-04-07
Apr 7, 2017 ... Rate coefficients of open shell molecules and radicals: R-matrix method. JASMEET SINGH1 ... lasers, study of structure of DNA and astrophysics which require a ..... [6] CCPForge, http://ccpforge.cse.rl.ac.uk/projects/ukrmol-in/.
American Society for Testing and Materials. Philadelphia
2008-01-01
1.1 The purpose of this test method is to define a general procedure for determining an unknown thermal-neutron fluence rate by neutron activation techniques. It is not practicable to describe completely a technique applicable to the large number of experimental situations that require the measurement of a thermal-neutron fluence rate. Therefore, this method is presented so that the user may adapt to his particular situation the fundamental procedures of the following techniques. 1.1.1 Radiometric counting technique using pure cobalt, pure gold, pure indium, cobalt-aluminum, alloy, gold-aluminum alloy, or indium-aluminum alloy. 1.1.2 Standard comparison technique using pure gold, or gold-aluminum alloy, and 1.1.3 Secondary standard comparison techniques using pure indium, indium-aluminum alloy, pure dysprosium, or dysprosium-aluminum alloy. 1.2 The techniques presented are limited to measurements at room temperatures. However, special problems when making thermal-neutron fluence rate measurements in high-...
Transitions in genetic toggle switches driven by dynamic disorder in rate coefficients
International Nuclear Information System (INIS)
Chen, Hang; Thill, Peter; Cao, Jianshu
2016-01-01
In biochemical systems, intrinsic noise may drive the system switch from one stable state to another. We investigate how kinetic switching between stable states in a bistable network is influenced by dynamic disorder, i.e., fluctuations in the rate coefficients. Using the geometric minimum action method, we first investigate the optimal transition paths and the corresponding minimum actions based on a genetic toggle switch model in which reaction coefficients draw from a discrete probability distribution. For the continuous probability distribution of the rate coefficient, we then consider two models of dynamic disorder in which reaction coefficients undergo different stochastic processes with the same stationary distribution. In one, the kinetic parameters follow a discrete Markov process and in the other they follow continuous Langevin dynamics. We find that regulation of the parameters modulating the dynamic disorder, as has been demonstrated to occur through allosteric control in bistable networks in the immune system, can be crucial in shaping the statistics of optimal transition paths, transition probabilities, and the stationary probability distribution of the network.
Transitions in genetic toggle switches driven by dynamic disorder in rate coefficients
Energy Technology Data Exchange (ETDEWEB)
Chen, Hang, E-mail: hangchen@mit.edu; Thill, Peter; Cao, Jianshu [Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)
2016-05-07
In biochemical systems, intrinsic noise may drive the system switch from one stable state to another. We investigate how kinetic switching between stable states in a bistable network is influenced by dynamic disorder, i.e., fluctuations in the rate coefficients. Using the geometric minimum action method, we first investigate the optimal transition paths and the corresponding minimum actions based on a genetic toggle switch model in which reaction coefficients draw from a discrete probability distribution. For the continuous probability distribution of the rate coefficient, we then consider two models of dynamic disorder in which reaction coefficients undergo different stochastic processes with the same stationary distribution. In one, the kinetic parameters follow a discrete Markov process and in the other they follow continuous Langevin dynamics. We find that regulation of the parameters modulating the dynamic disorder, as has been demonstrated to occur through allosteric control in bistable networks in the immune system, can be crucial in shaping the statistics of optimal transition paths, transition probabilities, and the stationary probability distribution of the network.
International Nuclear Information System (INIS)
Chiu, C.
1981-01-01
Combustion Engineering Inc. designs its modern PWR reactor cores using open-core thermal-hydraulic methods where the mass, momentum and energy equations are solved in three dimensions (one axial and two lateral directions). The resultant fluid properties are used to compute the minimum Departure from Nuclear Boiling Ratio (DNBR) which ultimately sets the power capability of the core. The on-line digital monitoring and protection systems require a small fast-running algorithm of the design code. This paper presents two techniques used in the development of the on-line DNB algorithm. First, a three-dimensional transport coefficient model is introduced to radially group the flow subchannel into channels for the thermal-hydraulic fluid properties calculation. Conservation equations of mass, momentum and energy for this channels are derived using transport coefficients to modify the calculation of the radial transport of enthalpy and momentum. Second, a simplified, non-iterative numerical method, called the prediction-correction method, is applied together with the transport coefficient model to reduce the computer execution time in the determination of fluid properties. Comparison of the algorithm and the design thermal-hydraulic code shows agreement to within 0.65% equivalent power at a 95/95 confidence/probability level for all normal operating conditions of the PWR core. This algorithm accuracy is achieved with 1/800th of the computer processing time of its parent design code. (orig.)
The 95% confidence intervals of error rates and discriminant coefficients
Directory of Open Access Journals (Sweden)
Shuichi Shinmura
2015-02-01
Full Text Available Fisher proposed a linear discriminant function (Fisher’s LDF. From 1971, we analysed electrocardiogram (ECG data in order to develop the diagnostic logic between normal and abnormal symptoms by Fisher’s LDF and a quadratic discriminant function (QDF. Our four years research was inferior to the decision tree logic developed by the medical doctor. After this experience, we discriminated many data and found four problems of the discriminant analysis. A revised Optimal LDF by Integer Programming (Revised IP-OLDF based on the minimum number of misclassification (minimum NM criterion resolves three problems entirely [13, 18]. In this research, we discuss fourth problem of the discriminant analysis. There are no standard errors (SEs of the error rate and discriminant coefficient. We propose a k-fold crossvalidation method. This method offers a model selection technique and a 95% confidence intervals (C.I. of error rates and discriminant coefficients.
Zero and low coefficient of thermal expansion polycrystalline oxides
International Nuclear Information System (INIS)
Skaggs, S.R.
1977-09-01
Polycrystalline oxide systems with zero to low coefficient of thermal expansion (CTE) investigated by the author include hafnia-titania and hafnia. The CTE for 30 to 40 mol% TiO 2 in HfO 2 is less than or equal to 1 x 10 -6 / 0 C, while for other compositions in the range 25 to 60 mol% it is approximately 4 x 10 -6 / 0 C. An investigation of the CTE of 99.999% HfO 2 yielded a value of 4.6 x 10 -6 / 0 C from room temperature to 1000 0 C. Correlation with data on HfO 2 by other investigators shows a definite relationship between the CTE and the amount of ZrO 2 present. Data are listed for comparison of the CTE of several other polycrystalline oxides investigated by Holcombe at Oak Ridge
Zero and low coefficient of thermal expansion polycrystalline oxides
International Nuclear Information System (INIS)
Skaggs, S.R.
1977-01-01
Polycrystalline oxide systems with zero to low coefficient of thermal expansion (CTE) investigated by the author include hafnia-titania and hafnia. The CTE for 30 to 40 mol percent TiO 2 in HfO 2 is less than or equal to 1 x 10 -6 / 0 C, while for other compositions in the range 25 to 60 mol percent approximately 4 x 10 -6 / 0 C. An investigation of the CTE of 99.999 percent HfO 2 yielded a value of 4.6 x 10 -6 / 0 C from room temperature to 1000 0 C. Correlation with data on HfO 2 by other investigators shows a definite relationship between the CTE and the amount of ZrO 2 present. Data are listed for comparison of the CTE of several other polycrystalline oxides investigated by Holcombe at Oak Ridge
Chung, Sang K.; Thiessen, David B.; Rhim, Won-Kyu
1996-01-01
A noncontact measurement technique for the density and the thermal expansion refractory materials in their molten as well as solid phases is presented. This technique is based on the video image processing of a levitated sample. Experiments were performed using the high-temperature electrostatic levitator (HTESL) at the Jet Propulsion Laboratory in which 2-3 mm diameter samples can be levitated, melted, and radiatively cooled in a vacuum. Due to the axisymmetric nature of the molten samples when levitated in the HTESL, a rather simple digital image analysis can be employed to accurately measure the volumetric change as a function of temperature. Density and the thermal expansion coefficient measurements were made on a pure nickel sample to test the accuracy of the technique in the temperature range of 1045-1565 C. The result for the liquid phase density can be expressed by p = 8.848 + (6.730 x 10(exp -4)) x T (degC) g/cu cm within 0.8% accuracy, and the corresponding thermal expansion coefficient can be expressed by Beta=(9.419 x 10(exp -5)) - (7.165 x 10(exp -9) x T (degC)/K within 0.2% accuracy.
Study of transport coefficients of nanodiamond nanofluids
Pryazhnikov, M. I.; Minakov, A. V.; Guzei, D. V.
2017-09-01
Experimental data on the thermal conductivity coefficient and viscosity coefficient of nanodiamond nanofluids are presented. Distilled water and ethylene glycol were used as the base fluid. Dependences of transport coefficients on concentration are obtained. It was shown that the thermal conductivity coefficient increases with increasing nanodiamonds concentration. It was shown that base fluids properties and nanodiamonds concentration affect on the rheology of nanofluids.
Direct access to dithiobenzoate RAFT agent fragmentation rate coefficients by ESR spin-trapping.
Ranieri, Kayte; Delaittre, Guillaume; Barner-Kowollik, Christopher; Junkers, Thomas
2014-12-01
The β-scission rate coefficient of tert-butyl radicals fragmenting off the intermediate resulting from their addition to tert-butyl dithiobenzoate-a reversible addition-fragmentation chain transfer (RAFT) agent-is estimated via the recently introduced electron spin resonance (ESR)-trapping methodology as a function of temperature. The newly introduced ESR-trapping methodology is critically evaluated and found to be reliable. At 20 °C, a fragmentation rate coefficient of close to 0.042 s(-1) is observed, whereas the activation parameters for the fragmentation reaction-determined for the first time-read EA = 82 ± 13.3 kJ mol(-1) and A = (1.4 ± 0.25) × 10(13) s(-1) . The ESR spin-trapping methodology thus efficiently probes the stability of the RAFT adduct radical under conditions relevant for the pre-equilibrium of the RAFT process. It particularly indicates that stable RAFT adduct radicals are indeed formed in early stages of the RAFT poly-merization, at least when dithiobenzoates are employed as controlling agents as stipulated by the so-called slow fragmentation theory. By design of the methodology, the obtained fragmentation rate coefficients represent an upper limit. The ESR spin-trapping methodology is thus seen as a suitable tool for evaluating the fragmentation rate coefficients of a wide range of RAFT adduct radicals. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Energy Technology Data Exchange (ETDEWEB)
Kato, T.; Asano, E. [National Institute for Fusion Science, Toki, Gifu (Japan)
1999-06-01
Recombination rate coefficients based on several empirical formulae are compared for ions of H, He, C, N, O, Ne, Na, Mg, Al, Si, S, P, Cl, Ar, Ca, Fe and Ni. The total rate coefficients including radiative recombination and dielectronic recombination are shown in graphs. (author)
Virtual thermal expansion coefficient of Cu precipitated in the Fe95Cu5 alloy
International Nuclear Information System (INIS)
Koeszegi, L.; Somogyvari, Z.
1999-01-01
Complete text of publication follows. Precipitations on grain boundaries play very important role in the formation of material's characteristics like embrittlement, durability etc. It was already shown [1] that Cu precipitations are under different stress conditions than the bulk material. The situation is more complicated in the case when a construction is exposed to temperature changes as well. In that case not only the residual stresses during the fabrication but the different thermal expansion coefficients can produce additional problems. This situation was modelled using Fe 95 Cu 5 alloy where Cu precipitates on the grain boundaries. The alloy was produced by high-frequency melting and an extra heat treatment was used to produce a quasi-equilibrium state. Pure Cu was also measured to compare the behaviours. Cu(111) Bragg peak was measured at different temperatures by high resolution neutron diffraction. The measurements were carried out on the G5-2 spectrometer at LLB in Saclay. Measurements show that not only residual stress can be recognised on the Cu precipitates but the thermal expansion coefficient of these precipitates definitly differ from the ones of pure Cu. (author)
A thermal transport coefficient for ohmic and ICRF plasmas in alcator C-mode
International Nuclear Information System (INIS)
Daughton, W.; Coppi, B.; Greenwald, M.
1996-01-01
The energy confinement in plasmas produced by Alcator C-Mod machine is markedly different from that observed by previous high field compact machines such as Alcator A and C, FT, and more recently FTU. For ohmic plasmas at low and moderate densities, the confinement times routinely exceed those expected from the so-called open-quotes neo-Alcatorclose quotes scaling by a factor as high as three. For both ohmic and ICRF heated plasmas, the energy confinement time increases with the current and is approximately independent of the density. The similarity in the confinement between the ohmic and ICRF regimes opens the possibility that the thermal transport in Alcator C-Mod may be described by one transport coefficient for both regimes. We introduce a modified form of a transport coefficient previously used to describe ohmic plasmas in Alcator C-Mod. The coefficient is inspired by the properties of the so-called open-quotes ubiquitousclose quotes mode that can be excited in the presence of a significant fraction of trapped electrons and also includes the constraint of profile consistency. A detailed series of transport simulations are used to show that the proposed coefficient can reproduce the observed temperature profiles, loop voltage and energy confinement time for both ohmic and ICRF discharges. A total of nearly two dozen ohmic and ICRF Alcator C-Mod discharges have been fit over the range of parameter space available using this transport coefficient
Automatic estimation of pressure-dependent rate coefficients.
Allen, Joshua W; Goldsmith, C Franklin; Green, William H
2012-01-21
A general framework is presented for accurately and efficiently estimating the phenomenological pressure-dependent rate coefficients for reaction networks of arbitrary size and complexity using only high-pressure-limit information. Two aspects of this framework are discussed in detail. First, two methods of estimating the density of states of the species in the network are presented, including a new method based on characteristic functional group frequencies. Second, three methods of simplifying the full master equation model of the network to a single set of phenomenological rates are discussed, including a new method based on the reservoir state and pseudo-steady state approximations. Both sets of methods are evaluated in the context of the chemically-activated reaction of acetyl with oxygen. All three simplifications of the master equation are usually accurate, but each fails in certain situations, which are discussed. The new methods usually provide good accuracy at a computational cost appropriate for automated reaction mechanism generation.
Automatic estimation of pressure-dependent rate coefficients
Allen, Joshua W.; Goldsmith, C. Franklin; Green, William H.
2012-01-01
A general framework is presented for accurately and efficiently estimating the phenomenological pressure-dependent rate coefficients for reaction networks of arbitrary size and complexity using only high-pressure-limit information. Two aspects of this framework are discussed in detail. First, two methods of estimating the density of states of the species in the network are presented, including a new method based on characteristic functional group frequencies. Second, three methods of simplifying the full master equation model of the network to a single set of phenomenological rates are discussed, including a new method based on the reservoir state and pseudo-steady state approximations. Both sets of methods are evaluated in the context of the chemically-activated reaction of acetyl with oxygen. All three simplifications of the master equation are usually accurate, but each fails in certain situations, which are discussed. The new methods usually provide good accuracy at a computational cost appropriate for automated reaction mechanism generation. This journal is © the Owner Societies.
Gijsbertsen, A.; Bicanic, D.; Gielen, J. L. W.; Chirtoc, M.
2004-03-01
CO 2-laser photothermal radiometry (PTR) was demonstrated to be suitable for the non-destructive and non-contact characterization (both optical and thermal) of solid phase agricultural commodities (fresh vegetables, fruits) and confectionery products (candy). Proper interpretation of PTR signals enable one to calculate two parameters, i.e. the well known thermal effusivity e ( e= λρc p, where λ and ρcp are the thermal conductivity and the volume specific heat, respectively) and a newly introduced physical quantity termed 'initial heating coefficient' chi ( χ= β/( ρcp), β is the absorption coefficient). Obtained values for e are in a good agreement with data reported in the literature. PTR enables one to rapidly determine e via a single measurement. As opposed to this, the knowledge of two out of three thermophysical parameters (thermal diffusivity, thermal conductivity and volume specific heat) is a condition sine qua non for determining effusivity in the conventional manner.
International Nuclear Information System (INIS)
Sharma, Rohit; Singh, Kuldip
2014-01-01
In the present work, two cases of thermal plasma have been considered; the ground state plasma in which all the atoms and ions are assumed to be in the ground state and the excited state plasma in which atoms and ions are distributed over various possible excited states. The variation of Zγ, frozen isentropic coefficient and the isentropic coefficient with degree of ionization and non-equilibrium parameter θ(= T e /T h ) has been investigated for the ground and excited state helium and argon plasmas at pressures 1 atm, 10 atm, and 100 atm in the temperature range from 6000 K to 60 000 K. For a given value of non-equilibrium parameter, the relationship of Zγ with degree of ionization does not show any dependence on electronically excited states in helium plasma whereas in case of argon plasma this dependence is not appreciable till degree of ionization approaches 2. The minima of frozen isentropic coefficient shifts toward lower temperature with increase of non-equilibrium parameter for both the helium and argon plasmas. The lowering of non-equilibrium parameter decreases the frozen isentropic coefficient more emphatically in helium plasma at high pressures in comparison to argon plasma. The increase of pressure slightly reduces the ionization range over which isentropic coefficient almost remains constant and it does not affect appreciably the dependence of isentropic coefficient on non-equilibrium parameter
Bisetti, Fabrizio
2012-12-01
Simulations of ion and electron transport in flames routinely adopt plasma fluid models, which require transport coefficients to compute the mass flux of charged species. In this work, the mobility and diffusion coefficient of thermal electrons in atmospheric premixed methane/air flames are calculated and analyzed. The electron mobility is highest in the unburnt region, decreasing more than threefold across the flame due to mixture composition effects related to the presence of water vapor. Mobility is found to be largely independent of equivalence ratio and approximately equal to 0.4m 2V -1s -1 in the reaction zone and burnt region. The methodology and results presented enable accurate and computationally inexpensive calculations of transport properties of thermal electrons for use in numerical simulations of charged species transport in flames. © 2012 The Combustion Institute.
International Nuclear Information System (INIS)
Petrov, K.; Will, G.
1981-01-01
High-temperature treatment of tungsten carbide-cobalt hard alloys in TiB 2 media leads to the formation of a surface diffusion coating which contains orthorhombic WCoB. The function of this compound in enhancing wear resistance of cutting tools, is discussed. The thermal expansion of WCoB is of primary interest, since the wear resistance of the coating reflects the degree of matching of the thermal expansion coefficients of the different phases. Preparation of the samples is described and experimental details of the X-ray diffraction measurements are given. The temperature dependence of the lattice parameters for the range 300 to 973 K, and the corresponding linear thermal expansion coefficients along the three principal crystallographic directions, are given. The results are discussed in terms of the bonding features of the solid. (U.K.)
Yamaguchi, H.; Takamori, K.; Perrier, P.; Graur, I.; Matsuda, Y.; Niimi, T.
2016-09-01
The viscous slip coefficient for helium-argon binary gas mixture is extracted from the experimental values of the mass flow rate through a microtube. The mass flow rate is measured by the constant-volume method. The viscous slip coefficient was obtained by identifying the measured mass flow rate through a microtube with the corresponding analytical expression, which is a function of the Knudsen number. The measurements were carried out in the slip flow regime where the first-order slip boundary condition can be applied. The measured viscous slip coefficients of binary gas mixtures exhibit a concave function of the molar ratio of the mixture, showing a similar profile with numerical results. However, from the detailed comparison between the measured and numerical values with the complete and incomplete accommodation at a surface, it is inappropriate to estimate the viscous slip coefficient for the mixture numerically by employing separately measured tangential momentum accommodation coefficient for each component. The time variation of the molar ratio in the downstream chamber was measured by sampling the gas from the chamber using the quadrupole mass spectrometer. In our measurements, it is indicated that the volume flow rate of argon is larger than that of helium because of the difference in the tangential momentum accommodation coefficient.
Tien, Chuen-Lin; Lin, Tsai-Wei
2012-10-20
We present a new method based on fast Fourier transform (FFT) for evaluating the thermal expansion coefficient and thermomechanical properties of thin films. The silicon nitride thin films deposited on Corning glass and Si wafers were prepared by plasma-enhanced chemical vapor deposition in this study. The anisotropic residual stress and thermomechanical properties of silicon nitride thin films were studied. Residual stresses in thin films were measured by a modified Michelson interferometer associated with the FFT method under different heating temperatures. We found that the average residual-stress value increases when the temperature increases from room temperature to 100°C. Increased substrate temperature causes the residual stress in SiN(x) film deposited on Si wafers to be more compressive, but the residual stress in SiN(x) film on Corning glass becomes more tensile. The residual-stress versus substrate-temperature relation is a linear correlation after heating. A double substrate technique is used to determine the thermal expansion coefficients of the thin films. The experimental results show that the thermal expansion coefficient of the silicon nitride thin films is 3.27×10(-6)°C(-1). The biaxial modulus is 1125 GPa for SiN(x) film.
Electron-impact excitation rate-coefficients and polarization of subsequent emission for Ar"+ ion
International Nuclear Information System (INIS)
Dipti; Srivastava, Rajesh
2016-01-01
Electron impact excitation in Ar"+ ions has been studied by using fully relativistic distorted wave theory. Calculations are performed to obtain the excitation cross-sections and rate-coefficients for the transitions from the ground state 3p"5 (J=3/2) to fine-structure levels of excited states 3p"44s, 3p"44p, 3p"45s, 3p"45p, 3p"43d and 3p"44d. Polarization of the radiation following the excitation has been calculated using the obtained magnetic sub-level cross-sections. Comparison of the present rate-coefficients is also done with the previously reported theoretical results for some unresolved fine structure transitions. - Highlights: • Fully relativistic distorted wave theory has been used to study the excitation of fine-structure states of Ar"+. • We have calculated electron-impact excitation cross-sections for the wide range of incident electron energies. • Electron impact excitation rate-coefficients are calculated as a function of electron temperature. • Polarization of photons emitted following the decay of the excited fine-structure states are also reported.
Zawawi, N. N. M.; Azmi, W. H.; Redhwan, A. A. M.; Sharif, M. Z.
2017-10-01
Wear of sliding parts and operational machine consistency enhancement can be avoided with good lubrication. Lubrication reduce wear between two contacting and sliding surfaces and decrease the frictional power losses in compressor. The coefficient of friction and wear rate effects study were carried out to measure the friction and anti-wear abilities of Al2O3-SiO2 composite nanolubricants a new type of compressor lubricant to enhanced the compressor performances. The tribology test rig employing reciprocating test conditions to replicate a piston ring contact in the compressor was used to measure the coefficient of friction and wear rate. Coefficient of friction and wear rate effects of different Al2O3-SiO2/PAG composite nanolubricants of Aluminium 2024 plate for 10-kg load at different speed were investigated. Al2O3 and SiO2 nanoparticles were dispersed in the Polyalkylene Glycol (PAG 46) lubricant using two-steps method of preparation. The result shows that the coefficient friction and wear rate of composite nanolubricants decreased compared to pure lubricant. The maximum reduction achievement for friction of coefficient and wear rate by Al2O3-SiO2 composite nanolubricants by 4.78% and 12.96% with 0.06% volume concentration. Therefore, 0.06% volume concentration is selected as the most enhanced composite nanolubricants with effective coefficient of friction and wear rate reduction compared to other volume concentrations. Thus, it is recommended to be used as the compressor lubrication to enhanced compressor performances.
International Nuclear Information System (INIS)
Banerjee, S.; Hassan, Y.A.
1995-01-01
Condensation in the presence of noncondensible gases plays an important role in the nuclear industry. The RELAP5/MOD3 thermal hydraulic code was used to study the ability of the code to predict this phenomenon. Two separate effects experiments were simulated using this code. These were the Massachusetts Institute of Technology's (MIT) Pressurizer Experiment, the MIT Single Tube Experiment. A new iterative approach to calculate the interface temperature and the degraded heat transfer coefficient was developed and implemented in the RELAP5/MOD3 thermal hydraulic code. This model employs the heat transfer simultaneously. This model was found to perform much better than the reduction factor approach. The calculations using the new model were found to be in much better agreement with the experimental values
Energy Technology Data Exchange (ETDEWEB)
Banerjee, S.; Hassan, Y.A. [Texas A& M Univ., College Station, TX (United States)
1995-09-01
Condensation in the presence of noncondensible gases plays an important role in the nuclear industry. The RELAP5/MOD3 thermal hydraulic code was used to study the ability of the code to predict this phenomenon. Two separate effects experiments were simulated using this code. These were the Massachusetts Institute of Technology`s (MIT) Pressurizer Experiment, the MIT Single Tube Experiment. A new iterative approach to calculate the interface temperature and the degraded heat transfer coefficient was developed and implemented in the RELAP5/MOD3 thermal hydraulic code. This model employs the heat transfer simultaneously. This model was found to perform much better than the reduction factor approach. The calculations using the new model were found to be in much better agreement with the experimental values.
International Nuclear Information System (INIS)
Haggerty, R.; Schroth, M.H.; Istok, J.D.
1998-01-01
The single-well, ''''push-pull'''' test method is useful for obtaining information on a wide variety of aquifer physical, chemical, and microbiological characteristics. A push-pull test consists of the pulse-type injection of a prepared test solution into a single monitoring well followed by the extraction of the test solution/ground water mixture from the same well. The test solution contains a conservative tracer and one or more reactants selected to investigate a particular process. During the extraction phase, the concentrations of tracer, reactants, and possible reaction products are measured to obtain breakthrough curves for all solutes. This paper presents a simplified method of data analysis that can be used to estimate a first-order reaction rate coefficient from these breakthrough curves. Rate coefficients are obtained by fitting a regression line to a plot of normalized concentrations versus elapsed time, requiring no knowledge of aquifer porosity, dispersivity, or hydraulic conductivity. A semi-analytical solution to the advective-dispersion equation is derived and used in a sensitivity analysis to evaluate the ability of the simplified method to estimate reaction rate coefficients in simulated push-pull tests in a homogeneous, confined aquifer with a fully-penetrating injection/extraction well and varying porosity, dispersivity, test duration, and reaction rate. A numerical flow and transport code (SUTRA) is used to evaluate the ability of the simplified method to estimate reaction rate coefficients in simulated push-pull tests in a heterogeneous, unconfined aquifer with a partially penetrating well. In all cases the simplified method provides accurate estimates of reaction rate coefficients; estimation errors ranged from 0.1 to 8.9% with most errors less than 5%
Wearable Sweat Rate Sensors for Human Thermal Comfort Monitoring.
Sim, Jai Kyoung; Yoon, Sunghyun; Cho, Young-Ho
2018-01-19
We propose watch-type sweat rate sensors capable of automatic natural ventilation by integrating miniaturized thermo-pneumatic actuators, and experimentally verify their performances and applicability. Previous sensors using natural ventilation require manual ventilation process or high-power bulky thermo-pneumatic actuators to lift sweat rate detection chambers above skin for continuous measurement. The proposed watch-type sweat rate sensors reduce operation power by minimizing expansion fluid volume to 0.4 ml through heat circuit modeling. The proposed sensors reduce operation power to 12.8% and weight to 47.6% compared to previous portable sensors, operating for 4 hours at 6 V batteries. Human experiment for thermal comfort monitoring is performed by using the proposed sensors having sensitivity of 0.039 (pF/s)/(g/m 2 h) and linearity of 97.9% in human sweat rate range. Average sweat rate difference for each thermal status measured in three subjects shows (32.06 ± 27.19) g/m 2 h in thermal statuses including 'comfortable', 'slightly warm', 'warm', and 'hot'. The proposed sensors thereby can discriminate and compare four stages of thermal status. Sweat rate measurement error of the proposed sensors is less than 10% under air velocity of 1.5 m/s corresponding to human walking speed. The proposed sensors are applicable for wearable and portable use, having potentials for daily thermal comfort monitoring applications.
Derivation of the chemical-equilibrium rate coefficient using scattering theory
Mickens, R. E.
1977-01-01
Scattering theory is applied to derive the equilibrium rate coefficient for a general homogeneous chemical reaction involving ideal gases. The reaction rate is expressed in terms of the product of a number of normalized momentum distribution functions, the product of the number of molecules with a given internal energy state, and the spin-averaged T-matrix elements. An expression for momentum distribution at equilibrium for an arbitrary molecule is presented, and the number of molecules with a given internal-energy state is represented by an expression which includes the partition function.
Cho, M; Jang, J; Suhr, J
2011-02-01
This study involves the investigation of the geometry effect of nano-fillers on thermally induced dimensional stability of epoxy composites by experimentally evaluating the linear coefficient of thermal expansion (CTE). Carbon nanofibers (CNF) were chosen as the filler in epoxy matrix to investigate the effect of an aspect ratio on the CTE of the nanocomposites at three different volume fractions of 0.5, 1, and 2% of the nano-filler. The composites were fabricated using a mechanical mixing method. The CTE values were evaluated by measuring thermal strains of the composites and also compared with a micromechanics model. It was observed that the composites with short CNF (average L/d = 10) show better thermal stability than one of the composites with long CNF (average L/d = 70), and the thermal stability of the composites was proportional to the volume fraction of the filler in each composite. In addition, the CTE of mutliwalled carbon nanotubes (MWNT) reinforced epoxy composites was evaluated and compared with the CTE of the CNF reinforced composites. Interestingly, the MWNT reinforced composites show the greatest thermal stability with an 11.5% reduction in the CTE over the pure epoxy. The experimental data was compared with micromechanics model.
Cooling load and coefficient of performance optimizations for real air-refrigerators
International Nuclear Information System (INIS)
Tu Youming; Chen Lingen; Sun Fengrui; Wu Chih
2006-01-01
Based on a simple irreversible variable-temperature heat reservoir air (Brayton) refrigeration cycle model, a performance analysis and optimization of a real air refrigerator is carried out using finite-time thermodynamics. To maximize the cooling load and the coefficient of performance (COP) of the cycle, the allocation of a fixed total heat-exchanger inventory and thermal-capacity rate matching between the working fluid and heat reservoirs are optimized, respectively. The influences of pressure ratio, the total heat-exchanger inventory, the efficiencies of the compressor and expander, the thermal capacity rate of the working fluid and the ratio of the thermal-capacity rates of the heat reservoirs on the performance of the cycle are shown by numerical examples. The results obtained provide guidances for the design of practical air-refrigeration plants
Energy Technology Data Exchange (ETDEWEB)
Bennion, Kevin; Moreno, Gilberto
2015-09-29
Thermal management for electric machines (motors/ generators) is important as the automotive industry continues to transition to more electrically dominant vehicle propulsion systems. Cooling of the electric machine(s) in some electric vehicle traction drive applications is accomplished by impinging automatic transmission fluid (ATF) jets onto the machine's copper windings. In this study, we provide the results of experiments characterizing the thermal performance of ATF jets on surfaces representative of windings, using Ford's Mercon LV ATF. Experiments were carried out at various ATF temperatures and jet velocities to quantify the influence of these parameters on heat transfer coefficients. Fluid temperatures were varied from 50 degrees C to 90 degrees C to encompass potential operating temperatures within an automotive transaxle environment. The jet nozzle velocities were varied from 0.5 to 10 m/s. The experimental ATF heat transfer coefficient results provided in this report are a useful resource for understanding factors that influence the performance of ATF-based cooling systems for electric machines.
Hintz, Paul A.; Ervin, Kent M.
1994-04-01
Reactions of Ni-n(n=3-10), Pd-n(n=3-8), and Pt-n(n=3-7) with CO are studied in a flow tube reactor. Bimolecular rate coefficients are measured for the association reaction of CO adsorbing on the cluster surface. The rate coefficients range from about 10% of the collision rate for the trimer anions to near the collision rate for clusters larger than four atoms. The maximum number of CO molecules that bind to each cluster is determined. Whereas the saturation limits for nickel are typical for an 18 electron transition metal, the limits for platinum are lower, reflecting the electron deficient structures observed in condensed phase chemistry. The CO saturated palladium clusters represent the first examples of saturated binary palladium carbonyl compounds. Comparisons are made to similar studies on metal cation and neutral clusters and also to surface scattering studies of nickel group metals.
Status of rates and rate equations for thermal leptogenesis
Biondini, S.; Bödeker, D.; Brambilla, N.; Garny, M.; Ghiglieri, J.; Hohenegger, A.; Laine, M.; Mendizabal, S.; Millington, P.; Salvio, A.; Vairo, A.
2018-02-01
In many realizations of leptogenesis, heavy right-handed neutrinos play the main role in the generation of an imbalance between matter and antimatter in the early Universe. Hence, it is relevant to address quantitatively their dynamics in a hot and dense environment by taking into account the various thermal aspects of the problem at hand. The strong washout regime offers an interesting framework to carry out calculations systematically and reduce theoretical uncertainties. Indeed, any matter-antimatter asymmetry generated when the temperature of the hot plasma T exceeds the right-handed neutrino mass scale M is efficiently erased, and one can focus on the temperature window T ≪ M. We review recent progress in the thermal field theoretic derivation of the key ingredients for the leptogenesis mechanism: the right-handed neutrino production rate, the CP asymmetry in the heavy-neutrino decays and the washout rates. The derivation of evolution equations for the heavy-neutrino and lepton-asymmetry number densities, their rigorous formulation and applicability are also discussed.
Temperature-Dependent Rate Coefficients for the Reaction of CH2OO with Hydrogen Sulfide.
Smith, Mica C; Chao, Wen; Kumar, Manoj; Francisco, Joseph S; Takahashi, Kaito; Lin, Jim Jr-Min
2017-02-09
The reaction of the simplest Criegee intermediate CH 2 OO with hydrogen sulfide was measured with transient UV absorption spectroscopy in a temperature-controlled flow reactor, and bimolecular rate coefficients were obtained from 278 to 318 K and from 100 to 500 Torr. The average rate coefficient at 298 K and 100 Torr was (1.7 ± 0.2) × 10 -13 cm 3 s -1 . The reaction was found to be independent of pressure and exhibited a weak negative temperature dependence. Ab initio quantum chemistry calculations of the temperature-dependent reaction rate coefficient at the QCISD(T)/CBS level are in reasonable agreement with the experiment. The reaction of CH 2 OO with H 2 S is 2-3 orders of magnitude faster than the reaction with H 2 O monomer. Though rates of CH 2 OO scavenging by water vapor under atmospheric conditions are primarily controlled by the reaction with water dimer, the H 2 S loss pathway will be dominated by the reaction with monomer. The agreement between experiment and theory for the CH 2 OO + H 2 S reaction lends credence to theoretical descriptions of other Criegee intermediate reactions that cannot easily be probed experimentally.
International Nuclear Information System (INIS)
Cheng, Wen-long; Yuan, Shuai; Song, Jia-liang
2014-01-01
PTC (positive temperature coefficient) material is a kind of thermo-sensitive material. In this study, a series of novel PTC materials adapted to thermal control of electron devices are prepared. By adding different low-melting-point blend matrixes into GP (graphite powder)/LDPE (low density polyethylene) composite, the Curie temperatures are adjusted to 9 °C, 25 °C, 34 °C and 41 °C, and the resistance–temperature coefficients are enhanced to 1.57/°C–2.15/°C. These PTC materials remain solid in the temperature region of PTC effect, which makes it possible to be used as heating element to achieve adaptive temperature control. In addition, the adaptive thermal control performances of this kind of materials are investigated both experimentally and theoretically. The result shows that the adaptive effect becomes more significant while the resistance–temperature coefficient increases. A critical heating power defined as the initial heating power which makes the equilibrium temperature reach terminal temperature is presented. The adaptive temperature control will be effective only if the initial power is below this value. The critical heating power is determined by the Curie temperature and resistance–temperature coefficient of PTC materials, and a higher Curie temperature or resistance–temperature coefficient will lead to a larger critical heating power. - Highlights: • A series of novel PTC (positive temperature coefficient) materials were prepared. • The Curie point of PTC material can be adjusted by choosing different blend matrixes. • The resistance–temperature coefficient of PTC materials is enhanced to 2.15/°C. • The material has good adaptive temperature control ability with no auxiliary method. • A mathematical model is established to analyze the performance and applicability
Yamaguchi, H.; Takamori, K.; Perrier, P.; Graur, I.; Matsuda, Y.; Niimi, T.
2016-01-01
The viscous slip coefficient for helium-argon binary gas mixture is extracted from the experimental values of the mass flow rate through a microtube. The mass flow rate is measured by the constant-volume method. The viscous slip coefficient was obtained by identifying the measured mass flow rate through a microtube with the corresponding analytical expression, which is a function of the Knudsen number. The measurements were carried out in the slip flow regime where the first-order slip bounda...
Directory of Open Access Journals (Sweden)
Naoki Yamamoto
2011-01-01
Full Text Available A new technique for measuring Young's modulus of an ultra-thin film, with a thickness in the range of about 10 nm, was developed by combining an optical lever technique for measuring the residual stress and X-ray diffraction for measuring the strain in the film. The new technique was applied to analyze the mechanical properties of Ga-doped ZnO (GZO films, that have become the focus of significant attention as a substitute material for indium-tin-oxide transparent electrodes. Young's modulus of the as-deposited GZO films decreased with thickness; the values for 30 nm and 500 nm thick films were 205 GPa and 117 GPa, respectively. The coefficient of linear thermal expansion of the GZO films was measured using the new technique in combination with in-situ residual stress measurement during heat-cycle testing. GZO films with 30–100 nm thickness had a coefficient of linear thermal expansion in the range of 4.3 × 10−6 – 5.6 × 10−6 °C−1.
International Nuclear Information System (INIS)
Baek, Seung Man; Nam, Jin Hyun; Hong, Hiki; Kim, Charn-Jung
2011-01-01
This study numerically investigates the effect of the brine flow rate on the thermal performance of a spiral-jacketed thermal storage tank (TST) installed in a solar domestic hot water (SDHW) system. The spiral-jacketed TST is a TST with a mantle heat exchanger, consisting of a vertical, cylindrical water tank for energy storage and a spiral brine flow path attached to the tank wall for heat transfer. A computational fluid dynamics (CFD) model was constructed based on the actual geometry of a spiral-jacketed TST. In addition, the boundary conditions were defined by considering solar radiation and ambient temperature data that were measured during experimental operation of the SDHW system. The numerical results demonstrated that an increase in the brine flow rate enhances the thermal efficiency of the TST due to higher heat transfer coefficients in the spiral path, and also leads to reduced thermal stratification in the TST. On the other hand, a lower brine flow rate increased the heat transfer rate at the inlet of the spiral path near the top of the TST, which resulted in enhanced thermal stratification. The optimal range for the rate of brine flow rate is discussed with respect to the thermal efficiency of the TST and the required pumping power for brine circulation in the spiral flow path. - Highlights: → A CFD model was developed for a spiral-jacketed thermal storage tank (TST) installed in a solar domestic hot water (SDHW) system. → Effects of brine flow rate on the overall performance of the spiral-jacketed TST were numerically investigated. → Higher brine flow rates slightly increased the solar energy acquired by the TST, but it also increased the pump power required to circulate the brine. → Lower brine flow rates were found to be a better option for the spiral-jacketed TST, by maximizing the exergy of the SDHW system.
International Nuclear Information System (INIS)
Noorddin Ibrahim; Rosnie Akang
2009-01-01
Full text: One of the major problems encountered during the irradiation of large inhomogeneous samples in performing activation analysis using neutron is the perturbation of the neutron field due to absorption and scattering of neutron within the sample as well as along the neutron guide in the case of prompt gamma activation analysis. The magnitude of this perturbation shown by self-shielding coefficient and flux depression depend on several factors including the average neutron energy, the size and shape of the sample, as well as the macroscopic absorption cross section of the sample. In this study, we use Monte Carlo N-Particle codes to simulate the variation of neutron self-shielding coefficient and thermal flux depression factor as a function of the macroscopic thermal absorption cross section. The simulation works was carried out using the high performance computing facility available at UTM while the experimental work was performed at the tangential beam port of Reactor TRIGA PUSPATI, Malaysia Nuclear Agency. The neutron flux measured along the beam port is found to be in good agreement with the simulated data. Our simulation results also reveal that total flux perturbation factor decreases as the value of absorption increases. This factor is close to unity for low absorbing sample and tends towards zero for strong absorber. In addition, sample with long mean chord length produces smaller flux perturbation than the shorter mean chord length. When comparing both the graphs of self-shielding factor and total disturbance, we can conclude that the total disturbance of the thermal neutron flux on the large samples is dominated by the self-shielding effect. (Author)
Thermal electron heating rate: a derivation
International Nuclear Information System (INIS)
Hoegy, W.R.
1983-11-01
The thermal electron heating rate is an important heat source term in the ionospheric electron energy balance equation, representing heating by photoelectrons or by precipitating higher energy electrons. A formula for the thermal electron heating rate is derived from the kinetic equation using the electron-electron collision operator as given by the unified theory of Kihara and Aono. This collision operator includes collective interactions to produce a finite collision operator with an exact Coulomb logarithm term. The derived heating rate O(e) is the sum of three terms, O(e) O(p) + S + O(int), which are respectively: (1) primary electron production term giving the heating from newly created electrons that have not yet suffered collisions with the ambient electrons, (2) a heating term evaluated on the energy surface m(e)/2 E(T) at the transition between Maxwellian and tail electrons at E(T), and (3) the integral term representing heating of Maxwellian electrons by energetic tail electrons at energies ET. Published ionospheric electron temperature studies used only the integral term O(int) with differing lower integration limits. Use of the incomplete heating rate could lead to erroneous conclusions regarding electron heat balance, since O(e) is greater than O(int) by as much as a factor of two
A Micro-Test Structure for the Thermal Expansion Coefficient of Metal Materials
Directory of Open Access Journals (Sweden)
Qingying Ren
2017-02-01
Full Text Available An innovative micro-test structure for detecting the thermal expansion coefficient (TEC of metal materials is presented in this work. Throughout this method, a whole temperature sensing moveable structures are supported by four groups of cascaded chevrons beams and packed together. Thermal expansion of the metal material causes the deflection of the cascaded chevrons, which leads to the capacitance variation. By detecting the capacitance value at different temperatures, the TEC value of the metal materials can be calculated. A finite element model has been established to verify the relationship between the TEC of the material and the displacement of the structure on horizontal and vertical directions, thus a function of temperature for different values of TEC can be deduced. In order to verify the analytical model, a suspended-capacitive micro-test structure has been fabricated by MetalMUMPs process and tested in a climate chamber. Test results show that in the temperature range from 30 °C to 80 °C, the TEC of the test material is 13.4 × 10−6 °C−1 with a maximum relative error of 0.8% compared with the given curve of relationship between displacement and temperature.
Dose Rate and Mass Attenuation Coefficients of Gamma Ray for Concretes
Abdel-Latif, A A; Kansouh, W A; El-Sayed, F H
2003-01-01
This work is concerned with the study of the leakage gamma ray dose and mass attenuation coefficients for ordinary, basalt and dolomite concretes made from local ores. Concretes under investigation were constructed from gravel, basalt and dolomite ores, and then reconstructed with the addition of 3% steel fibers by weight. Measurements were carried out using a collimated beam from sup 6 sup 0 Co gamma ray source and sodium iodide (3x3) crystal with the genie 2000 gamma spectrometer. The obtained fluxes were transformed to gamma ray doses and displayed in the form of gamma ray dose rates distribution. The displayed curves were used to estimate the linear attenuation coefficients (mu), the relaxation lengths (lambda), half value layer (t sub 1 /2) and tenth value layer (t sub 1 /10). Also, The total mass attenuation coefficients of gamma ray have been calculated to the concerned concretes using XCOM (version 3.1) program and database elements cross sections from Z=1 to 100 at energies from 10 keV to 100 MeV. In...
International Nuclear Information System (INIS)
Li, Cheng; Liu, Qianwen; Peng, Xiaobin; Fan, Shangchun
2016-01-01
Application of the Fabry–Perot (FP) interference method for determining the coefficient of thermal expansion (CTE) of a graphene diaphragm is investigated in this paper. A miniature extrinsic FP interferometric (EFPI) sensor was fabricated by using an approximate 8-layer graphene diaphragm. The extremely thin diaphragm was transferred onto the endface of a ferrule with an inner diameter of 125 μ m, and van der Waals interactions between the graphene diaphragm and its substrate created a low finesse FP interferometer with a cavity length of 36.13 μ m. Double reference FP cavities using two cleaved optical fibers as reflectors were also constructed to differentially cancel the thermal expansion effects of the trapped gas and adhesive material. A temperature test demonstrated an approximate cavity length change of 166.1 nm °C −1 caused by film thermal expansion in the range of 20–60 °C. Then along with the established thermal deformation model of the suspended circular diaphragm, the calculated CTE ranging from −9.98 × 10 −6 K −1 to −2.09 × 10 −6 K −1 conformed well to the previously measured results. The proposed method would be applicable in other types of elastic materials as the sensitive diaphragm of an EFPI sensor over a wide temperature range. (paper)
Directory of Open Access Journals (Sweden)
Shim S.M.
2012-01-01
Full Text Available The performance of the CO2 absorber column using mono-ethanolamine (MEA solution as chemical solvent are predicted by a One-Dimensional (1-D rate based model in the present study. 1-D Mass and heat balance equations of vapor and liquid phase are coupled with interfacial mass transfer model and vapor-liquid equilibrium model. The two-film theory is used to estimate the mass transfer between the vapor and liquid film. Chemical reactions in MEA-CO2-H2O system are considered to predict the equilibrium pressure of CO2 in the MEA solution. The mathematical and reaction kinetics models used in this work are calculated by using in-house code. The numerical results are validated in the comparison of simulation results with experimental and simulation data given in the literature. The performance of CO2 absorber column is evaluated by the 1-D rate based model using various reaction rate coefficients suggested by various researchers. When the rate of liquid to gas mass flow rate is about 8.3, 6.6, 4.5 and 3.1, the error of CO2 loading and the CO2 removal efficiency using the reaction rate coefficients of Aboudheir et al. is within about 4.9 % and 5.2 %, respectively. Therefore, the reaction rate coefficient suggested by Aboudheir et al. among the various reaction rate coefficients used in this study is appropriate to predict the performance of CO2 absorber column using MEA solution. [Acknowledgement. This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF, funded by the Ministry of Education, Science and Technology (2011-0017220].
Elasticity moduli, thermal expansion coefficients and Debye temperature of titanium alloys
International Nuclear Information System (INIS)
Beletskij, V.M.; Glej, V.A.; Maksimyuk, P.A.; Tabachnik, V.I.; Opanasenko, V.F.
1979-01-01
Studied are the characteristics of titanium alloys which reflect best the bonding forces for atoms in a crystal lattice: elastic modules, their temperature dependences, thermal expansion coefficient and Debye temperatures. For the increase of the accuracy of measuring modules and especially their changes with temperature an ultrasonic echo-impulse method of superposition has been used. The temperature dependences of Young modulus of the VT1-0, VT16 and VT22 titanium alloys are plotted. The Young module and its change with temperature depend on the content of alloying elements. The Young module decrease with temperature may be explained within the framework of the inharmonic effect theory. The analysis of the results obtained permits to suppose that alloying of titanium alloys with aluminium results in an interatomic interaction increase that may be one of the reasons of their strength increase
Thermodynamically based constraints for rate coefficients of large biochemical networks.
Vlad, Marcel O; Ross, John
2009-01-01
Wegscheider cyclicity conditions are relationships among the rate coefficients of a complex reaction network, which ensure the compatibility of kinetic equations with the conditions for thermodynamic equilibrium. The detailed balance at equilibrium, that is the equilibration of forward and backward rates for each elementary reaction, leads to compatibility between the conditions of kinetic and thermodynamic equilibrium. Therefore, Wegscheider cyclicity conditions can be derived by eliminating the equilibrium concentrations from the conditions of detailed balance. We develop matrix algebra tools needed to carry out this elimination, reexamine an old derivation of the general form of Wegscheider cyclicity condition, and develop new derivations which lead to more compact and easier-to-use formulas. We derive scaling laws for the nonequilibrium rates of a complex reaction network, which include Wegscheider conditions as a particular case. The scaling laws for the rates are used for clarifying the kinetic and thermodynamic meaning of Wegscheider cyclicity conditions. Finally, we discuss different ways of using Wegscheider cyclicity conditions for kinetic computations in systems biology.
Rate process analysis of thermal damage in cartilage
International Nuclear Information System (INIS)
Diaz, Sergio H; Nelson, J Stuart; Wong, Brian J F
2003-01-01
Cartilage laser thermoforming (CLT) is a new surgical procedure that allows in situ treatment of deformities in the head and neck with less morbidity than traditional approaches. While some animal and human studies have shown promising results, the clinical feasibility of CLT depends on preservation of chondrocyte viability, which has not been extensively studied. The present paper characterizes cellular damage due to heat in rabbit nasal cartilage. Damage was modelled as a first order rate process for which two experimentally derived coefficients, A=1.2x10 70 s -1 and E a =4.5x10 5 J mole -1 , were determined by quantifying the decrease in concentration of healthy chondrocytes in tissue samples as a function of exposure time to constant-temperature water baths. After immersion, chondrocytes were enzymatically isolated from the matrix and stained with a two-component fluorescent dye. The dye binds nuclear DNA differentially depending upon chondrocyte viability. A flow cytometer was used to detect differential cell fluorescence to determine the percentage of live and dead cells in each sample. As a result, a damage kinetic model was obtained that can be used to predict the onset, extent and severity of cellular injury to thermal exposure
Transport coefficients in high-temperature ionized air flows with electronic excitation
Istomin, V. A.; Oblapenko, G. P.
2018-01-01
Transport coefficients are studied in high-temperature ionized air mixtures using the modified Chapman-Enskog method. The 11-component mixture N2/N2+/N /N+/O2/O2+/O /O+/N O /N O+/e- , taking into account the rotational and vibrational degrees of freedom of molecules and electronic degrees of freedom of both atomic and molecular species, is considered. Using the PAINeT software package, developed by the authors of the paper, in wide temperature range calculations of the thermal conductivity, thermal diffusion, diffusion, and shear viscosity coefficients for an equilibrium ionized air mixture and non-equilibrium flow conditions for mixture compositions, characteristic of those in shock tube experiments and re-entry conditions, are performed. For the equilibrium air case, the computed transport coefficients are compared to those obtained using simplified kinetic theory algorithms. It is shown that neglecting electronic excitation leads to a significant underestimation of the thermal conductivity coefficient at temperatures higher than 25 000 K. For non-equilibrium test cases, it is shown that the thermal diffusion coefficients of neutral species and the self-diffusion coefficients of all species are strongly affected by the mixture composition, while the thermal conductivity coefficient is most strongly influenced by the degree of ionization of the flow. Neglecting electronic excitation causes noticeable underestimation of the thermal conductivity coefficient at temperatures higher than 20 000 K.
EFFECTS OF TIN ON HARDNESS, WEAR RATE AND COEFFICIENT OF FRICTION OF CAST CU-NI-SN ALLOYS
Directory of Open Access Journals (Sweden)
S. ILANGOVAN
2013-02-01
Full Text Available An investigation was carried out to understand the effects of Sn on hardness, wear rate and the coefficient of friction of spinodal Cu-Ni-Sn alloys. Alloys of appropriate compositions were melted in a crucible furnace under argon atmosphere and cast into sand moulds. Solution heat treated and aged specimens were tested for hardness, wear rate and the coefficient of friction. It was found that the hardness increases when the Sn content increases from 4% to 8% in the solution heat treated conditions. The peak aging time is found to decrease with an increase in the Sn content. Further, the coefficient of friction is independent of hardness whereas the wear rate decreases linearly with hardness irrespective of Sn content.
Energy Technology Data Exchange (ETDEWEB)
Zheng, Fasong [The State Key Lab of Precision Measurement Technology and Instrument, Department of Precision Instruments, Tsinghua University, Beijing 100084 (China); Departments of Physics, College of Science, Beijing University of Chemical Technology, Beijing 100029 (China); Tan, Yidong; Zhang, Shulian, E-mail: zsl-dpi@mail.tsinghua.edu.cn [The State Key Lab of Precision Measurement Technology and Instrument, Department of Precision Instruments, Tsinghua University, Beijing 100084 (China); Lin, Jing; Ding, Yingchun [Departments of Physics, College of Science, Beijing University of Chemical Technology, Beijing 100029 (China)
2015-04-15
The noncooperative and ultrahigh sensitive length measurement approach is of great significance to the study of a high-precision thermal expansion coefficient (TEC) determination of materials at a wide temperature range. The novel approach is presented in this paper based on the Nd:YAG microchip laser feedback interferometry with 1064 nm wavelength, the beam frequency of which is shifted by a pair of acousto-optic modulators and then the heterodyne phase measurement technique is used. The sample is placed in a muffle furnace with two coaxial holes opened on the opposite furnace walls. The measurement beams are perpendicular and coaxial on each surface of the sample, the configuration which can not only achieve the length measurement of sample but also eliminate the influence of the distortion of the sample supporter. The reference beams inject on the reference mirrors which are put as possible as near the holes, respectively, to eliminate the air disturbances and the influence of thermal lens effect out of the furnace chamber. For validation, the thermal expansion coefficients of aluminum and steel 45 samples are measured from room temperature to 748 K, which proved measurement repeatability of TECs is better than 0.6 × 10{sup −6}(K{sup −1}) at the range of 298 K–598 K and the high-sensitive non-contact measurement of the low reflectivity surface induced by the oxidization of the samples at the range of 598 K–748 K.
Tchakoua, Théophile; Nkot Nkot, Pierre René; Fifen, Jean Jules; Nsangou, Mama; Motapon, Ousmanou
2018-06-01
We present the first potential energy surface (PES) for the AlO(X2Σ+)-He(1 S) van der Waals complex. This PES has been calculated at the RCCSD(T) level of theory. The mixed Gaussian/Exponential Extrapolation Scheme of complete basis set [CBS(D,T,Q)] was employed. The PES was fitted using global analytical method. This fitted PES was used subsequently in the close-coupling approach for the computation of the state-to-state collisional excitation cross sections of the fine-structure levels of the AlO-He complex. Collision energies were taken up to 2500 cm-1 and they yield after thermal averaging, state-to-state rate coefficients up to 300 K. The propensity rules between the lowest fine-structure levels were studied. These rules show, on one hand, a strong propensity in favour of odd ΔN transitions, and on the other hand, that cross sections and collisional rate coefficients for Δj = ΔN transitions are larger than those for Δj ≠ ΔN transitions.
Gas-phase rate coefficients of the reaction of ozone with four sesquiterpenes at 295 ± 2 K.
Richters, Stefanie; Herrmann, Hartmut; Berndt, Torsten
2015-05-07
The rate coefficients of the reaction of ozone with the four atmospherically relevant sesquiterpenes β-caryophyllene, α-humulene, α-cedrene and isolongifolene were investigated at 295 ± 2 K and atmospheric pressure by at least two independent experimental investigations for each reaction. Relative rate experiments were carried out in a flow tube using two different experimental approaches with GC-MS detection (RR 1) and PTR-MS analysis (RR 2) as the analytical techniques. Absolute rate coefficients were determined in a stopped-flow experiment following the ozone depletion by means of UV spectroscopy. The average rate coefficients from the combined investigations representing the mean values of the different experimental methods are (unit: cm(3) molecule(-1) s(-1)): k(O3+β-caryophyllene) = (1.1 ± 0.3) × 10(-14) (methods: RR 1, RR 2, absolute), k(O3+α-humulene) = (1.2 ± 0.3) × 10(-14) (RR 1, RR 2), k(O3+α-cedrene) = (1.7 ± 0.5) × 10(-16) (RR 2, absolute) and k(O3+isolongifolene) = (1.1 ± 0.5) × 10(-17) (RR 2, absolute). The high ozonolysis rate coefficients for β-caryophyllene and α-humulene agree well with the results by Shu and Atkinson (Int. J. Chem. Kinet., 1994, 26) and lead to short atmospheric lifetimes of about two minutes with respect to the ozone reaction. The relatively small rate coefficients for α-cedrene and isolongifolene differ from the available literature values by a factor of about 2.5-6. Possible reasons for the deviations are discussed. Finally, calibrated sesquiterpene FT-IR spectra were recorded for the first time.
Formalev, V. F.; Kolesnik, S. A.
2017-11-01
The authors are the first to present a closed procedure for numerical solution of inverse coefficient problems of heat conduction in anisotropic materials used as heat-shielding ones in rocket and space equipment. The reconstructed components of the thermal-conductivity tensor depend on temperature (are nonlinear). The procedure includes the formation of experimental data, the implicit gradient-descent method, the economical absolutely stable method of numerical solution of parabolic problems containing mixed derivatives, the parametric identification, construction, and numerical solution of the problem for elements of sensitivity matrices, the development of a quadratic residual functional and regularizing functionals, and also the development of algorithms and software systems. The implicit gradient-descent method permits expanding the quadratic functional in a Taylor series with retention of the linear terms for the increments of the sought functions. This substantially improves the exactness and stability of solution of the inverse problems. Software systems are developed with account taken of the errors in experimental data and disregarding them. On the basis of a priori assumptions of the qualitative behavior of the functional dependences of the components of the thermal-conductivity tensor on temperature, regularizing functionals are constructed by means of which one can reconstruct the components of the thermal-conductivity tensor with an error no higher than the error of the experimental data. Results of the numerical solution of the inverse coefficient problems on reconstruction of nonlinear components of the thermal-conductivity tensor have been obtained and are discussed.
Onel, L; Blitz, M A; Seakins, P W
2012-04-05
Monoethanol amine (H2NCH2CH2OH, MEA) has been proposed for large-scale use in carbon capture and storage. We present the first absolute, temperature-dependent determination of the rate coefficient for the reaction of OH with MEA using laser flash photolysis for OH generation, monitoring OH removal by laser-induced fluorescence. The room-temperature rate coefficient is determined to be (7.61 ± 0.76) × 10(-11) cm(3) molecule(-1) s(-1), and the rate coefficient decreases by about 40% by 510 K. The temperature dependence of the rate coefficient is given by k1= (7.73 ± 0.24) × 10(-11)(T/295)(-(0.79±0.11)) cm(3) molecule(-1) s(-1). The high rate coefficient shows that gas-phase processing in the atmosphere will be competitive with uptake onto aerosols.
Torr, D. G.; Torr, M. R.
1980-01-01
Atmosphere Explorer-C satellite measurements are used to determine rate coefficients (RCs) for the following reactions: O(+)(D-2) + N2 yields N2(+) + O (reaction 1), O(+)(D-2) + N2 yields O(+)(S-4) + N2 (reaction 2), and O(+)(D-2) + N2 yields NO(+) + N (reaction 3). Results show the RC for reaction 1 to be 1 (plus 1 or minus 0.5) x 10 to the -10th cu cm per sec, for reaction 2 to be 3 (plus 1 or minus 2) x 10 to the -11th cu cm per sec, and 3 to be less than 5.5 x 10 to the -11th cu cm per sec. It is also found that the reaction of O(+)(D-2) with N2 does not constitute a detectable source of NO(+) ions in the thermosphere.
A High Temperature Kinetic Study for the Thermal Unimolecular Decomposition of Diethyl Carbonate
Alabbad, Mohammed
2017-07-08
Thermal unimolecular decomposition of diethyl carbonate (DEC) was investigated in a shock tube by measuring ethylene concentration with a CO2 gas laser over 900 - 1200 K and 1.2 – 2.8 bar. Rate coefficients were extracted using a simple kinetic scheme comprising of thermal decomposition of DEC as initial step followed by rapid thermal decomposition of the intermediate ethyl-hydrogen-carbonate. Our results were further analysed using ab initio and master equation calculations to obtain pressure- and temperature- dependence of rate coefficients. Similar to alkyl esters, unimolecular decomposition of DEC is found to undergo six-center retro-ene elimination of ethylene in a concerted manner.
A High Temperature Kinetic Study for the Thermal Unimolecular Decomposition of Diethyl Carbonate
Alabbad, Mohammed; Giri, Binod; Szőri, Milan; Viskolcz, Bé la; Farooq, Aamir
2017-01-01
Thermal unimolecular decomposition of diethyl carbonate (DEC) was investigated in a shock tube by measuring ethylene concentration with a CO2 gas laser over 900 - 1200 K and 1.2 – 2.8 bar. Rate coefficients were extracted using a simple kinetic scheme comprising of thermal decomposition of DEC as initial step followed by rapid thermal decomposition of the intermediate ethyl-hydrogen-carbonate. Our results were further analysed using ab initio and master equation calculations to obtain pressure- and temperature- dependence of rate coefficients. Similar to alkyl esters, unimolecular decomposition of DEC is found to undergo six-center retro-ene elimination of ethylene in a concerted manner.
Energy Technology Data Exchange (ETDEWEB)
Pawlak, M., E-mail: mpawlak@fizyka.umk.pl [Institute of Physics, Faculty of Physics, Astronomy and Informatics, Nicolaus Copernicus University, Grudziądzka 5/7, Toruń (Poland); Maliński, M. [Department of Electronics and Computer Science, Koszalin University of Technology, 2 Śniadeckich St., Koszalin 75-453 (Poland)
2015-01-10
Highlights: • The new method of determination of the effective infrared absorption coefficient is presented. • The method can be used for transparent samples for the excitation radiation. • The effect of aluminum foil on the PTR signal in a transmission configuration is discussed. - Abstract: In this paper we propose a new procedure of simultaneous estimation of the effective infrared optical absorption coefficient and the thermal diffusivity of solid state samples using the photothermal infrared radiometry method in the transmission configuration. The proposed procedure relies on the analysis of the frequency dependent signal obtained from the samples covered with thin aluminum foil. This method can be applied for both optically opaque and transparent samples. The proposed method is illustrated with the results of the thermal diffusivity and the effective IR absorption coefficient obtained for several Cd{sub 1−x}Mg{sub x}Se crystals.
Accurate and approximate thermal rate constants for polyatomic chemical reactions
International Nuclear Information System (INIS)
Nyman, Gunnar
2007-01-01
In favourable cases it is possible to calculate thermal rate constants for polyatomic reactions to high accuracy from first principles. Here, we discuss the use of flux correlation functions combined with the multi-configurational time-dependent Hartree (MCTDH) approach to efficiently calculate cumulative reaction probabilities and thermal rate constants for polyatomic chemical reactions. Three isotopic variants of the H 2 + CH 3 → CH 4 + H reaction are used to illustrate the theory. There is good agreement with experimental results although the experimental rates generally are larger than the calculated ones, which are believed to be at least as accurate as the experimental rates. Approximations allowing evaluation of the thermal rate constant above 400 K are treated. It is also noted that for the treated reactions, transition state theory (TST) gives accurate rate constants above 500 K. TST theory also gives accurate results for kinetic isotope effects in cases where the mass of the transfered atom is unchanged. Due to neglect of tunnelling, TST however fails below 400 K if the mass of the transferred atom changes between the isotopic reactions
Barbosa, Thaís da Silva; Peirone, Silvina; Barrera, Javier A; Abrate, Juan P A; Lane, Silvia I; Arbilla, Graciela; Bauerfeldt, Glauco Favilla
2015-04-14
The kinetics of the cis-3-hexene + OH reaction were investigated by an experimental relative rate method and at the density functional theory level. The experimental set-up consisted of a 200 L Teflon bag, operated at atmospheric pressure and 298 K. OH radicals were produced by the photolysis of H2O2 at 254 nm. Relative rate coefficients were determined by comparing the decays of the cis-3-hexene and reference compounds (cyclohexene, 2-buten-1-ol and allyl ether). The mean second-order rate coefficient value found was (6.27 ± 0.66) × 10(-11) cm(3) molecule(-1) s(-1), the uncertainty being estimated by propagation of errors. Theoretical calculations for the addition reaction of OH to cis-3-hexene have also been performed, at the BHandHLYP/aug-cc-pVDZ level, in order to investigate the reaction mechanism, to clarify the experimental observations and to model the reaction kinetics. Different conformations of the reactants, pre-barrier complexes and saddle points were considered in our calculations. The individual rate coefficients, calculated for each conformer of the reactant, at 298 K, using a microcanonical variational transition state method, are 4.19 × 10(-11) and 1.23 × 10(-10) cm(3) molecule(-1) s(-1). The global rate coefficient was estimated from the Boltzmann distribution of the conformers to be 8.10 × 10(-11) cm(3) molecule(-1) s(-1), which is in agreement with the experimental value. Rate coefficients calculated over the temperature range from 200-500 K are also given. Our results suggest that the complex mechanism, explicitly considering different conformations for the stationary points, must be taken into account for a proper description of the reaction kinetics.
Chung, Hoi Sung; Gopich, Irina V; McHale, Kevin; Cellmer, Troy; Louis, John M; Eaton, William A
2011-04-28
Recently developed statistical methods by Gopich and Szabo were used to extract folding and unfolding rate coefficients from single-molecule Förster resonance energy transfer (FRET) data for proteins with kinetics too fast to measure waiting time distributions. Two types of experiments and two different analyses were performed. In one experiment bursts of photons were collected from donor and acceptor fluorophores attached to a 73-residue protein, α(3)D, freely diffusing through the illuminated volume of a confocal microscope system. In the second, the protein was immobilized by linkage to a surface, and photons were collected until one of the fluorophores bleached. Folding and unfolding rate coefficients and mean FRET efficiencies for the folded and unfolded subpopulations were obtained from a photon by photon analysis of the trajectories using a maximum likelihood method. The ability of the method to describe the data in terms of a two-state model was checked by recoloring the photon trajectories with the extracted parameters and comparing the calculated FRET efficiency histograms with the measured histograms. The sum of the rate coefficients for the two-state model agreed to within 30% with the relaxation rate obtained from the decay of the donor-acceptor cross-correlation function, confirming the high accuracy of the method. Interestingly, apparently reliable rate coefficients could be extracted using the maximum likelihood method, even at low (rate coefficients and mean FRET efficiencies were also obtained in an approximate procedure by simply fitting the FRET efficiency histograms, calculated by binning the donor and acceptor photons, with a sum of three-Gaussian functions. The kinetics are exposed in these histograms by the growth of a FRET efficiency peak at values intermediate between the folded and unfolded peaks as the bin size increases, a phenomenon with similarities to NMR exchange broadening. When comparable populations of folded and unfolded
International Nuclear Information System (INIS)
Avezova, N.R.; Avezov, R.R.
2015-01-01
The approximation formula is derived for calculating the normalized coefficient of thermal losses of flat solar collectors (FSCs) for heating heat-transfer fluid (HTF). These are used in hot water supply systems in the warmer part of the year, depending on the average working surface temperature of their radiation-absorbing thermal exchange panels (RATEPs) (t"-_w_s_r) and the ambient temperature (t_a_m_b) in their realistic variation range. (author)
Loss and thermal model for power semiconductors including device rating information
DEFF Research Database (Denmark)
Ma, Ke; Bahman, Amir Sajjad; Beczkowski, Szymon
2014-01-01
The electrical loading and device rating are both important factors that determine the loss and thermal behaviors of power semiconductor devices. In the existing loss and thermal models, only the electrical loadings are focused and treated as design variables, while the device rating is normally...
Estimating Reaction Rate Coefficients Within a Travel-Time Modeling Framework
Energy Technology Data Exchange (ETDEWEB)
Gong, R [Georgia Institute of Technology; Lu, C [Georgia Institute of Technology; Luo, Jian [Georgia Institute of Technology; Wu, Wei-min [Stanford University; Cheng, H. [Stanford University; Criddle, Craig [Stanford University; Kitanidis, Peter K. [Stanford University; Gu, Baohua [ORNL; Watson, David B [ORNL; Jardine, Philip M [ORNL; Brooks, Scott C [ORNL
2011-03-01
A generalized, efficient, and practical approach based on the travel-time modeling framework is developed to estimate in situ reaction rate coefficients for groundwater remediation in heterogeneous aquifers. The required information for this approach can be obtained by conducting tracer tests with injection of a mixture of conservative and reactive tracers and measurements of both breakthrough curves (BTCs). The conservative BTC is used to infer the travel-time distribution from the injection point to the observation point. For advection-dominant reactive transport with well-mixed reactive species and a constant travel-time distribution, the reactive BTC is obtained by integrating the solutions to advective-reactive transport over the entire travel-time distribution, and then is used in optimization to determine the in situ reaction rate coefficients. By directly working on the conservative and reactive BTCs, this approach avoids costly aquifer characterization and improves the estimation for transport in heterogeneous aquifers which may not be sufficiently described by traditional mechanistic transport models with constant transport parameters. Simplified schemes are proposed for reactive transport with zero-, first-, nth-order, and Michaelis-Menten reactions. The proposed approach is validated by a reactive transport case in a two-dimensional synthetic heterogeneous aquifer and a field-scale bioremediation experiment conducted at Oak Ridge, Tennessee. The field application indicates that ethanol degradation for U(VI)-bioremediation is better approximated by zero-order reaction kinetics than first-order reaction kinetics.
Domenegueti, Jose Francisco Miras; Andrade, Acacio A; Pilla, Viviane; Zilio, Sergio Carlos
2017-01-09
A low-cost single arm double interferometer was developed for the concurrent measurement of linear thermal expansion (α) and thermo-optic (dn/dT) coefficients of transparent samples with plane and parallel surfaces. Owing to its common-path optical arrangement, the device is compact and stable, and allows the simultaneous measurement of interferences arising from a low-finesse Fabry-Perot etalon and from a Mach-Zehnder-type interferometer. The method was demonstrated with measurements of solid (silica, BK7, SF6) and liquid (water, ethanol and acetone) samples.
Oki, Kensuke; Ma, Bei; Ishitani, Yoshihiro
2017-11-01
Population distributions and transition fluxes of the A exciton in bulk GaN are theoretically analyzed using rate equations of states of the principal quantum number n up to 5 and the continuum. These rate equations consist of the terms of radiative, electron-collisional, and phononic processes. The dependence of the rate coefficients on temperature is revealed on the basis of the collisional-radiative model of hydrogen plasma for the electron-collisional processes and theoretical formulation using Fermi's "golden rule" for the phononic processes. The respective effects of the variations in electron, exciton, and lattice temperatures are exhibited. This analysis is a base of the discussion on nonthermal equilibrium states of carrier-exciton-phonon dynamics. It is found that the exciton dissociation is enhanced even below 150 K mainly by the increase in the lattice temperature. When the thermal-equilibrium temperature increases, the population fluxes between the states of n >1 and the continuum become more dominant. Below 20 K, the severe deviation from the Saha-Boltzmann distribution occurs owing to the interband excitation flux being higher than the excitation flux from the 1 S state. The population decay time of the 1 S state at 300 K is more than ten times longer than the recombination lifetime of excitons with kinetic energy but without the upper levels (n >1 and the continuum). This phenomenon is caused by a shift of population distribution to the upper levels. This phonon-exciton-radiation model gives insights into the limitations of conventional analyses such as the ABC model, the Arrhenius plot, the two-level model (n =1 and the continuum), and the neglect of the upper levels.
Noda, Nao-Aki; Hendra; Li, Wenbin; Takase, Yasushi; Ogura, Hiroki; Higashi, Yusuke
Low pressure die casting is defined as a net shape casting technology in which the molten metal is injected at high speeds and pressure into a metallic die. The low pressure die casting process plays an increasingly important role in the foundry industry as a low-cost and high-efficiency precision forming technique. In the low pressure die casting process is that the permanent die and filling systems are placed over the furnace containing the molten alloy. The filling of the cavity is obtained by forcing the molten metal, by means of a pressurized gas, to rise into a ceramic tube having protuberance, which connects the die to the furnace. The ceramics tube, called stalk, has high temperature resistance and high corrosion resistance. However, attention should be paid to the thermal stress when the stalk having protuberance is dipped into the molten aluminum. It is important to reduce the risk of fracture that may happen due to the thermal stresses. In this paper, thermo-fluid analysis is performed to calculate surface heat transfer coefficient. The finite element method is applied to calculate the thermal stresses when the stalk having protuberance is dipped into the crucible with varying dipping speeds. It is found that the stalk with or without protuberance should be dipped into the crucible slowly to reduce the thermal stress.
arXiv Status of rates and rate equations for thermal leptogenesis
Biondini, Simone; Brambilla, Nora; Garny, Mathias; Ghiglieri, Jacopo; Hohenegger, Andreas; Laine, Mikko; Mendizabal, Sebastian; Millington, Peter; Salvio, Alberto; Vairo, Antonio
2018-02-28
In many realizations of leptogenesis, heavy right-handed neutrinos play the main role in the generation of an imbalance between matter and antimatter in the early Universe. Hence, it is relevant to address quantitatively their dynamics in a hot and dense environment by taking into account the various thermal aspects of the problem at hand. The strong washout regime offers an interesting framework to carry out calculations systematically and reduce theoretical uncertainties. Indeed, any matter-antimatter asymmetry generated when the temperature of the hot plasma $T$ exceeds the right-handed neutrino mass scale $M$ is efficiently erased, and one can focus on the temperature window $T \\ll M$. We review recent progresses in the thermal field theoretic derivation of the key ingredients for the leptogenesis mechanism: the right-handed neutrino production rate, the CP asymmetry in the heavy-neutrino decays and the washout rates. The derivation of evolution equations for the heavy-neutrino and lepton-asymmetry number...
International Nuclear Information System (INIS)
Zokaei-Kadijani, S.; Safdari, J.; Mousavian, M.A.; Rashidi, A.
2013-01-01
Highlights: ► Mass transfer coefficient does not depend on biomass concentration. ► The pulp density has a negative effect on mass transfer coefficient. ► The pulp density is the unique factor that affects maximum OUR. ► In this work, Neale’s correlation is corrected for prediction of mass transfer coefficient. ► Biochemical reaction is a limiting factor in the uranium bioleaching process. - Abstract: In this work, the volumetric oxygen mass transfer coefficient and the oxygen uptake rate (OUR) were studied for uranium ore bioleaching process by Acidthiobacillus ferrooxidans in a stirred tank reactor. The Box-Bohnken design method was used to study the effect of operating parameters on the oxygen mass transfer coefficient. The investigated factors were agitation speed (rpm), aeration rate (vvm) and pulp density (% weight/volume) of the stirred tank reactor. Analysis of experimental results showed that the oxygen mass transfer coefficient had low dependence on biomass concentration but had higher dependence on the agitation speed, aeration rate and pulp density. The obtained biological enhancement factors were equal to ones in experiments. On the other hand, the obtained values for Damkohler number (Da < 0.468) indicated that the process was limited by the biochemical reaction rate. Experimental results obtained for oxygen mass transfer coefficient were correlated with the empirical relations proposed by Garcia-Ochoa and Gomez (2009) and Neale and Pinches (1994). Due to the high relative error in the correlation of Neale and Pinches, that correlation was corrected and the coefficient of determination was calculated to be 89%. The modified correlation has been obtained based on a wide range of operating conditions, which can be used to determine the mass transfer coefficient in a bioreactor
Wu, Yi; Wang, Chunlin; Sun, Hao; Murphy, Anthony B.; Rong, Mingzhe; Yang, Fei; Chen, Zhexin; Niu, Chunpin; Wang, Xiaohua
2018-04-01
The thermophysical properties, including composition, thermodynamic properties, transport coefficients and net emission coefficients, of thermal plasmas formed from pure iso-C4 perfluoronitrile C4F7N and C4F7N–CO2 mixtures are calculated for temperatures from 300 to 30 000 K and pressures from 0.1 to 20 atm. These gases have received much attention as alternatives to SF6 for use in circuit breakers, due to the low global warming potential and good dielectric properties of C4F7N. Since the parameters of the large molecules formed in the dissociation of C4F7N are unavailable, the partition function and enthalpy of formation were calculated using computational chemistry methods. From the equilibrium composition calculations, it was found that when C4F7N is mixed with CO2, CO2 can capture C atoms from C4F7N, producing CO, since the system consisting of small molecules such as CF4 and CO has lower energy at room temperature. This is in agreement with previous experimental results, which show that CO dominates the decomposition products of C4F7N–CO2 mixtures; it could limit the repeated breaking performance of C4F7N. From the point of view of chemical stability, the mixing ratio of CO2 should therefore be chosen carefully. Through comparison with common arc quenching gases (including SF6, CF3I and C5F10O), it is found that for the temperature range for which electrical conductivity remains low, pure C4F7N has similar ρC p (product of mass density and specific heat) properties to SF6, and higher radiative emission coefficient, properties that are correlated with good arc extinguishing capability. For C4F7N–CO2 mixtures, the electrical conductivity is very close to that of SF6 while the ρC p peak at 7000 K caused by decomposition of CO implies inferior interruption capability to that of SF6. The calculated properties will be useful in arc simulations.
Directory of Open Access Journals (Sweden)
Abdollah Saboori
2017-12-01
Full Text Available In this research, copper nanocomposites reinforced by graphene nanoplatelets (GNPs were fabricated using a wet mixing method followed by a classical powder metallurgy route. In order to find the best dispersion technique, ball milling and wet mixing were chosen. Qualitative evaluation of the structure of the graphene after mixing indicated that the wet mixing is an appropriate technique to disperse the GNPs. Thereafter, the influence of graphene content on microstructure, density, hardness, elastic modulus, and thermal expansion coefficient of composites was investigated. It was shown that by increasing the graphene content the aggregation of graphene is more obvious and, thus, these agglomerates affect the final properties adversely. In comparison with the unreinforced Cu, Cu–GNP composites were lighter, and their hardness and Young’s modulus were higher as a consequence of graphene addition. According to the microstructural observation of pure copper and its composites after sintering, it was concluded that grain refinement is the main mechanism of strengthening in this research. Apart from the mechanical characteristics, the coefficient of thermal expansion of composites decreased remarkably and the combination of this feature with appropriate mechanical properties can make them a promising candidate for use in electronic packaging applications.
Method and apparatus for obtaining enhanced production rate of thermal chemical reactions
Tonkovich, Anna Lee Y [Pasco, WA; Wang, Yong [Richland, WA; Wegeng, Robert S [Richland, WA; Gao, Yufei [Kennewick, WA
2003-04-01
The present invention is a method and apparatus (vessel) for providing a heat transfer rate from a reaction chamber through a wall to a heat transfer chamber substantially matching a local heat transfer rate of a catalytic thermal chemical reaction. The key to the invention is a thermal distance defined on a cross sectional plane through the vessel inclusive of a heat transfer chamber, reaction chamber and a wall between the chambers. The cross sectional plane is perpendicular to a bulk flow direction of the reactant stream, and the thermal distance is a distance between a coolest position and a hottest position on the cross sectional plane. The thermal distance is of a length wherein the heat transfer rate from the reaction chamber to the heat transfer chamber substantially matches the local heat transfer rate.
Rate Coefficient Measurements and Theoretical Analysis of the OH + ( E) CF3CH=CHCF3 Reaction.
Baasandorj, Munkhbayar; Marshall, Paul; Waterland, Robert L; Ravishankara, Akkihebbal R; Burkholder, James B
2018-04-25
Rate coefficients, k, for the gas-phase reaction of the OH radical with (E) CF3CH=CHCF3 ((E)-1,1,14,4,4-hexafluoro-2-butene, HFO-1336mzz(E)) were measured over a range of temperature (211-374 K) and bath gas pressure (20-300 Torr; He, N2) using a pulsed laser photolysis-laser induced fluorescence (PLP-LIF) technique. k1(T) was independent of pressure over this range of conditions with k1(296 K) = (1.31 ± 0.15) × 10 13 cm3 molecule 1 s 1 and k1(T) = (6.94 ± 0.80) × 10 13 exp[ (496 ± 10)/T] cm3 molecule 1 s 1, where the uncertainties are 2 and the pre-exponential term includes estimated systematic error. Rate coefficients for the OD reaction were also determined over a range of temperature (262-374 K) at 100 Torr (He). The OD rate coefficients were ~15% greater than the OH values and showed similar temperature dependent behavior with k2(T) = (7.52 ± 0.44) × 10 13 exp[ (476 ± 20)/T] and k2(296 K) = (1.53 ± 0.15) × 10 13 cm3 molecule 1 s 1. The rate coefficients for reaction 1 were also measured using a relative rate technique between 296 and 375 K with k1(296 K) measured to be (1.22 ± 0.1) × 10 13 cm3 molecule 1 s 1 in agreement with the PLP-LIF results. In addition, the 296 K rate coefficient for the O3 + (E) CF3CH=CHCF3 reaction was determined to be reaction and the significant decrease in OH reactivity compared to the (Z) CF3CH=CHCF3 stereoisomer reaction. The estimated atmospheric lifetime of (E) CF3CH=CHCF3, due to loss by reaction with OH, is estimated to be ~90 days, while the actual lifetime will depend on the location and season of its emission. Infrared absorption spectra of (E) CF3CH=CHCF3 were measured and used to estimate the 100-year time horizon global warming potentials (GWP) of 32 (atmospherically well-mixed) and 14 (lifetime-adjusted).
International Nuclear Information System (INIS)
Riahi, R.; Ben Lakhdar, Z.; Teulet, Ph.; Gleizes, A.
2006-01-01
The weighted total cross-sections (WTCS) theory is used to calculate electron impact excitation, ionization and dissociation cross-sections and rate coefficients of OH, H 2 , OH + , H 2 + , OH - and H 2 - diatomic molecules in the temperature range 1500-15000 K. Calculations are performed for H 2 (X, B, C), OH(X, A, B), H 2 + (X), OH + (X, a, A, b, c), H 2 - (X) and OH - (X) electronic states for which Dunham coefficients are available. Rate coefficients are calculated from WTCS assuming Maxwellian energy distribution functions for electrons and heavy particles. One and 2 temperatures (θ e and θ g respectively for electron and heavy particles kinetic temperatures) results are presented and fitting parameters (a, b and c) are given for each reaction rate coefficient: k(θ) a(θ b )exp(-c/θ). (authors)
Determination of absorption coefficient based on laser beam thermal blooming in gas-filled tube.
Hafizi, B; Peñano, J; Fischer, R; DiComo, G; Ting, A
2014-08-01
Thermal blooming of a laser beam propagating in a gas-filled tube is investigated both analytically and experimentally. A self-consistent formulation taking into account heating of the gas and the resultant laser beam spreading (including diffraction) is presented. The heat equation is used to determine the temperature variation while the paraxial wave equation is solved in the eikonal approximation to determine the temporal and spatial variation of the Gaussian laser spot radius, Gouy phase (longitudinal phase delay), and wavefront curvature. The analysis is benchmarked against a thermal blooming experiment in the literature using a CO₂ laser beam propagating in a tube filled with air and propane. New experimental results are presented in which a CW fiber laser (1 μm) propagates in a tube filled with nitrogen and water vapor. By matching laboratory and theoretical results, the absorption coefficient of water vapor is found to agree with calculations using MODTRAN (the MODerate-resolution atmospheric TRANsmission molecular absorption database) and HITRAN (the HIgh-resolution atmospheric TRANsmission molecular absorption database).
Li, Litong; Lv, Dajuan; Yang, Minghong; Xiong, Liangming; Luo, Jie
2018-01-26
In this paper, a hybrid sensor was fabricated using a IR-femtosecond laser to measure the thermal expansion and thermo-optical coefficient of silica-based fiber Bragg gratings (FBGs). The hybrid sensor was composed of an inline fiber Fabry-Perot interferometer (FFPI) cavity and a type-II FBG. Experiment results showed that the type-II FBG had three high reflectivity resonances in the wavelength ranging from 1100 to 1600 nm, showing the peaks in 1.1, 1.3 and 1.5 μm, respectively. The thermal expansion and thermo-optical coefficient (1.3 μm, 1.5 μm) of silica-based FBG, under temperatures ranging from 30 to 1100 °C, had been simultaneously calculated by measuring the wavelength of the type-II FBG and FFPI cavity length.
Directory of Open Access Journals (Sweden)
N R Rema
2017-08-01
Full Text Available In this paper, a multiwavelet based fingerprint compression technique using set partitioning in hierarchical trees (SPIHT algorithm with optimised prefilter coefficients is proposed. While wavelet based progressive compression techniques give a blurred image at lower bit rates due to lack of high frequency information, multiwavelets can be used efficiently to represent high frequency information. SA4 (Symmetric Antisymmetric multiwavelet when combined with SPIHT reduces the number of nodes during initialization to 1/4th compared to SPIHT with wavelet. This reduction in nodes leads to improvement in PSNR at lower bit rates. The PSNR can be further improved by optimizing the prefilter coefficients. In this work genetic algorithm (GA is used for optimizing prefilter coefficients. Using the proposed technique, there is a considerable improvement in PSNR at lower bit rates, compared to existing techniques in literature. An overall average improvement of 4.23dB and 2.52dB for bit rates in between 0.01 to 1 has been achieved for the images in the databases FVC 2000 DB1 and FVC 2002 DB3 respectively. The quality of the reconstructed image is better even at higher compression ratios like 80:1 and 100:1. The level of decomposition required for a multiwavelet is lesser compared to a wavelet.
Baasandorj, Munkhbayar; Ravishankara, A R; Burkholder, James B
2011-09-29
Rate coefficients, k, for the gas-phase reaction of the OH radical with (Z)-CF(3)CH═CHCF(3) (cis-1,1,1,4,4,4-hexafluoro-2-butene) were measured under pseudo-first-order conditions in OH using pulsed laser photolysis (PLP) to produce OH and laser-induced fluorescence (LIF) to detect it. Rate coefficients were measured over a range of temperatures (212-374 K) and bath gas pressures (20-200 Torr; He, N(2)) and found to be independent of pressure over this range of conditions. The rate coefficient has a non-Arrhenius behavior that is well-described by the expression k(1)(T) = (5.73 ± 0.60) × 10(-19) × T(2) × exp[(678 ± 10)/T] cm(3) molecule(-1) s(-1) where k(1)(296 K) was measured to be (4.91 ± 0.50) × 10(-13) cm(3) molecule(-1) s(-1) and the uncertainties are at the 2σ level and include estimated systematic errors. Rate coefficients for the analogous OD radical reaction were determined over a range of temperatures (262-374 K) at 100 Torr (He) to be k(2)(T) = (4.81 ± 0.20) × 10(-19) × T(2) × exp[(776 ± 15)/T], with k(2)(296 K) = (5.73 ± 0.50) × 10(-13) cm(3) molecule(-1) s(-1). OH radical rate coefficients were also measured at 296, 345, and 375 K using a relative rate technique and found to be in good agreement with the PLP-LIF results. A room-temperature rate coefficient for the O(3) + (Z)-CF(3)CH═CHCF(3) reaction was measured using an absolute method with O(3) in excess to be reaction was estimated to be ~20 days. Infrared absorption spectra of (Z)-CF(3)CH═CHCF(3) measured in this work were used to determine a (Z)-CF(3)CH═CHCF(3) global warming potential (GWP) of ~9 for the 100 year time horizon. A comparison of the OH reactivity of (Z)-CF(3)CH═CHCF(3) with other unsaturated fluorinated compounds is presented.
Saponification reaction system: a detailed mass transfer coefficient determination.
Pečar, Darja; Goršek, Andreja
2015-01-01
The saponification of an aromatic ester with an aqueous sodium hydroxide was studied within a heterogeneous reaction medium in order to determine the overall kinetics of the selected system. The extended thermo-kinetic model was developed compared to the previously used simple one. The reaction rate within a heterogeneous liquid-liquid system incorporates a chemical kinetics term as well as mass transfer between both phases. Chemical rate constant was obtained from experiments within a homogeneous medium, whilst the mass-transfer coefficient was determined separately. The measured thermal profiles were then the bases for determining the overall reaction-rate. This study presents the development of an extended kinetic model for considering mass transfer regarding the saponification of ethyl benzoate with sodium hydroxide within a heterogeneous reaction medium. The time-dependences are presented for the mass transfer coefficient and the interfacial areas at different heterogeneous stages and temperatures. The results indicated an important role of reliable kinetic model, as significant difference in k(L)a product was obtained with extended and simple approach.
International Nuclear Information System (INIS)
Herbst, E.; Leung, C.M.; Rensselaer Polytechnic Institute, Troy, NY)
1986-01-01
Pseudo-time-dependent models of the gas phase chemistry of dense interstellar clouds have been run with large rate coefficients for reactions between ions and polar neutral species, as advocated by Adams, Smith, and Clary. The higher rate coefficients normally lead to a reduction in both the peak and steady state abundances of polar neutrals, which can be as large as an order of magnitude but is more often smaller. Other differences between the results of these models and previous results are also discussed. 38 references
Subjective thermal sensation and human body exergy consumption rate: analysis and correlation
DEFF Research Database (Denmark)
Simone, Angela; Dovjak, M.; Kolarik, Jakub
2011-01-01
, it is reasonable to consider both the exergy flows in building and those within the human body. There is a need to verify the human-body exergy model with the Thermal-Sensation (TS) response of subjects exposed to different combinations of indoor climate parameters (temperature, humidity, etc.). First results...... available on the relation between human-body exergy consumption rates and subjectively assessed thermal sensation showed that the minimum human body exergy consumption rate is associated with thermal sensation votes close to thermal neutrality, tending to slightly cool side of thermal sensation. By applying...... the exergy concept to the built indoor environment, additional results are going to be explored. By using the data available so far of operative temperature (to), the human body exergy consumption rates increase as to increases above 24°C or decreases below 22°C at relative humidity (RH) lower than 50...
Measurement of the Thermal Expansion Coefficient for Ultra-High Temperatures up to 3000 K
Kompan, T. A.; Kondratiev, S. V.; Korenev, A. S.; Puhov, N. F.; Inochkin, F. M.; Kruglov, S. K.; Bronshtein, I. G.
2018-03-01
The paper is devoted to a new high-temperature dilatometer, a part of the State Primary Standard of the thermal expansion coefficient (TEC) unit. The dilatometer is designed for investigation and certification of materials for TEC standards in the range of extremely high temperatures. The critical review of existing methods of TEC measurements is given. Also, the design, principles of operation and metrological parameters of the new device are described. The main attention is paid to the system of machine vision that allows accurate measurement of elongation at high temperatures. The results of TEC measurements for graphite GIP-4, single crystal Al2O3, and some other materials are also presented.
International Nuclear Information System (INIS)
Glosik, J.; Rakshit, A.B.; Twiddy, N.D.; Adams, N.G.; Smith, D.
1978-01-01
Thermal-energy reaction rate coefficients and product ion distributions have been measured for reactions of both the ground state and metastable electronic states of 0 2 + , N0 + and 0 + with several neutral species, using a selected-ion flow tube. In general the excited-ion reaction rates are fast, frequently approaching the Langevin limit. Collisional quenching occurs for the reactions of N0 + sup(star) with N 2 ,0 2 and H 2 and the quenching rates have been determined. The ion source also provided a substantial yield of doubly charged 0 2 permitting some measurements of reaction rates of 0 2 2+ . (author)
Directory of Open Access Journals (Sweden)
M.A. Chowdhury
2013-12-01
Full Text Available In the present study, friction coefficient and wear rate of gear fiber reinforced plastic (gear fiber and glass fiber reinforced plastic (glass fiber sliding against mild steel are investigated experimentally. In order to do so, a pin on disc apparatus is designed and fabricated. Experiments are carried out when smooth or rough mild steel pin slides on gear fiber and glass fiber disc. Experiments are conducted at normal load 10, 15 and 20 N, sliding velocity 1, 1.5 and 2 m/s and relative humidity 70%. Variations of friction coefficient with the duration of rubbing at different normal loads and sliding velocities are investigated. Results show that friction coefficient is influenced by duration of rubbing, normal load and sliding velocity. In general, friction coefficient increases for a certain duration of rubbing and after that it remains constant for the rest of the experimental time. The obtained results reveal that friction coefficient decreases with the increase in normal load for gear fiber and glass fiber mating with smooth or rough mild steel counterface. On the other hand, it is also found that friction coefficient increases with the increase in sliding velocity for both of the tested materials. Moreover, wear rate increases with the increase in normal load and sliding velocity. The magnitudes of friction coefficient and wear rate are different depending on sliding velocity and normal load for both smooth and rough counterface pin materials.
Measuring effusion rates of obsidian lava flows by means of satellite thermal data
Coppola, D.; Laiolo, M.; Franchi, A.; Massimetti, F.; Cigolini, C.; Lara, L. E.
2017-11-01
Space-based thermal data are increasingly used for monitoring effusive eruptions, especially for calculating lava discharge rates and forecasting hazards related to basaltic lava flows. The application of this methodology to silicic, more viscous lava bodies (such as obsidian lava flows) is much less frequent, with only few examples documented in the last decades. The 2011-2012 eruption of Cordón Caulle volcano (Chile) produced a voluminous obsidian lava flow ( 0.6 km3) and offers an exceptional opportunity to analyze the relationship between heat and volumetric flux for such type of viscous lava bodies. Based on a retrospective analysis of MODIS infrared data (MIROVA system), we found that the energy radiated by the active lava flow is robustly correlated with the erupted lava volume, measured independently. We found that after a transient time of about 15 days, the coefficient of proportionality between radiant and volumetric flux becomes almost steady, and stabilizes around a value of 5 × 106 J m- 3. This coefficient (i.e. radiant density) is much lower than those found for basalts ( 1 × 108 J m- 3) and likely reflects the appropriate spreading and cooling properties of the highly-insulated, viscous flows. The effusion rates trend inferred from MODIS data correlates well with the tremor amplitude and with the plume elevation recorded throughout the eruption, thus suggesting a link between the effusive and the coeval explosive activity. Modelling of the eruptive trend indicates that the Cordón Caulle eruption occurred in two stages, either incompletely draining a single magma reservoir or more probably tapping multiple interconnected magmatic compartments.
Laser lock-in thermography for thermal contact characterisation of surface layer
International Nuclear Information System (INIS)
Semerok, A.; Jaubert, F.; Fomichev, S.V.; Thro, P.-Y.; Courtois, X.; Grisolia, C.
2012-01-01
Lock-in thermography was applied to determine the thermal contact conductance of a W-layer (140 μm) on a CFC-substrate. A lock-in thermography system together with a pulse repetition rate Nd:YAG laser (1064 nm, 1–500 Hz pulse repetition rate) for layer heating was applied for phase shift measurements on the W-layer. A numerical model for direct phase shift calculations was developed and applied to rapid determination of the Fourier amplitudes and phases of the temperature. Thermal conductance coefficients were obtained by comparing the experimental and simulation phase shifts. -- Highlights: ► Lock-in thermography determines a layer/substrate thermal conductance. ► Thermal conductance coefficient of W-layer on a CFC-substrate. ► Model for direct phase shift calculations was developed and applied. ► Rapid determination of the Fourier amplitudes and phases of the temperature. ► Comparing the experimental and simulation phase shifts.
Thermal shock resistance behavior of a functionally graded ceramic: Effects of finite cooling rate
Directory of Open Access Journals (Sweden)
Zhihe Jin
2014-01-01
Full Text Available This work presents a semi-analytical model to explore the effects of cooling rate on the thermal shock resistance behavior of a functionally graded ceramic (FGC plate with a periodic array of edge cracks. The FGC is assumed to be a thermally heterogeneous material with constant elastic modulus and Poisson's ratio. The cooling rate applied at the FGC surface is modeled using a linear ramp function. An integral equation method and a closed form asymptotic temperature solution are employed to compute the thermal stress intensity factor (TSIF. The thermal shock residual strength and critical thermal shock of the FGC plate are obtained using the SIF criterion. Thermal shock simulations for an Al2O3/Si3N4 FGC indicate that a finite cooling rate leads to a significantly higher critical thermal shock than that under the sudden cooling condition. The residual strength, however, is relatively insensitive to the cooling rate.
DEFF Research Database (Denmark)
Simone, Angela; Kolarik, Jakub; Iwamatsu, Toshiya
2011-01-01
occupants, it is reasonable to consider both the exergy flows in building and those within the human body. Until now, no data have been available on the relation between human-body exergy consumption rates and subjectively assessed thermal sensation. The objective of the present work was to relate thermal...... sensation data, from earlier thermal comfort studies, to calculated human-body exergy consumption rates. The results show that the minimum human body exergy consumption rate is associated with thermal sensation votes close to thermal neutrality, tending to the slightly cool side of thermal sensation....... Generally, the relationship between air temperature and the exergy consumption rate, as a first approximation, shows an increasing trend. Taking account of both convective and radiative heat exchange between the human body and the surrounding environment by using the calculated operative temperature, exergy...
International Nuclear Information System (INIS)
Su, Guozhen; Chen, Liwei; Chen, Jincan
2014-01-01
Due to quantum size effects (QSEs), the isobaric thermal expansion coefficient and isothermal compressibility well defined for macroscopic systems are invalid for finite-size systems. The two parameters are redefined and calculated for a finite-size ideal Fermi gas confined in a rectangular container. It is found that the isobaric thermal expansion coefficient and isothermal compressibility are generally anisotropic, i.e., they are generally different in different directions. Moreover, it is found the thermal expansion coefficient may be negative in some directions under the condition that the pressures in all directions are kept constant. - Highlights: • Isobaric thermal expansion coefficient and isothermal compressibility are redefined. • The two parameters are calculated for a finite-size ideal Fermi gas. • The two parameters are generally anisotropic for a finite-size system. • Isobaric thermal expansion coefficient may be negative in some directions
Ablation, Thermal Response, and Chemistry Program for Analysis of Thermal Protection Systems
Milos, Frank S.; Chen, Yih-Kanq
2010-01-01
In previous work, the authors documented the Multicomponent Ablation Thermochemistry (MAT) and Fully Implicit Ablation and Thermal response (FIAT) programs. In this work, key features from MAT and FIAT were combined to create the new Fully Implicit Ablation, Thermal response, and Chemistry (FIATC) program. FIATC is fully compatible with FIAT (version 2.5) but has expanded capabilities to compute the multispecies surface chemistry and ablation rate as part of the surface energy balance. This new methodology eliminates B' tables, provides blown species fractions as a function of time, and enables calculations that would otherwise be impractical (e.g. 4+ dimensional tables) such as pyrolysis and ablation with kinetic rates or unequal diffusion coefficients. Equations and solution procedures are presented, then representative calculations of equilibrium and finite-rate ablation in flight and ground-test environments are discussed.
Gupta, Roop N.; Yos, Jerrold M.; Thompson, Richard A.
1989-01-01
Reaction rate coefficients and thermodynamic and transport properties are provided for the 11-species air model which can be used for analyzing flows in chemical and thermal nonequilibrium. Such flows will likely occur around currently planned and future hypersonic vehicles. Guidelines for determining the state of the surrounding environment are provided. Approximate and more exact formulas are provided for computing the properties of partially ionized air mixtures in such environments.
Thermal history regulates methylbutenol basal emission rate in Pinus ponderosa.
Gray, Dennis W; Goldstein, Allen H; Lerdau, Manuel T
2006-07-01
Methylbutenol (MBO) is a 5-carbon alcohol that is emitted by many pines in western North America, which may have important impacts on the tropospheric chemistry of this region. In this study, we document seasonal changes in basal MBO emission rates and test several models predicting these changes based on thermal history. These models represent extensions of the ISO G93 model that add a correction factor C(basal), allowing MBO basal emission rates to change as a function of thermal history. These models also allow the calculation of a new emission parameter E(standard30), which represents the inherent capacity of a plant to produce MBO, independent of current or past environmental conditions. Most single-component models exhibited large departures in early and late season, and predicted day-to-day changes in basal emission rate with temporal offsets of up to 3 d relative to measured basal emission rates. Adding a second variable describing thermal history at a longer time scale improved early and late season model performance while retaining the day-to-day performance of the parent single-component model. Out of the models tested, the T(amb),T(max7) model exhibited the best combination of day-to-day and seasonal predictions of basal MBO emission rates.
International Nuclear Information System (INIS)
Kim, Jae Kwan; Cho, Hye Sung; Jung, Ho-Sup; Suh, Kahp-Yang; Lim, Kipil; Kim, Ki-Bum; Choi, Dae-Geun; Jeong, Jun-Ho
2012-01-01
We report on nanoimprinting of polymer thin films at 30 nm scale resolution using two types of ultraviolet (UV)-curable, flexible polymer molds: perfluoropolyether (PFPE) and polyurethane acrylate (PUA). It was found that the quality of nanopatterning at the 30 nm scale is largely determined by the combined effects of surface tension and the coefficient of thermal expansion of the polymer mold. In particular, the polar component of surface tension may play a critical role in clean release of the mold, as evidenced by much reduced delamination or broken structures for the less polarized PFPE mold when patterning a relatively hydrophilic PMMA film. In contrast, such problems were not notably observed with a relatively hydrophobic PS film for both polymer molds. In addition, the demolding characteristic was also influenced by the coefficient of thermal expansion so that no delamination or uniformity problems were observed when patterning a UV-curable polymer film at room temperature. These results suggest that a proper polymeric mold material needs to be chosen for patterning polymer films under different surface properties and processing conditions, providing insights into how a clean demolding characteristic can be obtained at 30 nm scale nanopatterning. (paper)
Influence of Gas Flow Rate on the Deposition Rate on Stainless Steel 202 Substrates
Directory of Open Access Journals (Sweden)
M.A. Chowdhury
2012-12-01
Full Text Available Solid thin films have been deposited on stainless steel 202 (SS 202 substrates at different flow rates of natural gas using a hot filament thermal chemical vapor deposition (CVD reactor. In the experiments, the variations of thin film deposition rate with the variation of gas flow rate have been investigated. The effects of gap between activation heater and substrate on the deposition rate have also been observed. Results show that deposition rate on SS 202 increases with the increase in gas flow rate within the observed range. It is also found that deposition rate increases with the decrease in gap between activation heater and substrate. In addition, friction coefficient and wear rate of SS 202 sliding against SS 304 under different sliding velocities are also investigated before and after deposition. The experimental results reveal that improved friction coefficient and wear rate is obtained after deposition than that of before deposition.
Lenzen, Matthias; Merklein, Marion
2017-10-01
In the automotive sector, a major challenge is the deep-drawing of modern lightweight sheet metals with limited formability. Thus, conventional material models lack in accuracy due to the complex material behavior. A current field of research takes into account the evolution of the Lankford coefficient. Today, changes in anisotropy under increasing degree of deformation are not considered. Only a consolidated average value of the Lankford coefficient is included in conventional material models. This leads to an increasing error in prediction of the flow behavior and therefore to an inaccurate prognosis of the forming behavior. To increase the accuracy of the prediction quality, the strain dependent Lankford coefficient should be respected, because the R-value has a direct effect on the contour of the associated flow rule. Further, the investigated materials show a more or less extinct rate dependency of the yield stress. For this reason, the rate dependency of the Lankford coefficient during uniaxial tension is focused within this contribution. To quantify the influence of strain rate on the Lankford coefficient, tensile tests are performed for three commonly used materials, the aluminum alloy AA6016-T4, the advanced high strength steel DP800 and the deep drawing steel DC06 at three different strain rates. The strain measurement is carried out by an optical strain measurement system. An evolution of the Lankford coefficient was observed for all investigated materials. Also, an influence of the deformation velocity on the anisotropy could be detected.
Homayoon, Zahra; Jambrina, Pablo G.; Aoiz, F. Javier; Bowman, Joel M.
2012-07-01
In a previous paper [P. G. Jambrina et al., J. Chem. Phys. 135, 034310 (2011), 10.1063/1.3611400] various calculations of the rate coefficient for the Mu + H2 → MuH + H reaction were presented and compared to experiment. The widely used standard quasiclassical trajectory (QCT) method was shown to overestimate the rate coefficients by several orders of magnitude over the temperature range 200-1000 K. This was attributed to a major failure of that method to describe the correct threshold for the reaction owing to the large difference in zero-point energies (ZPE) of the reactant H2 and product MuH (˜0.32 eV). In this Communication we show that by performing standard QCT calculations for the reverse reaction and then applying detailed balance, the resulting rate coefficient is in very good agreement with the other computational results that respect the ZPE, (as well as with the experiment) but which are more demanding computationally.
Bogan, Denis
1999-01-01
Laboratory measurements have been carried out to determine low temperature chemical rate coefficients of ethynyl radical (C2H) for the atmospheres of the outer planets and their satellites. This effort is directly related to the Cassini mission which will explore Saturn and Titan. A laser-based photolysis/infrared laser probe setup was used to measure the temperature dependence of kinetic rate coefficients from approx. equal to 150 to 350 K for C2H radicals with H2, C2H2, CH4, CD4, C2H4, C2H6, C3H8, n-C4H10, i-C4H10, neo-C5H12, C3H4 (methylacetylene and allene), HCN, and CH3CN. The results revealed discrepancies of an order of magnitude or more compared with the low temperature rate coefficients used in present models. A new Laval nozzle, low Mach number supersonic expansion kinetics apparatus has been constructed, resulting in the first measurements of neutral C2H radical kinetics at 90 K and permitting studies on condensable gases with insufficient vapor pressure at low temperatures. New studies of C 2H with acetylene have been completed.
Energy Technology Data Exchange (ETDEWEB)
Simone, Angela; Kolarik, Jakub; Olesen, Bjarne W. [ICIEE/BYG, Technical University of Denmark (Denmark); Iwamatsu, Toshiya [Faculty of Urban Environmental Science, Tokyo Metropolitan University (Japan); Asada, Hideo [Architech Consulting Co., Tokyo (Japan); Dovjak, Mateja [Faculty of Civil and Geodetic Engineering, University of Ljubljana (Slovenia); Schellen, Lisje [Eindhoven University of Technology, Faculty of Architecture Building and Planning (Netherlands); Shukuya, Masanori [Laboratory of Building Environment, Tokyo City University, Yokohama (Japan)
2011-01-15
Application of the exergy concept to research on the built environment is a relatively new approach. It helps to optimize climate conditioning systems so that they meet the requirements of sustainable building design. As the building should provide a healthy and comfortable environment for its occupants, it is reasonable to consider both the exergy flows in building and those within the human body. Until now, no data have been available on the relation between human-body exergy consumption rates and subjectively assessed thermal sensation. The objective of the present work was to relate thermal sensation data, from earlier thermal comfort studies, to calculated human-body exergy consumption rates. The results show that the minimum human body exergy consumption rate is associated with thermal sensation votes close to thermal neutrality, tending to the slightly cool side of thermal sensation. Generally, the relationship between air temperature and the exergy consumption rate, as a first approximation, shows an increasing trend. Taking account of both convective and radiative heat exchange between the human body and the surrounding environment by using the calculated operative temperature, exergy consumption rates increase as the operative temperature increases above 24 C or decreases below 22 C. With the data available so far, a second-order polynomial relationship between thermal sensation and the exergy consumption rate was established. (author)
Srinivasulu, G; Bunkan, A J C; Amedro, D; Crowley, J N
2018-01-31
The rate coefficient (k 1 ) for the reaction of OH radicals with perfluoro ethyl vinyl ether (PEVE, C 2 F 5 OCF[double bond, length as m-dash]CF 2 ) has been measured as a function of temperature (T = 207-300 K) using the technique of pulsed laser photolysis with detection of OH by laser-induced fluorescence (PLP-LIF) at pressures of 50 or 100 Torr N 2 bath gas. In addition, the rate coefficient was measured at 298 K and in one atmosphere of air by the relative-rate technique with loss of PEVE and reference reactant monitored in situ by IR absorption spectroscopy. The rate coefficient has a negative temperature dependence which can be parameterized as: k 1 (T) = 6.0 × 10 -13 exp[(480 ± 38/T)] cm 3 molecule -1 s -1 and a room temperature value of k 1 (298 K) = (3.0 ± 0.3) × 10 -12 cm 3 molecule -1 s -1 . Highly accurate rate coefficients from the PLP-LIF experiments were achieved by optical on-line measurements of PEVE and by performing the measurements at two different apparatuses. The large rate coefficient and the temperature dependence indicate that the reaction proceeds via OH addition to the C[double bond, length as m-dash]C double bond, the high pressure limit already being reached at 50 Torr N 2 . Based on the rate coefficient and average OH levels, the atmospheric lifetime of PEVE was estimated to be a few days.
A review of reaction rates in high temperature air
Park, Chul
1989-01-01
The existing experimental data on the rate coefficients for the chemical reactions in nonequilibrium high temperature air are reviewed and collated, and a selected set of such values is recommended for use in hypersonic flow calculations. For the reactions of neutral species, the recommended values are chosen from the experimental data that existed mostly prior to 1970, and are slightly different from those used previously. For the reactions involving ions, the recommended rate coefficients are newly chosen from the experimental data obtained more recently. The reacting environment is assumed to lack thermal equilibrium, and the rate coefficients are expressed as a function of the controlling temperature, incorporating the recent multitemperature reaction concept.
Petrignani, A.; Zande, W.J. van der; Cosby, P.C.; Hellberg, F.; Thomas, R.; Larsson, M.
2005-01-01
We have studied the dissociative recombination of the first three vibrational levels of O-2(+) in its electronic ground X (2)Pi(g) state. Absolute rate coefficients, cross sections, quantum yields and branching fractions have been determined in a merged-beam experiment in the heavy-ion storage ring,
Complete Loss and Thermal Model of Power Semiconductors Including Device Rating Information
DEFF Research Database (Denmark)
Ma, Ke; Bahman, Amir Sajjad; Beczkowski, Szymon
2015-01-01
Thermal loading of power devices are closely related to the reliability performance of the whole converter system. The electrical loading and device rating are both important factors that determine the loss and thermal behaviors of power semiconductor devices. In the existing loss and thermal...
International Nuclear Information System (INIS)
Cheng, Chao-Lin; Fang, Weileun; Tsai, Ming-Han
2015-01-01
Many standard CMOS processes, provided by existing foundries, are available. These standard CMOS processes, with stacking of various metal and dielectric layers, have been extensively applied in integrated circuits as well as micro-electromechanical systems (MEMS). It is of importance to determine the material properties of the metal and dielectric films to predict the performance and reliability of micro devices. This study employs an existing approach to determine the coefficients of thermal expansion (CTEs) of metal and dielectric films for standard CMOS processes. Test cantilevers with different stacking of metal and dielectric layers for standard CMOS processes have been designed and implemented. The CTEs of standard CMOS films can be determined from measurements of the out-of-plane thermal deformations of the test cantilevers. To demonstrate the feasibility of the present approach, thin films prepared by the Taiwan Semiconductor Manufacture Company 0.35 μm 2P4M CMOS process are characterized. Eight test cantilevers with different stacking of CMOS layers and an auxiliary Si cantilever on a SOI wafer are fabricated. The equivalent elastic moduli and CTEs of the CMOS thin films including the metal and dielectric layers are determined, respectively, from the resonant frequency and static thermal deformation of the test cantilevers. Moreover, thermal deformations of cantilevers with stacked layers different to those of the test beams have been employed to verify the measured CTEs and elastic moduli. (paper)
International Nuclear Information System (INIS)
Seo, M; Shimamura, T; Furutani, T; Hasuo, M; Bahrim, C; Fujimoto, T
2003-01-01
Disalignment of neon excited atoms in the fine-structure 2p i levels (in Paschen notation) of the 2p 5 3p configuration is investigated in a helium-neon glow discharge at temperatures between 15 and 77 K. At several temperatures, we plot the disalignment rate as a function of the helium atom density for Ne* (2p 2 or 2p 7 ) + He(1s 2 ) collisions. The slope of this dependence gives the disalignment rate coefficient. For both collisions, the experimental data for the disalignment rate coefficient show a more rapid decrease with the decrease in temperature below 40 K than our quantum close-coupling calculations based on the model potential of Hennecart and Masnou-Seeuws (1985 J. Phys. B: At. Mol. Phys. 18 657). This finding suggests that the disalignment cross section rapidly decreases below a few millielectronvolts, in disagreement with our theoretical quantum calculations which predict a strong increase below 1 meV. The disagreement suggests that the long-range electrostatic potentials are significantly more repulsive than in the aforementioned model
A study of the coefficient of thermal expansion of nuclear graphites
International Nuclear Information System (INIS)
Hacker, P.J.
2001-02-01
This thesis presents the results of a study of the Coefficient of Thermal Expansion (CTE) of two grades of nuclear graphite that are used as the moderator in the Magnox and Advanced Gas-Cooled reactors operated in the UK. This work has two main aims, the first is to characterise those elements of the graphite microstructure that control CTE within these materials and to relate these to the effects induced within the reactor. The second is to develop a microstructural model, of general applicability, that can initially be applied to model the CTE changes within the graphites under reactor conditions (neutron irradiation and radiolytic oxidation). These aims have been met by study in three interlinked areas, theoretical, experimental and modelling. Previous to this study, a loose assembly of single crystals together with changes in small scale nanometric porosity (Mrozowski cracks) were used to describe CTE behaviour of nuclear graphite both as-received and under reactor conditions. Within the experimental part of this thesis the graphite nanostructure was studied using, primarily, Transmission Electron Microscopy (TEM). This work concluded that structure on this scale was complex and that the loose assembly of single crystals was a poor microstructural approximation for modelling the CTE of these materials. Other experimental programmes measured the CTE of highly oxidised samples and simulated the effects of irradiation. The former discovered that CTE remained largely unaffected to high weight losses. This insensitivity was explained by ''The Continuous Network Hypothesis'' that was also related to classical percolation theory. The final part of the thesis modelled an abstraction of the key microstructural features identified in the previous parts of the thesis. This approach has been applied to AGR moderator graphite where it has successfully modelled the thermal expansion behaviour of the as-received, irradiated and oxidised material. (author)
Chee Siang, GO
2017-07-01
Experimental test was carried out to determine the coefficient of thermal expansion (CTE) value of 20MPa mass concrete using granite aggregate. The CTE value was established using procedure proposed by Kada et al. 2002 in determining the magnitude of early-ages CTE through laboratory test which is a rather accurate way by eliminating any possible superimposed effect of others early-age thermal deformation shrinkages such as autogenous, carbonation, plastic and drying shrinkage. This was done by submitting granite concrete block samples instrumented with ST4 vibrating wire extensometers to thermal shocks. The response of the concrete samples to this shock results in a nearly instantaneous deformation, which are measured by the sensor. These deformations, as well as the temperature signal, are used to calculate the CTE. By repeating heat cycles, the variation in the early-ages of concrete CTE over time was monitored and assessed for a period of upto 7 days. The developed CTE value facilitating the verification and validation of actual maximum permissible critical temperature differential limit (rather than arbitrarily follow published value) of cracking potential. For thick sections, internal restraint is dominant and this is governed by differentials mainly. Of the required physical properties for thermal modelling, CTE is of paramount importance that with given appropriate internal restraint factor the condition of cracking due to internal restraint is governs by equation, ΔTmax= 3.663ɛctu / αc. Thus, it can be appreciated that an increase in CTE will lower the maximum allowable differential for cracking avoidance in mass concrete while an increase of tensile strain capacity will increase the maximum allowable temperature differential.
Fukuda, Makoto; Yoshimura, Kengo; Namekawa, Koki; Sakai, Kiyotaka
2017-06-01
The objective of the present study is to evaluate the effect of filtration coefficient and internal filtration on dialysis fluid flow and mass transfer coefficient in dialyzers using dimensionless mass transfer correlation equations. Aqueous solution of vitamin B 12 clearances were obtained for REXEED-15L as a low flux dialyzer, and APS-15EA and APS-15UA as high flux dialyzers. All the other design specifications were identical for these dialyzers except for filtration coefficient. The overall mass transfer coefficient was calculated, moreover, the exponents of Reynolds number (Re) and film mass transfer coefficient of the dialysis-side fluid (k D ) for each flow rate were derived from the Wilson plot and dimensionless correlation equation. The exponents of Re were 0.4 for the low flux dialyzer whereas 0.5 for the high flux dialyzers. Dialysis fluid of the low flux dialyzer was close to laminar flow because of its low filtration coefficient. On the other hand, dialysis fluid of the high flux dialyzers was assumed to be orthogonal flow. Higher filtration coefficient was associated with higher k D influenced by mass transfer rate through diffusion and internal filtration. Higher filtration coefficient of dialyzers and internal filtration affect orthogonal flow of dialysis fluid.
Transfer coefficients in ultracold strongly coupled plasma
Bobrov, A. A.; Vorob'ev, V. S.; Zelener, B. V.
2018-03-01
We use both analytical and molecular dynamic methods for electron transfer coefficients in an ultracold plasma when its temperature is small and the coupling parameter characterizing the interaction of electrons and ions exceeds unity. For these conditions, we use the approach of nearest neighbor to determine the average electron (ion) diffusion coefficient and to calculate other electron transfer coefficients (viscosity and electrical and thermal conductivities). Molecular dynamics simulations produce electronic and ionic diffusion coefficients, confirming the reliability of these results. The results compare favorably with experimental and numerical data from earlier studies.
Thermal Conductivity of the Multicomponent Neutral Atmosphere
Pavlov, A. V.
2017-12-01
Approximate expressions for the thermal conductivity coefficient of the multicomponent neutral atmosphere consisting of N2, O2, O, He, and H are analyzed and evaluated for the atmospheric conditions by comparing them with that given by the rigorous hydrodynamic theory. The new approximations of the thermal conductivity coefficients of simple gases N2, O2, O, He, and H are derived and used. It is proved that the modified Mason and Saxena approximation of the atmospheric thermal conductivity coefficient is more accurate in reproducing the atmospheric values of the rigorous hydrodynamic thermal conductivity coefficient in comparison with those that are generally accepted in atmospheric studies. This approximation of the thermal conductivity coefficient is recommended to use in calculations of the neutral temperature of the atmosphere.
Energy Technology Data Exchange (ETDEWEB)
Freour, S. [GeM, Institut de Recherche en Genie Civil et Mecanique (UMR CNRS 6183), Universite de Nantes, Ecole Centrale de Nantes, 37 Boulevard de l' Universite, BP 406, 44 602 Saint-Nazaire cedex (France)]. E-mail: freour@crttsn.univ-nantes.fr; Gloaguen, D. [GeM, Institut de Recherche en Genie Civil et Mecanique (UMR CNRS 6183), Universite de Nantes, Ecole Centrale de Nantes, 37 Boulevard de l' Universite, BP 406, 44 602 Saint-Nazaire cedex (France); Francois, M. [Laboratoire des Systemes Mecaniques et d' Ingenierie Simultanee (LASMIS FRE CNRS 2719), Universite de Technologie de Troyes, 12 Rue Marie Curie, BP 2060, 10010 Troyes (France); Guillen, R. [GeM, Institut de Recherche en Genie Civil et Mecanique (UMR CNRS 6183), Universite de Nantes, Ecole Centrale de Nantes, 37 Boulevard de l' Universite, BP 406, 44 602 Saint-Nazaire cedex (France)
2006-04-15
scope of this work is the determination of the coefficients of thermal expansion of the Ti-17 {beta}-phase. A rigorous inverse thermo-elastic self-consistent scale transition micro-mechanical model extended to multi-phase materials was used. The experimental data required for the application of the inverse method were obtained from both the available literature and especially dedicated X-ray diffraction lattice strain measurements performed on the studied ({alpha} + {beta}) two-phase titanium alloy.
Fréour , Sylvain; Gloaguen , David; François , Marc; Guillén , Ronald
2006-01-01
International audience; The scope of this work is the determination of the coefficients of thermal expansion of the Ti-17 beta-phase. A rigorous inverse thermo-elastic self-consistent scale transition inicro-mechanical model extended to multi-phase materials was used. The experimental data required for the application of the inverse method were obtained from both the available literature and especially dedicated X-ray diffraction lattice strain measurements performed on the studied (alpha + b...
Directory of Open Access Journals (Sweden)
V. S. Zarubin
2015-01-01
Full Text Available The rational use of composites as structural materials, while perceiving the thermal and mechanical loads, to a large extent determined by their thermoelastic properties. From the presented review of works devoted to the analysis of thermoelastic characteristics of composites, it follows that the problem of estimating these characteristics is important. Among the thermoelastic properties of composites occupies an important place its temperature coefficient of linear expansion.Along with fiber composites are widely used in the technique of dispersion hardening composites, in which the role of inclusions carry particles of high-strength and high-modulus materials, including nanostructured elements. Typically, the dispersed particles have similar dimensions in all directions, which allows the shape of the particles in the first approximation the ball.In an article for the composite with isotropic spherical inclusions of a plurality of different materials by the self-produced design formulas relating the temperature coefficient of linear expansion with volume concentration of inclusions and their thermoelastic characteristics, as well as the thermoelastic properties of the matrix of the composite. Feature of the method is the self-accountability thermomechanical interaction of a single inclusion or matrix particles with a homogeneous isotropic medium having the desired temperature coefficient of linear expansion. Averaging over the volume of the composite arising from such interaction perturbation strain and stress in the inclusions and the matrix particles and makes it possible to obtain such calculation formulas.For the validation of the results of calculations of the temperature coefficient of linear expansion of the composite of this type used two-sided estimates that are based on the dual variational formulation of linear thermoelasticity problem in an inhomogeneous solid containing two alternative functional (such as Lagrange and Castigliano
Su, Yong-Yang; Marsh, Aleksandra; Haddrell, Allen E.; Li, Zhi-Ming; Reid, Jonathan P.
2017-11-01
In order to quantify the kinetics of mass transfer between the gas and condensed phases in aerosol, physicochemical properties of the gas and condensed phases and kinetic parameters (mass/thermal accommodation coefficients) are crucial for estimating mass fluxes over a wide size range from the free molecule to continuum regimes. In this study, we report measurements of the evaporation kinetics of droplets of 1-butanol, ethylene glycol (EG), diethylene glycol (DEG), and glycerol under well-controlled conditions (gas flow rates and temperature) using the previously developed cylindrical electrode electrodynamic balance technique. Measurements are compared with a model that captures the heat and mass transfer occurring at the evaporating droplet surface. The aim of these measurements is to clarify the discrepancy in the reported values of mass accommodation coefficient (αM, equals to evaporation coefficient based on microscopic reversibility) for 1-butanol, EG, and DEG and improve the accuracy of the value of the diffusion coefficient for glycerol in gaseous nitrogen. The uncertainties in the thermophysical and experimental parameters are carefully assessed, the literature values of the vapor pressures of these components are evaluated, and the plausible ranges of the evaporation coefficients for 1-butanol, EG, and DEG as well as uncertainty in diffusion coefficient for glycerol are reported. Results show that αM should be greater than 0.4, 0.2, and 0.4 for EG, DEG, and 1-butanol, respectively. The refined values are helpful for accurate prediction of the evaporation/condensation rates.
Transport Coefficients from Large Deviation Functions
Directory of Open Access Journals (Sweden)
Chloe Ya Gao
2017-10-01
Full Text Available We describe a method for computing transport coefficients from the direct evaluation of large deviation functions. This method is general, relying on only equilibrium fluctuations, and is statistically efficient, employing trajectory based importance sampling. Equilibrium fluctuations of molecular currents are characterized by their large deviation functions, which are scaled cumulant generating functions analogous to the free energies. A diffusion Monte Carlo algorithm is used to evaluate the large deviation functions, from which arbitrary transport coefficients are derivable. We find significant statistical improvement over traditional Green–Kubo based calculations. The systematic and statistical errors of this method are analyzed in the context of specific transport coefficient calculations, including the shear viscosity, interfacial friction coefficient, and thermal conductivity.
Transport Coefficients from Large Deviation Functions
Gao, Chloe; Limmer, David
2017-10-01
We describe a method for computing transport coefficients from the direct evaluation of large deviation function. This method is general, relying on only equilibrium fluctuations, and is statistically efficient, employing trajectory based importance sampling. Equilibrium fluctuations of molecular currents are characterized by their large deviation functions, which is a scaled cumulant generating function analogous to the free energy. A diffusion Monte Carlo algorithm is used to evaluate the large deviation functions, from which arbitrary transport coefficients are derivable. We find significant statistical improvement over traditional Green-Kubo based calculations. The systematic and statistical errors of this method are analyzed in the context of specific transport coefficient calculations, including the shear viscosity, interfacial friction coefficient, and thermal conductivity.
Study of Stirling Engine Efficiency Coefficient under Conditions Being Close to Real Ones
Directory of Open Access Journals (Sweden)
R. M. Abramian
2013-01-01
Full Text Available An absolute internal efficiency coefficient of the Stirling engine has been obtained without regenerator and with regenerator under conditions when van der Waals gas serves as a working medium. The paper reveals that while taking into account own volume of molecules thermal efficiency coefficient of the Stirling engine depends on mole number of the working medium and it is slightly increasing in comparison with the case of an ideal gas. The paper gives consideration to heat losses while the Stirling machine operates with heat regeneration. Dependence of regeneration rate on time of heat transfer has been obtained in the paper.
Aziz, Asim; Jamshed, Wasim; Aziz, Taha
2018-04-01
In the present research a simplified mathematical model for the solar thermal collectors is considered in the form of non-uniform unsteady stretching surface. The non-Newtonian Maxwell nanofluid model is utilized for the working fluid along with slip and convective boundary conditions and comprehensive analysis of entropy generation in the system is also observed. The effect of thermal radiation and variable thermal conductivity are also included in the present model. The mathematical formulation is carried out through a boundary layer approach and the numerical computations are carried out for Cu-water and TiO2-water nanofluids. Results are presented for the velocity, temperature and entropy generation profiles, skin friction coefficient and Nusselt number. The discussion is concluded on the effect of various governing parameters on the motion, temperature variation, entropy generation, velocity gradient and the rate of heat transfer at the boundary.
Relative measurement of the excitation rate coefficients of the FeXI ion
International Nuclear Information System (INIS)
Marotta, A.
1982-01-01
The collision rate coefficients for the iron atoms are measured through the hot plasma obtainment. The physical model used in this determination is the crown stationary model which consider that the excitation by electronic collisions is balanced by the spontaneous emission. This work was realized in a 15Kj theta pinch device, of high pulse reproductibility. The iron-pentacarbonyl [Fe(Co) 5 ] was used as the impurity source of a hydrogen gas. The temperature and density were determined by the scattering light analysis of a rubi laser using the Thomson scattering. (L.C.) [pt
International Nuclear Information System (INIS)
Ye, Yong-jun; Wang, Li-heng; Ding, De-xin; Zhao, Ya-li; Fan, Nan-bin
2014-01-01
The radon diffusion coefficient and the free radon production rate are important parameters for describing radon migration in the fragmented uranium ore. In order to determine the two parameters, the pure diffusion migration equation for radon was firstly established and its analytic solution with the two parameters to be determined was derived. Then, a self manufactured experimental column was used to simulate the pure diffusion of the radon, the improved scintillation cell method was used to measure the pore radon concentrations at different depths of the column loaded with the fragmented uranium ore, and the nonlinear least square algorithm was used to inversely determine the radon diffusion coefficient and the free radon production rate. Finally, the solution with the two inversely determined parameters was used to predict the pore radon concentrations at some depths of the column, and the predicted results were compared with the measured results. The results show that the predicted results are in good agreement with the measured results and the numerical inverse method is applicable to the determination of the radon diffusion coefficient and the free radon production rate for the fragmented uranium ore. - Highlights: • Inverse method for determining two transport parameters of radon is proposed. • A self-made experimental apparatus is used to simulate radon diffusion process. • Sampling volume and position for measuring radon concentration are optimized. • The inverse results of an experimental sample are verified
Crossover behavior of the thermal conductance and Kramers’ transition rate theory
Velizhanin, Kirill A.; Sahu, Subin; Chien, Chih-Chun; Dubi, Yonatan; Zwolak, Michael
2015-12-01
Kramers’ theory frames chemical reaction rates in solution as reactants overcoming a barrier in the presence of friction and noise. For weak coupling to the solution, the reaction rate is limited by the rate at which the solution can restore equilibrium after a subset of reactants have surmounted the barrier to become products. For strong coupling, there are always sufficiently energetic reactants. However, the solution returns many of the intermediate states back to the reactants before the product fully forms. Here, we demonstrate that the thermal conductance displays an analogous physical response to the friction and noise that drive the heat current through a material or structure. A crossover behavior emerges where the thermal reservoirs dominate the conductance at the extremes and only in the intermediate region are the intrinsic properties of the lattice manifest. Not only does this shed new light on Kramers’ classic turnover problem, this result is significant for the design of devices for thermal management and other applications, as well as the proper simulation of transport at the nanoscale.
Negative power coefficient on PHWRs with CARA fuel
International Nuclear Information System (INIS)
Lestani, H.A.; González, H.J.; Florido, P.C.
2014-01-01
Highlights: • A PHWR fuel was optimized to obtain a negative power coefficient. • Fuel cost, being a measure of design investment efficiency, was optimized. • Influence on power coefficient of geometrical and economical parameters’ was studied. • Different neutronic absorbers were studied; pure absorbers can be used. • Thermal and economical models were developed to complement neutronic assessment. - Abstract: A study of power coefficient of reactivity in heavy water reactors is made analyzing the reactivity components of fuels with several modifications oriented at reducing the coefficient. A cell model is used for neutronics calculations; a non-linear two dimensional model is used to evaluate the thermal changes that follow a power change; and a levelized unit energy cost model is used to assess the economical feasibility of the design changes introduced to reduce power coefficient. The necessity of modelling all the aforementioned quantities in a coupled scheme is stressed, as a strong interdependence was found. A series of design changes complied with a negative power coefficient of reactivity, with a feasible power radial distribution and with low refuelling cost. Some investigation lines that exceed the fuel cell study and deal with the plant operation are marked as potentially addressing the stable operation of big heavy water reactors
Kustova, E. V.; Savelev, A. S.; Kunova, O. V.
2018-05-01
Theoretical models for the vibrational state-resolved Zeldovich reaction are assessed by comparison with the results of quasi-classical trajectory (QCT) calculations. An error in the model of Aliat is corrected; the model is generalized taking into account NO vibrational states. The proposed model is fairly simple and can be easily implemented to the software for non-equilibrium flow modeling. It provides a good agreement with the QCT rate coefficients in the whole range of temperatures and reagent/product vibrational states. The developed models are tested in simulations of vibrational and chemical relaxation of air mixture behind a shock wave. The importance of accounting for excitated NO vibrational states and accurate prediction of Zeldovich reactions rates is shown.
Feofilov, A. G.; Kutepov, A. A.; She, C.-Y.; Smith, A. K.; Pesnell, W. D.; Goldberg, R. A.
2012-01-01
Among the processes governing the energy balance in the mesosphere and lower thermosphere (MLT), the quenching of CO2(nu2) vibrational levels by collisions with O atoms plays an important role. However, there is a factor of 3-4 discrepancy between the laboratory measurements of the CO2-O quenching rate coefficient, k(sub VT),and its value estimated from the atmospheric observations. In this study, we retrieve k(sub VT) in the altitude region85-105 km from the coincident SABER/TIMED and Fort Collins sodium lidar observations by minimizing the difference between measured and simulated broadband limb 15 micron radiation. The averaged k(sub VT) value obtained in this work is 6.5 +/- 1.5 X 10(exp -12) cubic cm/s that is close to other estimates of this coefficient from the atmospheric observations.However, the retrieved k(sub VT) also shows altitude dependence and varies from 5.5 1 +/-1 10(exp -12) cubic cm/s at 90 km to 7.9 +/- 1.2 10(exp -12) cubic cm/s at 105 km. Obtained results demonstrate the deficiency in current non-LTE modeling of the atmospheric 15 micron radiation, based on the application of the CO2-O quenching and excitation rates, which are linked by the detailed balance relation. We discuss the possible model improvements, among them accounting for the interaction of the non-thermal oxygen atoms with CO2 molecules.
Flow Patterns and Thermal Drag in a One-Dimensional Inviscid Channel with Heating or Cooling
Institute of Scientific and Technical Information of China (English)
无
1993-01-01
In this paper investigations on the flow patterns and the thermal drag phenomenon in one -dimensional inviscid channel flow with heating or cooling are described and discussed:expressions of flow rate ratio and thermal drag coefficient for different flow patterns and its physical mechanism are presented.
Energy Technology Data Exchange (ETDEWEB)
Laporta, V. [Istituto di Metodologie Inorganiche e dei Plasmi, CNR, Bari, Italy and Department of Physics and Astronomy, University College London, London WC1E 6BT (United Kingdom); Celiberto, R. [Dipartimento di Ingegneria Civile, Ambientale, del Territorio, Edile e di Chimica, Politecnico di Bari, Italy and Istituto di Metodologie Inorganiche e dei Plasmi, CNR, Bari (Italy); Tennyson, J. [Department of Physics and Astronomy, University College London, London WC1E 6BT (United Kingdom)
2014-12-09
Rate coefficients for dissociative electron attachment and electron-impact dissociation processes, involving vibrationally excited molecular oxygen, are presented. Analytical fits of the calculated numerical data, useful in the applications, are also provided.
Numerical study of effects of accommodation coefficients on slip phenomena
Energy Technology Data Exchange (ETDEWEB)
Choi, Young Jae; Kwon, Oh Joon [KAIST, Daejeon (Korea, Republic of)
2015-05-15
An unstructured mesh Navier-Stokes solver employing a Maxwell slip boundary condition was developed. The present flow solver was applied to the simulation of flows around an axisymmetric hollow cylinder in a Mach 10.4 free stream, known as Calspan-UB Research Center (CUBRC) Run 14 case, and the velocity slip and the temperature jump on the cylinder surface were investigated. The effect of tangential momentum and thermal accommodation coefficients used in the Maxwell condition was also investigated by adjusting their values. The results show that the reverse flow region is developed on the body surface due to the interaction between the shock and the boundary layer. Also, the shock impingement makes pressure high. The flow properties on the surface agree well with the experimental data, and the velocity slip and the temperature jump vary consistently with the local Knudsen number change. The accommodation coefficients affect the slip phenomena and the size of the flow region. The slip phenomena become larger when both tangential momentum and thermal accommodation coefficients are decreased. However, the range of the reverse flow region decreases when the momentum accommodation coefficient is decreased. The characteristics of the momentum and thermal accommodation coefficients also are overlapped when they are altered together.
Astrath, N G C; Steimacher, A; Rohling, J H; Medina, A N; Bento, A C; Baesso, M L; Jacinto, C; Catunda, T; Lima, S M; Karthikeyan, B
2008-12-22
In this work the time resolved thermal lens method is combined with interferometric technique, the thermal relaxation calorimetry, photoluminescence and lifetime measurements to determine the thermo physical properties of Nd(2)O(3) doped sodium zincborate glass as a function of temperature up to the glass transition region. Thermal diffusivity, thermal conductivity, fluorescence quantum efficiency, linear thermal expansion coefficient and thermal coefficient of electronic polarizability were determined. In conclusion, the results showed the ability of thermal lens and interferometric methods to perform measurements very close to the phase transition region. These techniques provide absolute values for the measured physical quantities and are advantageous when low scan rates are required.
Energy Technology Data Exchange (ETDEWEB)
Canciam, Cesar Augusto [Universidade Tecnologica Federal do Parana (UTFPR), Campus Ponta Grossa, PR (Brazil)], e-mail: canciam@utfpr.edu.br
2012-07-01
When evaluating the consumption of bio fuels, the knowledge of the density is of great importance for rectify the effect of temperature. The thermal expansion coefficient is a thermodynamic property that provides a measure of the density variation in response to temperature variation, keeping the pressure constant. This study aimed to predict the thermal expansion coefficients of ethyl bio diesels from castor beans, soybeans, sunflower seeds and Mabea fistulifera Mart. oils and of methyl bio diesels from soybeans, sunflower seeds, souari nut, cotton, coconut, castor beans and palm oils, from beef tallow, chicken fat and hydrogenated vegetable fat residual. For this purpose, there was a linear regression analysis of the density of each bio diesel a function of temperature. These data were obtained from other works. The thermal expansion coefficients for bio diesels are between 6.3729x{sup 10-4} and 1.0410x10{sup -3} degree C-1. In all the cases, the correlation coefficients were over 0.99. (author)
Directory of Open Access Journals (Sweden)
Kenichi Miyazaki
2016-05-01
Full Text Available We investigated the effects of chromium (Cr and niobium (Nb co-doping on the temperature coefficient of resistance (TCR and the thermal hysteresis of the metal–insulator transition of vanadium dioxide (VO2 films. We determined the TCR and thermal-hysteresis-width diagram of the V1−x−yCrxNbyO2 films by electrical-transport measurements and we found that the doping conditions x ≳ y and x + y ≥ 0.1 are appropriate for simultaneously realizing a large TCR value and an absence of thermal hysteresis in the films. By using these findings, we developed a V0.90Cr0.06Nb0.04O2 film grown on a TiO2-buffered SiO2/Si substrate that showed practically no thermal hysteresis while retaining a large TCR of 11.9%/K. This study has potential applications in the development of VO2-based uncooled bolometers.
Determination and Analysis of Ar-41 Dose Rate Characteristic at Thermal Column of Kartini Reactor
International Nuclear Information System (INIS)
Widarto; Sardjono, Y.
2007-01-01
Determination and Analysis of Ar-41 activity dose rate at the thermal column after shutdown of Kartini reactor has been done. Based on evaluation and analysis concluded that external dose rate is D = 1.606x10 -6 Sv/second and internal dose rate is 3.429x10 -1 1 Sv/second. It means that if employee work at the column thermal area for 15 minutes a day, 5 days a week, in a year will be 0.376 Sv still under dose rate limit i.e. 0.5 Sv, so that the column thermal facility is safely area. (author)
Hirai, Akiko; Bitou, Youichi; Oike, Yoshiyuki
2018-06-01
The long-term stability of NEXCERA™ ceramics having a low coefficient of thermal expansion was evaluated over a period of eight years. Several gauge blocks of differing lengths were prepared, using two types of NEXCERA. Each gauge block was kept wrung to a platen and its absolute length was periodically measured by gauge block interferometer during the eight years. Relative uncertainties of measurement of changes in gauge block length were estimated as 4.1 × 10‑8 and 2.9 × 10‑8 for 200 mm and 800 mm gauge blocks, respectively. The experimental results show the trend of expansion and a relative change of less than 0.1 × 10‑6/year for every gauge block.
Isotropic Negative Thermal Expansion Metamaterials.
Wu, Lingling; Li, Bo; Zhou, Ji
2016-07-13
Negative thermal expansion materials are important and desirable in science and engineering applications. However, natural materials with isotropic negative thermal expansion are rare and usually unsatisfied in performance. Here, we propose a novel method to achieve two- and three-dimensional negative thermal expansion metamaterials via antichiral structures. The two-dimensional metamaterial is constructed with unit cells that combine bimaterial strips and antichiral structures, while the three-dimensional metamaterial is fabricated by a multimaterial 3D printing process. Both experimental and simulation results display isotropic negative thermal expansion property of the samples. The effective coefficient of negative thermal expansion of the proposed models is demonstrated to be dependent on the difference between the thermal expansion coefficient of the component materials, as well as on the circular node radius and the ligament length in the antichiral structures. The measured value of the linear negative thermal expansion coefficient of the three-dimensional sample is among the largest achieved in experiments to date. Our findings provide an easy and practical approach to obtaining materials with tunable negative thermal expansion on any scale.
Thermal expansion of beryllium oxide
International Nuclear Information System (INIS)
Solodukhin, A.V.; Kruzhalov, A.V.; Mazurenko, V.G.; Maslov, V.A.; Medvedev, V.A.; Polupanova, T.I.
1987-01-01
Precise measurements of temperature dependence of the coefficient of linear expansion in the 22-320 K temperature range on beryllium oxide monocrystals are conducted. A model of thermal expansion is suggested; the range of temperature dependence minimum of the coefficient of thermal expansion is well described within the frames of this model. The results of the experiment may be used for investigation of thermal stresses in crystals
Eldridge, Jeffrey I.; Spuckler, Charles M.; Markham, James R.
2009-01-01
The temperature dependence of the scattering and absorption coefficients for a set of freestanding plasma-sprayed 8 wt% yttria-stabilized zirconia (8YSZ) thermal barrier coatings (TBCs) was determined at temperatures up to 1360 C in a wavelength range from 1.2 micrometers up to the 8YSZ absorption edge. The scattering and absorption coefficients were determined by fitting the directional-hemispherical reflectance and transmittance values calculated by a four-flux Kubelka Munk method to the experimentally measured hemispherical-directional reflectance and transmittance values obtained for five 8YSZ thicknesses. The scattering coefficient exhibited a continuous decrease with increasing wavelength and showed no significant temperature dependence. The scattering is primarily attributed to the relatively temperature-insensitive refractive index mismatch between the 8YSZ and its internal voids. The absorption coefficient was very low (less than 1 per centimeter) at wavelengths between 2 micrometers and the absorption edge and showed a definite temperature dependence that consisted of a shift of the absorption edge to shorter wavelengths and an increase in the weak absorption below the absorption edge with increasing temperature. The shift in the absorption edge with temperature is attributed to strongly temperature-dependent multiphonon absorption. While TBC hemispherical transmittance beyond the absorption edge can be predicted by a simple exponential decrease with thickness, below the absorption edge, typical TBC thicknesses are well below the thickness range where a simple exponential decrease in hemispherical transmittance with TBC thickness is expected. [Correction added after online publication August 11, 2009: "edge to a shorter wavelengths" has been updated as edge to shorter wavelengths."
Investigation of thermal fatigue behavior of thermal barrier coating systems
International Nuclear Information System (INIS)
Zhu Dongming; Miller, R.A.
1997-01-01
In the present study, the mechanisms of fatigue crack initiation and propagation, and of coating failure under thermal loads that simulate those in diesel engines are investigated. Surface cracks initiate early and grow continuously under thermal low cycle fatigue (LCF) and high cycle fatigue (HCF) stresses. It is found that, in the absence of interfacial oxidation, the failure associated with LCF is closely related to coating sintering and creep at high temperatures. Significant LCF and HCF interactions have been observed in the thermal fatigue tests. The fatigue crack growth rate in the ceramic coating strongly depends on the characteristic HCF cycle number, N* HCF which is defined as the number of HCF cycles per LCF cycle. The crack growth rate is increased from 0.36 μm/LCF cycle for a pure LCF test to 2.8 μm/LCF cycle for a combined LCF and HCF test at N* HCF about 20 000. A surface wedging model has been proposed to account for the HCF crack growth in the coating systems. This mechanism predicts that the HCF damage effect increases with heat flux and thus with increasing surface temperature swing, thermal expansion coefficient and elastic modulus of the ceramic coating, as well as with the HCF interacting depth. Good correlation has been found between the analysis and experimental evidence. (orig.)
DEFF Research Database (Denmark)
Schweiker, Marcel; Kolarik, Jakub; Dovjak, Mateja
2016-01-01
of the present study confirmed previously indicated trends that lowest human body exergy consumption rate is associated with thermal sensation close to neutrality. Moreover, higher acceptability was in general associated with lower human body exergy consumption rate. (C) 2016 Elsevier B.V. All rights reserved.......Few examples studied applicability of exergy analysis on human thermal comfort. These examples relate the human-body exergy consumption rate with subjectively obtained thermal sensation votes and had been based on steady-state calculation methods. However, humans are rarely exposed to steady...... between the human-body exergy consumption rate and subjective assessment of thermal environment represented by thermal sensation as well as to extend the investigation towards thermal acceptability votes. Comparison of steady-state and unsteady-state model showed that results from both models were...
Study of Physical Properties of SiCw/Al Composites During Unloaded Thermal Cycling
Institute of Scientific and Technical Information of China (English)
ZHAO Xin-ming; TIAN zhi-gang; CHENG hua; ZHU Xiao-gang; CHEN Wen-li
2004-01-01
The thermal expansion coefficient of SiCw/Al composites squeeze cast during unloaded thermal cycling was determined and analyzed. The study had shown that the thermal expansion coefficient of SiCw/Al composites reduced greatly with temperature raising. The thermal expansion coefficient of artificial ageing treatment SiCw/Al composites during unloaded thermal cycling reduced gradually, while the thermal expansion coefficient of squeezing SiCw/Al composites increased gradually. In addition, the thermal expansion coefficient of SiCw/Al composites reduced drastically with fiber fraction increasing.
International Nuclear Information System (INIS)
Ruan, Ying; Li, Liuhui; Gu, Qianqian; Zhou, Kai; Yan, Na; Wei, Bingbo
2016-01-01
Highlights: • Length change difference between rapidly and slowly solidified Co-Si alloy occurs at high temperature. • Generally CTE increases with an increasing Si content. • The thermal diffusion abilities are CoSi 2 > Co 95 Si 5 > Co 90 Si 10 > Co 2 Si > CoSi if T exceeds 565 K. • All the CTE and thermal diffusivity variations with T satisfy linear or polynomial relations. - Abstract: The thermal expansion of Co-Si solid solutions and intermetallic compounds was measured via dilatometric method, compared with the results of first-principles calculations, and their thermal diffusivities were investigated using laser flash method. The length changes of rapidly solidified Co-Si alloys are larger than those of slowly solidified alloys when temperature increases to around 1000 K due to the more competitive atom motion. The coefficient of thermal expansion (α) of Co-Si alloy increases with an increasing Si content, except that the coefficient of thermal expansion of Co 95 Si 5 influenced by both metastable structure and allotropic transformation is lower than that of Co 90 Si 10 at a higher temperature. The thermal expansion abilities of Co-Si intermetallic compounds satisfy the relationship of Co 2 Si > CoSi > CoSi 2 , and the differences of the coefficients of thermal expansion between them increase with the rise of temperature. The thermal diffusivity of CoSi 2 is evidently larger than the values of other Co-Si alloys. If temperature exceeds 565 K, their thermal diffusion abilities are CoSi 2 > Co 95 Si 5 > Co 90 Si 10 > Co 2 Si > CoSi. All the coefficient of thermal expansion and thermal diffusivity variations with temperature satisfy linear or polynomial relations.
Effect of the thermal evaporation rate of Al cathodes on organic light emitting diodes
International Nuclear Information System (INIS)
Shin, Hee Young; Suh, Min Chul
2014-01-01
Graphical abstract: - Highlights: • The TOF-SIMS analysis to investigate cathode diffusion during evaporation process. • Performance change of OLEDs prepared with different evaporation rate of Al cathode. • Change of electron transport behavior during thermal evaporation process. - Abstract: The relationship between the thermal evaporation rate of Al cathodes and the device performance of organic light-emitting diodes (OLEDs) was investigated to clarify the source of leakage current. Time-of-flight secondary ion mass spectrometry was applied to identify the diffusion of Li and Al fragments into the underlying organic layer during the thermal evaporation process. We prepared various OLEDs by varying the evaporation rates of the Al cathode to investigate different device performance. Interestingly, the leakage current level decreased when the evaporation rate reached ∼25 Å/s. In contrast, the best efficiency and operational lifetime was obtained when the evaporation rate was 5 Å/s
International Nuclear Information System (INIS)
Furuhashi, Ichiro; Kawasaki, Nobuchika; Kasahara, Naoto
2008-01-01
Temperature and thermal stress in cylindrical vessels were analysed for the thermal stratification of contained fluid. Two kinds of temperature analysis results were obtained such as the exact temperature solution of eigenfunction series and the simple approximate one by the temperature profile method. Furthermore, thermal stress shell solutions were obtained for the simple approximate temperatures. Through comparison with FEM analyses, these solutions were proved to be adequate. The simple temperature solution is described by one parameter that is the temperature decay coefficient. The thermal stress shell solutions are described by two parameters. One is the ratio between the temperature decay coefficient and the load decay coefficient. Another is the nondimensional width of stratification. These solutions are so described by few parameters that those are suitable for the simplified thermal stress evaluation charts. These charts enable quick and accurate thermal stress evaluations of cylindrical vessel of this problem compared with conventional methods. (author)
Effect of high heating rate on thermal decomposition behaviour of ...
Indian Academy of Sciences (India)
the thermal decomposition behaviour of the aforementioned powder at high heating rates was taken into considera- ... does not change the process of releasing hydrogen from titanium hydride ... from titanium hydride in a sequence of steps.
CFD Extraction of Heat Transfer Coefficient in Cryogenic Propellant Tanks
Yang, H. Q.; West, Jeff
2015-01-01
Current reduced-order thermal model for cryogenic propellant tanks is based on correlations built for flat plates collected in the 1950's. The use of these correlations suffers from inaccurate geometry representation; inaccurate gravity orientation; ambiguous length scale; and lack of detailed validation. This study uses first-principles based CFD methodology to compute heat transfer from the tank wall to the cryogenic fluids and extracts and correlates the equivalent heat transfer coefficient to support reduced-order thermal model. The CFD tool was first validated against available experimental data and commonly used correlations for natural convection along a vertically heated wall. Good agreements between the present prediction and experimental data have been found for flows in laminar as well turbulent regimes. The convective heat transfer between the tank wall and cryogenic propellant, and that between the tank wall and ullage gas were then simulated. The results showed that the commonly used heat transfer correlations for either vertical or horizontal plate over-predict heat transfer rate for the cryogenic tank, in some cases by as much as one order of magnitude. A characteristic length scale has been defined that can correlate all heat transfer coefficients for different fill levels into a single curve. This curve can be used for the reduced-order heat transfer model analysis.
Effect of high heating rate on thermal decomposition behaviour of ...
Indian Academy of Sciences (India)
Effect of high heating rate on thermal decomposition behaviour of titanium hydride ... hydride powder, while switching it from internal diffusion to chemical reaction. ... TiH phase and oxides form on the powder surface, controlling the process.
Hot B violation, the lattice, and hard thermal loops
International Nuclear Information System (INIS)
Arnold, P.
1997-01-01
It has recently been argued that the rate per unit volume of baryon number violation (topological transitions) in the hot, symmetric phase of electroweak theory is of the form ηα w 5 T 4 in the weak-coupling limit, where η is a nonperturbative numerical coefficient. Over the past several years, there have been attempts to extract the rate of baryon number violation from real-time simulations of classical thermal field theory on a spatial lattice. Unfortunately, the coefficient η will not be the same for classical lattice theories and the real quantum theory. However, by analyzing the appropriate effective theory on the lattice using the method of hard thermal loops, I show that the only obstruction to precisely relating the rates in the real and lattice theories is the fact that the long-distance physics on the lattice is not rotationally invariant. (This is unlike Euclidean-time measurements, where rotational invariance is always recovered in the continuum limit.) I then propose how this violation of rotational invariance can be eliminated emdash and the real B violation rate measured emdash by choosing an appropriate lattice Hamiltonian. I also propose a rough measure of the systematic error to be expected from using simpler, unimproved Hamiltonians. As a byproduct of my investigation, the plasma frequency and Debye mass are computed for classical thermal field theory on the lattice. copyright 1997 The American Physical Society
Energy Technology Data Exchange (ETDEWEB)
Zou, C.Y.; Cai, X.Z.; Jiang, D.Z.; Yu, C.G.; Li, X.X.; Ma, Y.W.; Han, J.L. [Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China); CAS Center for Excellence in TMSR Energy System, Chinese Academy of Sciences, Shanghai 201800 (China); Key Laboratory of Nuclear Radiation and Nuclear Energy Technology, Chinese Academy of Sciences, Shanghai 201800 (China); Chen, J.G., E-mail: chenjg@sinap.ac.cn [Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China); CAS Center for Excellence in TMSR Energy System, Chinese Academy of Sciences, Shanghai 201800 (China); Key Laboratory of Nuclear Radiation and Nuclear Energy Technology, Chinese Academy of Sciences, Shanghai 201800 (China)
2015-01-15
Highlights: • The temperature feedback coefficient with different moderation ratios for TMSR in thermal neutron region is optimized. • The breeding ratio and doubling time of a thermal TMSR with three different reprocessing schemes are analyzed. • The smaller hexagon size and larger salt fraction with more negative feedback coefficient can better satisfy the safety demands. • A shorter reprocessing time can achieve a better breeding ratio in a thermal TMSR. • The graphite moderator lifespan is compared with other MSRs and discussed. - Abstract: Molten salt reactor (MSR) has fascinating features: inherent safety, no fuel fabrication, online fuel reprocessing, etc. However, the graphite moderated MSR may present positive feedback coefficient which has severe implications for the transient behavior during operation. In this paper, the feedback coefficient and the breeding ratio are optimized based on the fuel-to-graphite ratio variation for a thorium based MSR (TMSR). A certain thermal core with negative feedback coefficient and relative high initial breeding ratio is chosen for the reprocessing scheme analysis. The breeding performances for the TMSR under different online fuel reprocessing efficiencies and frequencies are evaluated and compared with other MSR concepts. The results indicate that the thermal TMSR can get a breeding ratio greater than 1.0 with appropriate reprocessing scheme. The low fissile inventory in thermal TMSR leads to a short doubling time and low transuranic (TRU) inventory. The lifetime of graphite used for the TMSR is also discussed.
Peltier Coefficient and Photon-Assisted Tunnelling in Quantum Point Contact
International Nuclear Information System (INIS)
Arafa, H. Aly
2008-01-01
We present the Peltier coefficient and thermal transport in quantum point contact (QPC), under the influence of external fields and different temperatures. Also we obtain the oscillations of the Peltier coefficient in external fields. Numerical calculations of the Peltier coefficient are performed at different applied voltages, amplitudes and temperatures. The obtained results are consistent with the experimental data in the literature
Thermal Modeling of the Mars Reconnaissance Orbiter's Solar Panel and Instruments during Aerobraking
Dec, John A.; Gasbarre, Joseph F.; Amundsen, Ruth M.
2007-01-01
The Mars Reconnaissance Orbiter (MRO) launched on August 12, 2005 and started aerobraking at Mars in March 2006. During the spacecraft s design phase, thermal models of the solar panels and instruments were developed to determine which components would be the most limiting thermally during aerobraking. Having determined the most limiting components, thermal limits in terms of heat rate were established. Advanced thermal modeling techniques were developed utilizing Thermal Desktop and Patran Thermal. Heat transfer coefficients were calculated using a Direct Simulation Monte Carlo technique. Analysis established that the solar panels were the most limiting components during the aerobraking phase of the mission.
Heat Transfer Analysis and Modification of Thermal Probe for Gas-Solid Measurement
Directory of Open Access Journals (Sweden)
Hong Zhang
2016-01-01
Full Text Available The presented work aims to measure the gas-solid two-phase mass flow-rate in pneumatic conveyor, and a novel modified thermal probe is applied. A new analysis of the local heat transfer coefficients of thermal probe is presented, while traditional investigations focus on global coefficients. Thermal simulations are performed in Fluent 6.2 and temperature distributions of the probe are presented. The results indicate that the probe has obviously stable and unstable heat transfer areas. Based on understanding of probe characteristics, a modified probe structure is designed, which makes the probe output signal more stable and widens the measuring range. The experiments are carried out in a special designed laboratory scale pneumatic conveyor, and the modified probe shows an unambiguous improvement of the performance compared with the traditional one.
Shaw, Jacob T.; Lidster, Richard T.; Cryer, Danny R.; Ramirez, Noelia; Whiting, Fiona C.; Boustead, Graham A.; Whalley, Lisa K.; Ingham, Trevor; Rickard, Andrew R.; Dunmore, Rachel E.; Heard, Dwayne E.; Lewis, Ally C.; Carpenter, Lucy J.; Hamilton, Jacqui F.; Dillon, Terry J.
2018-03-01
Gas-phase rate coefficients are fundamental to understanding atmospheric chemistry, yet experimental data are not available for the oxidation reactions of many of the thousands of volatile organic compounds (VOCs) observed in the troposphere. Here, a new experimental method is reported for the simultaneous study of reactions between multiple different VOCs and OH, the most important daytime atmospheric radical oxidant. This technique is based upon established relative rate concepts but has the advantage of a much higher throughput of target VOCs. By evaluating multiple VOCs in each experiment, and through measurement of the depletion in each VOC after reaction with OH, the OH + VOC reaction rate coefficients can be derived. Results from experiments conducted under controlled laboratory conditions were in good agreement with the available literature for the reaction of 19 VOCs, prepared in synthetic gas mixtures, with OH. This approach was used to determine a rate coefficient for the reaction of OH with 2,3-dimethylpent-1-ene for the first time; k = 5.7 (±0.3) × 10-11 cm3 molecule-1 s-1. In addition, a further seven VOCs had only two, or fewer, individual OH rate coefficient measurements available in the literature. The results from this work were in good agreement with those measurements. A similar dataset, at an elevated temperature of 323 (±10) K, was used to determine new OH rate coefficients for 12 aromatic, 5 alkane, 5 alkene and 3 monoterpene VOC + OH reactions. In OH relative reactivity experiments that used ambient air at the University of York, a large number of different VOCs were observed, of which 23 were positively identified. Due to difficulties with detection limits and fully resolving peaks, only 19 OH rate coefficients were derived from these ambient air samples, including 10 reactions for which data were previously unavailable at the elevated reaction temperature of T = 323 (±10) K.
Directory of Open Access Journals (Sweden)
J. T. Shaw
2018-03-01
Full Text Available Gas-phase rate coefficients are fundamental to understanding atmospheric chemistry, yet experimental data are not available for the oxidation reactions of many of the thousands of volatile organic compounds (VOCs observed in the troposphere. Here, a new experimental method is reported for the simultaneous study of reactions between multiple different VOCs and OH, the most important daytime atmospheric radical oxidant. This technique is based upon established relative rate concepts but has the advantage of a much higher throughput of target VOCs. By evaluating multiple VOCs in each experiment, and through measurement of the depletion in each VOC after reaction with OH, the OH + VOC reaction rate coefficients can be derived. Results from experiments conducted under controlled laboratory conditions were in good agreement with the available literature for the reaction of 19 VOCs, prepared in synthetic gas mixtures, with OH. This approach was used to determine a rate coefficient for the reaction of OH with 2,3-dimethylpent-1-ene for the first time; k = 5.7 (±0.3 × 10−11 cm3 molecule−1 s−1. In addition, a further seven VOCs had only two, or fewer, individual OH rate coefficient measurements available in the literature. The results from this work were in good agreement with those measurements. A similar dataset, at an elevated temperature of 323 (±10 K, was used to determine new OH rate coefficients for 12 aromatic, 5 alkane, 5 alkene and 3 monoterpene VOC + OH reactions. In OH relative reactivity experiments that used ambient air at the University of York, a large number of different VOCs were observed, of which 23 were positively identified. Due to difficulties with detection limits and fully resolving peaks, only 19 OH rate coefficients were derived from these ambient air samples, including 10 reactions for which data were previously unavailable at the elevated reaction temperature of T = 323 (±10 K.
Growth and development rates have different thermal responses.
Forster, Jack; Hirst, Andrew G; Woodward, Guy
2011-11-01
Growth and development rates are fundamental to all living organisms. In a warming world, it is important to determine how these rates will respond to increasing temperatures. It is often assumed that the thermal responses of physiological rates are coupled to metabolic rate and thus have the same temperature dependence. However, the existence of the temperature-size rule suggests that intraspecific growth and development are decoupled. Decoupling of these rates would have important consequences for individual species and ecosystems, yet this has not been tested systematically across a range of species. We conducted an analysis on growth and development rate data compiled from the literature for a well-studied group, marine pelagic copepods, and use an information-theoretic approach to test which equations best describe these rates. Growth and development rates were best characterized by models with significantly different parameters: development has stronger temperature dependence than does growth across all life stages. As such, it is incorrect to assume that these rates have the same temperature dependence. We used the best-fit models for these rates to predict changes in organism mass in response to temperature. These predictions follow a concave relationship, which complicates attempts to model the impacts of increasing global temperatures on species body size.
Dateo, Christopher E.; Walch, Stephen P.
2002-01-01
As part of NASA Ames Research Center's Integrated Process Team on Device/Process Modeling and Nanotechnology our goal is to create/contribute to a gas-phase chemical database for use in modeling microelectronics devices. In particular, we use ab initio methods to determine chemical reaction pathways and to evaluate reaction rate coefficients. Our initial studies concern reactions involved in the dichlorosilane-hydrogen (SiCl2H2--H2) and trichlorosilane-hydrogen (SiCl2H-H2) systems. Reactant, saddle point (transition state), and product geometries and their vibrational harmonic frequencies are determined using the complete-active-space self-consistent-field (CASSCF) electronic structure method with the correlation consistent polarized valence double-zeta basis set (cc-pVDZ). Reaction pathways are constructed by following the imaginary frequency mode of the saddle point to both the reactant and product. Accurate energetics are determined using the singles and doubles coupled-cluster method that includes a perturbational estimate of the effects of connected triple excitations (CCSD(T)) extrapolated to the complete basis set limit. Using the data from the electronic structure calculations, reaction rate coefficients are obtained using conventional and variational transition state and RRKM theories.
Parametric Investigation of Optimum Thermal Insulation Thickness for External Walls
Directory of Open Access Journals (Sweden)
Omer Kaynakli
2011-06-01
Full Text Available Numerous studies have estimated the optimum thickness of thermal insulation materials used in building walls for different climate conditions. The economic parameters (inflation rate, discount rate, lifetime and energy costs, the heating/cooling loads of the building, the wall structure and the properties of the insulation material all affect the optimum insulation thickness. This study focused on the investigation of these parameters that affect the optimum thermal insulation thickness for building walls. To determine the optimum thickness and payback period, an economic model based on life-cycle cost analysis was used. As a result, the optimum thermal insulation thickness increased with increasing the heating and cooling energy requirements, the lifetime of the building, the inflation rate, energy costs and thermal conductivity of insulation. However, the thickness decreased with increasing the discount rate, the insulation material cost, the total wall resistance, the coefficient of performance (COP of the cooling system and the solar radiation incident on a wall. In addition, the effects of these parameters on the total life-cycle cost, payback periods and energy savings were also investigated.
Rate Coefficient Determinations for H + NO2 → OH + NO from High Pressure Flow Reactor Measurements.
Haas, Francis M; Dryer, Frederick L
2015-07-16
Rate coefficients for the reaction H + NO2 → OH + NO (R1) have been determined over the nominal temperature and pressure ranges of 737-882 K and 10-20 atm, respectively, from measurements in two different flow reactor facilities: one laminar and one turbulent. Considering the existing database of experimental k1 measurements, the present conditions add measurements of k1 at previously unconsidered temperatures between ∼820-880 K, as well as at pressures that exceed existing measurements by over an order of magnitude. Experimental measurements of NOx-perturbed H2 oxidation have been interpreted by a quasi-steady state NOx plateau (QSSP) method. At the QSSP conditions considered here, overall reactivity is sensitive only to the rates of R1 and H + O2 + M → HO2 + M (R2.M). Consequently, the ratio of k1 to k2.M may be extracted as a simple algebraic function of measured NO2, O2, and total gas concentrations with only minimal complication (within measurement uncertainty) due to treatment of overall gas composition M that differs slightly from pure bath gas B. Absolute values of k1 have been determined with reference to the relatively well-known, pressure-dependent rate coefficients of R2.B for B = Ar and N2. Rate coefficients for the title reaction determined from present experimental interpretation of both laminar and turbulent flow reactor results appear to be in very good agreement around a representative value of 1.05 × 10(14) cm(3) mol(-1) s(-1) (1.74 × 10(-10) cm(3) molecule(-1) s(-1)). Further, the results of this study agree both with existing low pressure flash photolysis k1 determinations of Ko and Fontijn (J. Phys. Chem. 95 3984) near 760 K as well as a present fit to the theoretical expression of Su et al. (J. Phys. Chem. A 106 8261). These results indicate that, over the temperature range considered in this study and up to at least 20 atm, net chemistry due to stabilization of the H-NO2 reaction intermediate to form isomers of HNO2 may proceed at
Yao, Y; Lian, Z; Liu, W; Jiang, C; Liu, Y; Lu, H
2009-04-01
Human thermal comfort researches mainly focus on the relation between the environmental factors (e.g. ambient temperature, air humidity, and air velocity, etc.) and the thermal comfort sensation based on a large amount of subjective field investigations. Although some physiological factors, such as skin temperature and metabolism were used in many thermal comfort models,they are not enough to establish a perfect thermal comfort model. In this paper,another two physiological factors, i.e. heart rate variation (HRV) and electroencephalograph (EEG), are explored for the thermal comfort study. Experiments were performed to investigate how these physiological factors respond to the environmental temperatures, and what is the relationship between HRV and EEG and thermal comfort. The experimental results indicate that HRV and EEG may be related to thermal comfort, and they may be useful to understand the mechanism of thermal comfort.
International Nuclear Information System (INIS)
Zientara, M; Jakubczyk, D; Derkachov, G; Kolwas, K; Kolwas, M
2005-01-01
Scattering of coherent light by an evaporating droplet of pure water several micrometres in size was investigated. The droplet was levitated in an electrodynamic trap placed in a small climatic chamber. The evolution of the droplet radius and the evolution dynamics were investigated by means of analysing the scattering patterns with the aid of Mie theory. A numerical model of droplet evolution, incorporating the kinetic effects near the droplet surface, was constructed. Application of this model to the experimental data allowed us to determine the mass and thermal accommodation coefficients to be α C = 0.12 ± 0.02 and α T = 0.65 ± 0.09, respectively. This model enabled us to determine with high precision the temperature evolution of the droplet and the relative humidity in the droplet vicinity
Evaluation of Instrumentation and Dynamic Thermal Ratings for Overhead Lines
Energy Technology Data Exchange (ETDEWEB)
Phillips, A. [New York Power Authority, White Plains, NY (United States)
2013-01-31
In 2010, a project was initiated through a partnership between the Department of Energy (DOE) and the New York Power Authority (NYPA) to evaluate EPRI's rating technology and instrumentation that can be used to monitor the thermal states of transmission lines and provide the required real-time data for real-time rating calculations. The project included the installation and maintenance of various instruments at three 230 kV line sites in northern New York. The instruments were monitored, and data collection and rating calculations were performed for about a three year period.
International Nuclear Information System (INIS)
Lee, S.H.; Mudawar, I.; Hasan, Mohammad M.
2016-01-01
Highlights: • Hybrid Thermal Control System (H-TCS) is proposed for future spacecraft. • Thermodynamic performance of H-TCS is examined for different space missions. • Operational modes including single-phase, two-phase and heat pump are explored. • R134a is deemed most appropriate working fluid. - Abstract: An urgent need presently exists to develop a new class of versatile spacecraft capable of conducting different types of missions and enduring varying gravitational and temperature environments, including Lunar, Martian and Near Earth Object (NEOs). This study concerns the spacecraft's Thermal Control System (TCS), which tackles heat acquisition, especially from crew and avionics, heat transport, and ultimate heat rejection by radiation. The primary goal of the study is to explore the design and thermal performance of a Hybrid Thermal Control System (H-TCS) that would satisfy the diverse thermal requirements of the different space missions. The H-TCS must endure both ‘cold’ and ‘hot’ environments, reduce weight and size, and enhance thermodynamic performance. Four different operational modes are considered: single-phase, two-phase, basic heat pump and heat pump with liquid-side, suction-side heat exchanger. A thermodynamic trade study is conducted for six different working fluids to assess important performance parameters including mass flow rate of the working fluid, maximum pressure, radiator area, compressor/pump work, and coefficient of performance (COP). R134a is determined to be most suitable based on its ability to provide a balanced compromise between reducing flow rate and maintaining low system pressure, and a moderate coefficient of performance (COP); this fluid is also both nontoxic and nonflammable, and features zero ozone depletion potential (ODP) and low global warming potential (GWP). It is shown how specific mission stages dictate which mode of operation is most suitable, and this information is used to size the radiator for the
Analytical method for estimating the thermal expansion coefficient of metals at high temperature
International Nuclear Information System (INIS)
Takamoto, S; Izumi, S; Nakata, T; Sakai, S; Oinuma, S; Nakatani, Y
2015-01-01
In this paper, we propose an analytical method for estimating the thermal expansion coefficient (TEC) of metals at high-temperature ranges. Although the conventional method based on quasiharmonic approximation (QHA) shows good results at low temperatures, anharmonic effects caused by large-amplitude thermal vibrations reduces its accuracy at high temperatures. Molecular dynamics (MD) naturally includes the anharmonic effect. However, since the computational cost of MD is relatively high, in order to make an interatomic potential capable of reproducing TEC, an analytical method is essential. In our method, analytical formulation of the radial distribution function (RDF) at finite temperature realizes the estimation of the TEC. Each peak of the RDF is approximated by the Gaussian distribution. The average and variance of the Gaussian distribution are formulated by decomposing the fluctuation of interatomic distance into independent elastic waves. We incorporated two significant anharmonic effects into the method. One is the increase in the averaged interatomic distance caused by large amplitude vibration. The second is the variation in the frequency of elastic waves. As a result, the TECs of fcc and bcc crystals estimated by our method show good agreement with those of MD. Our method enables us to make an interatomic potential that reproduces the TEC at high temperature. We developed the GEAM potential for nickel. The TEC of the fitted potential showed good agreement with experimental data from room temperature to 1000 K. As compared with the original potential, it was found that the third derivative of the wide-range curve was modified, while the zeroth, first and second derivatives were unchanged. This result supports the conventional theory of solid state physics. We believe our analytical method and developed interatomic potential will contribute to future high-temperature material development. (paper)
Jameson, A. R.
1990-01-01
The relationship between the rainfall rate (R) obtained from radiometric brightness temperatures and the extinction coefficient (k sub e) is investigated by computing the values of k sub e over a wide range of rainfall rates, for frequencies from 3 to 25 GHz. The results show that the strength of the relation between the R and the k sub e values exhibits considerable variation for frequencies at this range. Practical suggestions are made concerning the selection of particular frequencies for rain measurements to minimize the error in R determinations.
International Nuclear Information System (INIS)
Vanderploeg, H.A.; Booth, R.S.
1976-01-01
Rigorous expressions are derived for the biological-rate coefficients (BRCs) determined from time-dependent measurements of three different dependent variables of radionuclide tracer experiments. These variables, which apply to a single organism, are radionuclide content, radionuclide concentration and specific activity. The BRCs derived from these variables have different mathematical expressions and, for high growth rates, their numerical values can be quite different. The precise mathematical expressions for the BRCs are presented here to aid modelers in selecting the correct parameters for their models and to aid experiments in interpreting their results. The usefulness of these three variables in quantifying elemental uptakes and losses by organisms is discussed. (U.K.)
The rate of thermal expansion of a thin metallic slab of arbitrary shape.
Lee, Y C
2009-08-12
In a previous paper the rate of thermal expansion of a long, slender insulating bar has been worked out. Our present aim is to extend that work to the thermal expansion rate of not only a long metallic bar, but to further generalize it to a thin metallic slab of arbitrary shape. Assuming that the thickness of the slab is small compared to the linear dimension of its area we again take advantage of the two distinct, disparate timescales to turn the familiar problem of thermal expansion into a time-dependent problem of the rate of the expansion. Based on the previously established finite physical momentum of an acoustic phonon when translational invariance is broken, we show that the combined pressure of the phonons and the free electrons due to their outward momenta would suffer a Doppler reduction as the specimen expands upon heating. This Doppler reduction gives rise to damping of the expanding motion, thus yielding as a first result the time of thermal expansion of a long slender metal bar. The generalization to the important case of a thin metallic slab of any shape is then worked out in detail before a concluding section containing a long physical discussion and summary.
Kinetic coefficients in isotopically disordered crystals
International Nuclear Information System (INIS)
Zhernov, Arkadii P; Inyushkin, Alexander V
2002-01-01
Peculiarities of the behavior of kinetic coefficients, like thermal conductivity, electric conductivity, and thermoelectric power, in isotopically disordered materials are reviewed in detail. New experimental and theoretical results on the isotope effects in the thermal conductivity of diamond, Ge, and Si semiconductors are presented. The suppression effect of phonon-drag thermopower in the isotopically disordered Ge crystals is discussed. The influence of dynamic and static crystal lattice deformations on the electric conductivity of metals as well as on the ordinary phonon spectrum deformations is considered. (reviews of topical problems)
Decay Rates of Interactive Hyperbolic-Parabolic PDE Models with Thermal Effects on the Interface
International Nuclear Information System (INIS)
Lasiecka, I.; Lebiedzik, C.
2000-01-01
estimates recently established for the co-continuous semigroup associated with thermal plates subject to free boundary conditions. These trace inequalities along with the analyticity of the thermoelastic plate component allow one to establish appropriate inverse/ recovery type estimates which are critical for uniform stabilization. Our main result provides 'optimal' uniform decay rates for the energy function corresponding to the full structure. These rates are described by a suitable nonlinear ordinary differential equation, whose coefficients depend on the growth of the nonlinear dissipation at the origin
High-temperature thermal conductivity of uranium chromite and uranium niobate
International Nuclear Information System (INIS)
Fedoseev, D.V.; Varshavskaya, I.G.; Lavrent'ev, A.V.; Oziraner, S.N.; Kuznetsova, D.G.
1979-01-01
The technique of determining thermal conductivity coefficient of uranium niobate and uranium chromite on heating with laser radiation is described. Determined is the coefficient of free-convective heat transfer (with provision for a conduction component) by means of a standard specimen. The thermal conductivity coefficients of uranium chromite and niobate were measured in the 1300-1700 K temperature range. The results are presented in a diagram form. It has been calculated, that the thermal conductivity coefficient for uranium niobate specimens is greater in comparison with uranium chromite specimens. The thermal conductivity coefficients of the materials mentioned depend on temperature very slightly. Thermal conductivity of the materials considerably depends on their porosity. The specimens under investigation were fabricated by the pressing method and had the following porosity: uranium chromite - 30 %, uranium niobate - 10 %. Calculation results show, that thermal conductivity of dense uranium chromite is higher than thermal conductivity of dense uranium niobate. The experimental error equals approximately 20 %, that is mainly due to the error of measuring the temperature equal to +-25 deg, with a micropyrometer
Thermal expansion in small metallic particles
International Nuclear Information System (INIS)
Ivanov, A.S.
1985-01-01
An anomalously low thermal expansion observable in small particles is attributed to extending effect of the shell. It is shown that the coefficient of thermal expansion of the oxide-film-coated aluminium particles calculated using elastic constants and coefficients of thermal expansion of massive materials agres well with those measured experimentally. The linear dilatation of the shell, its stress to rupture and the values of the structural tension are estimated vs the temperature
Hou, Lixia; Du, Yanli; Johnson, Judy A; Wang, Shaojin
2015-10-01
Thermal death kinetics of Conogethes punctiferalis (Guenée) (Lepidoptera: Pyralidae) at different life stages, heating rate, and temperature is essential for developing postharvest treatments to control pests in chestnuts. Using a heating block system (HBS), the most heat-tolerant life stage of C. punctiferalis and the effects of heating rate (0.1, 0.5, 1, 5, and 10°C/min) on insect mortality were determined. The thermal death kinetic data of fifth-instar C. punctiferalis were obtained at temperatures between 44 and 50°C at a heating rate of 5°C/min. The results showed that the relative heat tolerance of C. punctiferalis was found to be fifth instars>pupae> third instars> eggs. To avoid the enhanced thermal tolerance of C. punctiferalis at low heating rates (0.1 or 0.5°C/min), a high heating rate of 5°C/min was selected to simulate the fast radio frequency heating in chestnuts and further determine the thermal death kinetic data. Thermal death curves of C. punctiferalis followed a 0th-order kinetic reaction model. The minimum exposure time to achieve 100% mortality was 55, 12, 6, and 3 min at 44, 46, 48, and 50°C, respectively. The activation energy for controlling C. punctiferalis was 482.15 kJ/mol with the z value of 4.09°C obtained from the thermal death-time curve. The information provided by thermal death kinetics for C. punctiferalis is useful in developing effective postharvest thermal treatment protocols for disinfesting chestnuts. © The Authors 2015. Published by Oxford University Press on behalf of Entomological Society of America. All rights reserved. For Permissions, please email: journals.permissions@oup.com.
Liu, Zhijian; Liu, Kejun; Li, Hao; Zhang, Xinyu; Jin, Guangya; Cheng, Kewei
2015-01-01
Measurements of heat collection rate and heat loss coefficient are crucial for the evaluation of in service water-in-glass evacuated tube solar water heaters. However, conventional measurement requires expensive detection devices and undergoes a series of complicated procedures. To simplify the measurement and reduce the cost, software based on artificial neural networks for measuring heat collection rate and heat loss coefficient of water-in-glass evacuated tube solar water heaters was developed. Using multilayer feed-forward neural networks with back-propagation algorithm, we developed and tested our program on the basis of 915 measured samples of water-in-glass evacuated tube solar water heaters. This artificial neural networks-based software program automatically obtained accurate heat collection rate and heat loss coefficient using simply "portable test instruments" acquired parameters, including tube length, number of tubes, tube center distance, heat water mass in tank, collector area, angle between tubes and ground and final temperature. Our results show that this software (on both personal computer and Android platforms) is efficient and convenient to predict the heat collection rate and heat loss coefficient due to it slow root mean square errors in prediction. The software now can be downloaded from http://t.cn/RLPKF08.
Hao, Junhui; Zhang, Jinhong; Qiao, Yingyun; Tian, Yuanyu
2017-08-01
This work was aimed to investigate effects of heating rate on thermal cracking behaviors, distribution of gaseous products and activation energy of the thermal cracking process of Xinjiang oil sand bitumen (OSB). The thermal cracking experiments of Xinjiang OSB were performed by using thermogravimetric analyzer (TGA) at various heating rates of 10, 20, 50, 80 and 120 K/min. The evolving characteristic of gaseous products produced from the thermal cracking process was evaluated by the Fourier transform infrared spectrometry (FTIR) connected with TG. The kinetic parameters of the thermal cracking process of Xinjiang OSB at each of heating rate were determined by the Coats-Redfern model. The result show that the temperature intervals of DE volatilization stage and main reaction stage, the ((dw/dt) max and Tmax in thermal cracking process of Xinjiang OSB all increased with the increasing heating rate. While the heating rate has not obvious effect on the coke yield of Xinjiang OSB. Furthermore, the maximum absorbance of gaseous products and corresponding temperature became larger as the heating rate increases. The activation energy of this two stage both presented increasing trend with the rising heating rate, while the increasing content of that of DE volatilization stage was weaker compared to that of main reaction stage.
Measured Thermal and Fast Neutron Fluence Rates for ATF-1 Holders During ATR Cycle 157D
Energy Technology Data Exchange (ETDEWEB)
Smith, Larry Don [Idaho National Lab. (INL), Idaho Falls, ID (United States); Miller, David Torbet [Idaho National Lab. (INL), Idaho Falls, ID (United States)
2016-03-01
This report contains the thermal (2200 m/s) and fast (E>1MeV) neutron fluence rate data for the ATF-1 holders located in core for ATR Cycle 157D which were measured by the Radiation Measurements Laboratory (RML) as requested by the Power Reactor Programs (ATR Experiments) Radiation Measurements Work Order. This report contains measurements of the fluence rates corresponding to the particular elevations relative to the 80-ft. core elevation. The data in this report consist of (1) a table of the ATR power history and distribution, (2) a hard copy listing of all thermal and fast neutron fluence rates, and (3) plots of both the thermal and fast neutron fluence rates. The fluence rates reported are for the average power levels given in the table of power history and distribution.
Neutron fluence rate and energy spectrum in SPRR-300 reactor thermal column
International Nuclear Information System (INIS)
Dou Haifeng; Dai Junlong
2006-01-01
In order to modify the simple one-dimension model, the neutron fluence rate distribution calculated with ANISN code ws checked with that calculated with MCNP code. To modify the error caused by ignoring the neutron landscape orientation leaking, the reflector that can't be modeled in a simple one-dimension model was dealt by extending landscape orientation scale. On this condition the neutron fluence rate distribution and the energy spectrum in the thermal column of SPRR-300 reactor were calculated with one-dimensional code ANISN, and the results of Cd ratio are well accorded with the experimental results. The deviation between them is less than 5% and it isn't above 10% in one or two special positions. It indicates that neutron fluence rate distribution and energy spectrum in the thermal column can be well calculated with one-dimensional code ANISN. (authors)
International Nuclear Information System (INIS)
Pietsch, U.; Marlow, D.
1986-01-01
The amount of the measured room temperature thermal expansion coefficient of tetragonal strained layers grown lattice matched on the InP substrate used is about 30% greater the expected one for a cubic 'relaxed' material. This issue has to be taken into account for the determination of the composition of the quarternary Ga/sub x/In/sub 1-x/As/sub y/P/sub 1-y/ layers from both X-ray and photoluminescence data as well as for the estimation of the thermally created stress field of optoelectronic devices. (author)
Leone, Stephen R.
1995-01-01
The objectives of the research are to measure low temperature laboratory rate coefficients for key reactions relevant to the atmospheres of Titan and Saturn. These reactions are, for example, C2H + H2, CH4, C2H2, and other hydrocarbons which need to be measured at low temperatures, down to approximately 150 K. The results of this work are provided to NASA specialists who study modeling of the hydrocarbon chemistry of the outer planets. The apparatus for this work consists of a pulsed laser photolysis system and a tunable F-center probe laser to monitor the disappearance of C2H. A low temperature cell with a cryogenic circulating fluid in the outer jacket provides the gas handling system for this work. These elements have been described in detail in previous reports. Several new results are completed and the publications are just being prepared. The reaction of C2H with C2H2 has been measured with an improved apparatus down to 154 K. An Arrhenius plot indicates a clear increase in the rate coefficient at the lowest temperatures, most likely because of the long-lived (C4H3) intermediate. The capability to achieve the lowest temperatures in this work was made possible by construction of a new cell and addition of a multipass arrangement for the probe laser, as well as improvements to the laser system.
Thermal behaviors of liquid La-based bulk metallic glasses
Energy Technology Data Exchange (ETDEWEB)
Zhang, D. W.; Wang, X. D., E-mail: wangxd@zju.edu.cn, E-mail: jiangjz@zju.edu.cn; Lou, H. B.; Cao, Q. P.; Jiang, J. Z., E-mail: wangxd@zju.edu.cn, E-mail: jiangjz@zju.edu.cn [International Center for New-Structured Materials (ICNSM), Laboratory of New-Structured Materials, State Key Laboratory of Silicon Materials, and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China); Wang, L. W. [Institute of Materials Science and Engineering, Lanzhou University, Lanzhou 730000 (China); Zhang, D. X. [State Key Laboratory of Modern Optical Instrumentation, Zhejiang University, Hangzhou 310027 (China)
2014-12-14
Thermal behaviors of liquid La-based bulk metallic glasses have been measured by using the dilatometer with a self-sealed sample cell. It is demonstrated that the strong glass forming liquid not only has the small thermal expansion coefficient but also shows the slow variation rate. Moreover, the strong glass former has relatively dense atomic packing and also small density change in the liquid state. The results suggest that the high glass forming ability of La-based metallic glasses would be closely related to the slow atomic rearrangements in liquid melts.
Thermal conductivity of high purity vanadium
International Nuclear Information System (INIS)
Jung, W.D.
1975-01-01
The thermal conductivity, Seebeck coefficient, and electrical resistivity of four high-purity vanadium samples were measured over the temperature range 5 to 300 0 K. The highest purity sample had a resistance ratio (rho 273 /rho 4 . 2 ) of 1524. The highest purity sample had a thermal conductivity maximum of 920 W/mK at 9 0 K and had a thermal conductivity of 35 W/mK at room temperature. At low temperatures, the thermal resistivity was limited by the scattering of electrons by impurities and phonons. The thermal resistivity of vanadium departed from Matthiessen's rule at low temperatures. The electrical resistivity and Seebeck coefficient of high purity vanadium showed no anomalous behavior above 130 0 K. The intrinsic electrical resistivity at low temperatures was due primarily to interband scattering of electrons. The Seebeck coefficient was positive from 10 to 240 0 K and had a maximum which was dependent upon sample purity
Non intrusive measurement of the convective heat transfer coefficient
Energy Technology Data Exchange (ETDEWEB)
Rebay, M.; Mebarki, G.; Padet, J. [Reims Univ., Reims (France). Faculty of Science, GRESPI Thermomechanical Lab; Arfaoui, A. [Reims Univ., Reims (France). Faculty of Science, GRESPI Thermomechanical Lab; Tunis Univ., Tunis (Tunisia). Faculty of Science, EL MANAR, LETTM; Maad, B.R. [Tunis Univ., Tunis (Tunisia). Faculty of Science, EL MANAR, LETTM
2010-07-01
The efficiency of cooling methods in thermal systems such as radiators and heat exchangers must be improved in order to enhance performance. The evaluation of the heat transfer coefficients between a solid and a fluid is necessary for the control and the dimensioning of thermal systems. In this study, the pulsed photothermal method was used to measure the convective heat transfer coefficient on a solid-fluid interface, notably between an air flow and a heated slab mounted on a PVC flat plate. This configuration simulated the electronic air-cooling inside enclosures and racks. The influence of the deflector's inclination angle on the enhancement of heat transfer was investigated using 2 newly developed identification models. The first model was based on a constant heat transfer coefficient during the pulsed experiment, while the second, improved model was based on a variable heat transfer coefficient. The heat transfer coefficient was deduced from the evolution of the transient temperature induced by a sudden deposit of a luminous energy on the front face of the slab. Temperature evolutions were derived by infrared thermography, a camera for cartography and a detector for precise measurement in specific locations. The results show the improvement of measurement accuracies when using a model that considers the temporal evolution of the convective heat transfer coefficient. The deflection of air flow on the upper surface of the heated slab demonstrated better cooling of the slab by the deflection of air flow. 11 refs., 1 tab., 8 figs.
On the thermal analysis of a plate-fin heat sink considering the thermal-entry length effect
International Nuclear Information System (INIS)
Bassiouny, Ramadan; Maher, Hisham; Hegazy, Adel A.
2016-01-01
Highlights: • Dissipated convective heat strongly depends on convection coefficient. Two correlations were developed for so and validated. • A clear error in air temperature distribution along the heat sink was seen if coefficient were not properly selected. • The error decreases when thermal-entry length effect is considered, as for thermal flow through short conduits as Pr <1. - Abstract: Cooling electric and electronic components is very imperative to keep these components functioning properly. The heat sink is a device used to dissipate generated heat and accordingly cool these components. Airflow through heat sinks experiences velocity and thermal boundary layer variation that significantly affects the heat transfer process and heat sink performance as a result. The present study aims at developing an analytical model that compares the effect of adopting fully-developed or thermally-developing flow on convective heat transfer coefficient and accordingly longitudinal predicted air temperature distribution. Experiments on plate-fin heat sinks were carried out to validate the developed model. The results quantitatively showed a noticeable overprediction in the air temperature distribution when the heat transfer coefficient was estimated based on a fully-developed assumption. On the other hand, a close agreement between predicted and measured values was noticed when the thermal-entry length effect was considered.
Thermal and Hygric Expansion of High Performance Concrete
J. Toman; R. Černý
2001-01-01
The linear thermal expansion coefficient of two types of high performance concrete was measured in the temperature range from 20 °C to 1000 °C, and the linear hygric expansion coefficient was determined in the moisture range from dry material to saturation water content. Comparative methods were applied for measurements of both coefficients. The experimental results show that both the effect of temperature on the values of linear thermal expansion coefficients and the effect of moisture on th...
Nasiri, Rasoul; Luo, Kai H
2017-07-10
For well over one century, the Hertz-Knudsen equation has established the relationship between thermal - mass transfer coefficients through a liquid - vapour interface and evaporation rate. These coefficients, however, have been often separately estimated for one-component equilibrium systems and their simultaneous influences on evaporation rate of fuel droplets in multicomponent systems have yet to be investigated at the atomic level. Here we first apply atomistic simulation techniques and quantum/statistical mechanics methods to understand how thermal and mass evaporation effects are controlled kinetically/thermodynamically. We then present a new development of a hybrid method of quantum transition state theory/improved kinetic gas theory, for multicomponent hydrocarbon systems to investigate how concerted-distinct conformational changes of hydrocarbons at the interface affect the evaporation rate. The results of this work provide an important physical concept in fundamental understanding of atomistic pathways in topological interface transitions of chain molecules, resolving an open problem in kinetics of fuel droplets evaporation.
Directory of Open Access Journals (Sweden)
Mahdi Alajmi
2015-07-01
Full Text Available The correlation between the mechanical properties of Fillers/Epoxy composites and their tribological behavior was investigated. Tensile, hardness, wear, and friction tests were conducted for Neat Epoxy (NE, Graphite/Epoxy composites (GE, and Data Palm Fiber/Epoxy with or without Graphite composites (GFE and FE. The correlation was made between the tensile strength, the modulus of elasticity, elongation at the break, and the hardness, as an individual or a combined factor, with the specific wear rate (SWR and coefficient of friction (COF of composites. In general, graphite as an additive to polymeric composite has had an eclectic effect on mechanical properties, whereas it has led to a positive effect on tribological properties, whilst date palm fibers (DPFs, as reinforcement for polymeric composite, promoted a mechanical performance with a slight improvement to the tribological performance. Statistically, this study reveals that there is no strong confirmation of any marked correlation between the mechanical and the specific wear rate of filler/Epoxy composites. There is, however, a remarkable correlation between the mechanical properties and the friction coefficient of filler/Epoxy composites.
Alajmi, Mahdi; Shalwan, Abdullah
2015-07-08
The correlation between the mechanical properties of Fillers/Epoxy composites and their tribological behavior was investigated. Tensile, hardness, wear, and friction tests were conducted for Neat Epoxy (NE), Graphite/Epoxy composites (GE), and Data Palm Fiber/Epoxy with or without Graphite composites (GFE and FE). The correlation was made between the tensile strength, the modulus of elasticity, elongation at the break, and the hardness, as an individual or a combined factor, with the specific wear rate (SWR) and coefficient of friction (COF) of composites. In general, graphite as an additive to polymeric composite has had an eclectic effect on mechanical properties, whereas it has led to a positive effect on tribological properties, whilst date palm fibers (DPFs), as reinforcement for polymeric composite, promoted a mechanical performance with a slight improvement to the tribological performance. Statistically, this study reveals that there is no strong confirmation of any marked correlation between the mechanical and the specific wear rate of filler/Epoxy composites. There is, however, a remarkable correlation between the mechanical properties and the friction coefficient of filler/Epoxy composites.
In-situ measurements of material thermal parameters for accurate LED lamp thermal modelling
Vellvehi, M.; Perpina, X.; Jorda, X.; Werkhoven, R.J.; Kunen, J.M.G.; Jakovenko, J.; Bancken, P.; Bolt, P.J.
2013-01-01
This work deals with the extraction of key thermal parameters for accurate thermal modelling of LED lamps: air exchange coefficient around the lamp, emissivity and thermal conductivity of all lamp parts. As a case study, an 8W retrofit lamp is presented. To assess simulation results, temperature is
Diffusion and transport coefficients in synthetic opals
International Nuclear Information System (INIS)
Sofo, J. O.; Mahan, G. D.
2000-01-01
Opals are structures composed of close-packed spheres in the size range of nano to micrometers. They are sintered to create small necks at the points of contact. We have solved the diffusion problem in such structures. The relation between the diffusion coefficient and the thermal and electrical conductivity is used to estimate the transport coefficients of opal structures as a function of the neck size and the mean free path of the carriers. The theory presented is also applicable to the diffusion problem in other periodic structures. (c) 2000 The American Physical Society
Negative thermal expansion materials: technological key for control of thermal expansion
Koshi Takenaka
2012-01-01
Most materials expand upon heating. However, although rare, some materials contract upon heating. Such negative thermal expansion (NTE) materials have enormous industrial merit because they can control the thermal expansion of materials. Recent progress in materials research enables us to obtain materials exhibiting negative coefficients of linear thermal expansion over −30 ppm K−1. Such giant NTE is opening a new phase of control of thermal expansion in composites. Specifically examining pra...
Performance Evaluation Facility for Fire Fighting Thermal Imager
International Nuclear Information System (INIS)
Kim, Sung Chan; Amon, Francine; Hamins, Anthony
2007-01-01
The present study investigates the characteristics of obscuring media inside an optical smoke cell, which is a bench-scale testing facility for the evaluation of thermal imaging cameras used by fire fighters. Light extinction coefficient and visibility through the smoke cell is characterized by the measured laser transmittance. The laser transmittance along the axial direction of the smoke cell is relatively uniform at upper and lower part for various air/fuel volume flow rate. Contrast level based image quality of visible CCD camera through the smoke cell is compared with that of thermal imaging camera. The optical smoke cell can be used as well-controlled and effective laboratory-scale test apparatus to evaluate the performance of thermal imaging camera for fire fighting application
A Novel SOFC/SOEC Sealing Glass with a Low SiO2 Content and a High Thermal Expansion Coefficient
DEFF Research Database (Denmark)
Kiebach, Wolff-Ragnar; Agersted, Karsten; Zielke, Philipp
2017-01-01
phase boundaries. To reduce the amount of Si emission, a low Si containing sealing glass (chemical composition: 48 mol% CaO, 19 mol% ZnO, 21 mol% B2O3 and 12 mol% SiO2) was developed at DTU. In this presentation, the results from thermal characterization, like thermal expansion coefficient, glass......Solid oxide cells require seals that can function in harsh, elevated temperature environments. In the case of solid oxide electrolysis (SOEC), also a low Si content is desired, since Si impurities from the glass sealing can be transported to the active fuel electrode and poison the Ni-YSZ triple...... transition temperature, crystallization temperature, etc., of the glass will be presented. Additionally, the crystallization behavior of the glass was analyzed by in-situ X-ray diffraction, recording temperature resolved XRD spectra from 30 °C up to 900 °C. Furthermore, the long-term stability...
Vert, Vicente B.; Serra, José M.
The influence of different application-oriented factors on the electrochemical activity and stability of TbBaCo 3ZnO 7+ δ when used as a solid oxide fuel cell cathode has been studied. Calcination at temperatures above 900 °C (e.g. 1000 °C) leads to a significant increase in the electrode polarization resistance. The effect of the sintering temperature of the TbBaCo 3ZnO 7+ δ cathode seems to be more important than the effect produced by the Tb substitution as observed when compared with 900 °C-sintered YBaCo 3ZnO 7+ δ; and ErBaCo 3ZnO 7+ δ electrode performances. The presence of CO 2 in the air flow leads to an increase of roughly 10% in the polarization resistance for the whole studied temperature range (500-850 °C) while this effect is reversible. Analysis of the impedance spectroscopy measurements shows that the exchange rate constant (k G from Gerischer element) is significantly affected by CO 2 at temperatures below 700 °C, while the diffusion coefficient related parameter is slightly influenced at low temperatures. Electrode degrades with a low constant rate of 1 mΩ cm 2 h -1 after 60 h. This cathode material exhibits high CO 2 tolerance, as shown by temperature programmed treatment under a continuous gas flow of air with 5% CO 2, and a relatively low thermal expansion coefficient.
International Nuclear Information System (INIS)
Rahgoshay, M.; Rahmani, Y.
2007-01-01
In this article we worked on the result and process of calculation of the gap heat transfer coefficient for a hot fuel pin in accordance with burn-up changes in the VVER-1000 reactor at the Bushehr nuclear power plant (Iran). With regard to the fact that in calculating the fuel gap heat transfer coefficient, various parameters are effective and the need for designing a model is being felt, therefore, in this article we used Ross and Stoute gap model to study impacts of different effective parameters such as thermal expansion and gaseous fission products on the h gap change rate. Over time and with changes in fuel burn-up some gaseous fission products such as xenon, argon and krypton gases are released to the gas mixture in the gap, which originally contained helium. In this study, the composition of gaseous elements in the gap volume during different times of reactor operation was found using ORIGEN code. Considering that the thermal conduction of these gases is lower than that of helium, and by using the Ross and Stoute gap model, we find first that the changes in gaseous compounds in the gap reduce the values of gap thermal conductivity coefficient, but considering thermal expansion (due to burn-up alterations) of fuel and clad resulting in the reduction of gap thickness we find that the gap heat transfer coefficient will augment in a broad range of burn-up changes. These changes result in a higher rate of gap thickness reduction than the low rate of decrease of heat conduction coefficient of the gas in the gap during burn-up. Once these changes have been defined, we can proceed with the analysis of the results of calculations based on the Ross and Stoute model and compare the results obtained with the experimental results for a hot fuel pin as presented in the final safety analysis report of the VVER-1000 reactor at Bushehr. It is noteworthy that the results of accomplished calculations based on the Ross and Stoute model correspond well with the existing
Thermal diffusivity of samarium-gadolinium zirconate solid solutions
International Nuclear Information System (INIS)
Pan, W.; Wan, C.L.; Xu, Q.; Wang, J.D.; Qu, Z.X.
2007-01-01
We synthesized samarium-gadolinium zirconate solid solutions and determined their thermal diffusivities, Young's moduli and thermal expansion coefficients, which are very important for their application in thermal barrier coatings. Samarium-gadolinium zirconate solid solutions have extremely low thermal diffusivity between 20 and 600 deg. C. The solid solutions have lower Young's moduli and higher thermal expansion coefficients than those of pure samarium and gadolinium zirconates. This combination of characteristics is promising for the application of samarium and gadolinium zirconates in gas turbines. The mechanism of phonon scattering by point defects is discussed
Transport coefficients in superfluid neutron stars
Energy Technology Data Exchange (ETDEWEB)
Tolos, Laura [Instituto de Ciencias del Espacio (IEEC/CSIC) Campus Universitat Autònoma de Barcelona, Facultat de Ciències, Torre C5, E-08193 Bellaterra (Barcelona) (Spain); Frankfurt Institute for Advances Studies. Johann Wolfgang Goethe University, Ruth-Moufang-Str. 1, 60438 Frankfurt am Main (Germany); Manuel, Cristina [Instituto de Ciencias del Espacio (IEEC/CSIC) Campus Universitat Autònoma de Barcelona, Facultat de Ciències, Torre C5, E-08193 Bellaterra (Barcelona) (Spain); Sarkar, Sreemoyee [Tata Institute of Fundamental Research, Homi Bhaba Road, Mumbai-400005 (India); Tarrus, Jaume [Physik Department, Technische Universität München, D-85748 Garching (Germany)
2016-01-22
We study the shear and bulk viscosity coefficients as well as the thermal conductivity as arising from the collisions among phonons in superfluid neutron stars. We use effective field theory techniques to extract the allowed phonon collisional processes, written as a function of the equation of state and the gap of the system. The shear viscosity due to phonon scattering is compared to calculations of that coming from electron collisions. We also comment on the possible consequences for r-mode damping in superfluid neutron stars. Moreover, we find that phonon collisions give the leading contribution to the bulk viscosities in the core of the neutron stars. We finally obtain a temperature-independent thermal conductivity from phonon collisions and compare it with the electron-muon thermal conductivity in superfluid neutron stars.
Micro thermal diode with glass thermal insulation structure embedded in a vapor chamber
Tsukamoto, Takashiro; Hirayanagi, Takashi; Tanaka, Shuji
2017-04-01
This paper reports a micro thermal diode based on one-way working fluid circulation driven by surface tension force. In forward mode, working fluid evaporates and condenses at a heated and cooled area, respectively, and the condensed liquid returns to the evaporation area due to the wettability difference. By this vapor-liquid phase change mechanism, the overall heat transfer coefficient becomes high. On the other hand, in reverse mode, no continuous evaporation-condensation cycle exists. The conductive heat loss in reverse mode was minimized by an embedded glass thermal isolation structure, which makes overall heat transfer coefficient low. The test device was made by a standard MEMS process combined with glass reflow and gold bump sealing. The overall heat transfer coefficients of 13 300 \\text{W}~{{\\text{m}}-2}~\\text{K} for forward mode and 4790 \\text{W}~{{\\text{m}}-2}~\\text{K} for reverse mode were measured. The performance index of the micro thermal diode was about 2.8.
Thermal and Hygric Expansion of High Performance Concrete
Directory of Open Access Journals (Sweden)
J. Toman
2001-01-01
Full Text Available The linear thermal expansion coefficient of two types of high performance concrete was measured in the temperature range from 20 °C to 1000 °C, and the linear hygric expansion coefficient was determined in the moisture range from dry material to saturation water content. Comparative methods were applied for measurements of both coefficients. The experimental results show that both the effect of temperature on the values of linear thermal expansion coefficients and the effect of moisture on the values of linear hygric expansion coefficients are very significant and cannot be neglected in practical applications.
Effect of warming rate on the critical thermal maxima of crabs, shrimp and fish
Vinagre, Catarina; Leal, Inês; Mendonça, Vanessa; Flores, Augusto Alberto Valero
2015-01-01
he threat of global warming has prompted numerous recent studies on the thermal tolerance of marine species. A widely used method to determine the upper thermal limit has been the Critical Thermal Maximum (CTMax), a dynamic method, meaning that temperature is increased gradually until a critical point is reached. This method presents several advantages over static methods, however, there is one main issue that hinders interpretation and comparison of CTMax results: the rate at which the tempe...
Estimation of respiratory rate from thermal videos of preterm infants.
Pereira, Carina Barbosa; Heimann, Konrad; Venema, Boudewijn; Blazek, Vladimir; Czaplik, Michael; Leonhardt, Steffen
2017-07-01
Studies have demonstrated that respiratory rate (RR) is a good predictor of the patient condition as well as an early marker of patient deterioration and physiological distress. However, it is also referred as "the neglected vital parameter". This is mainly due to shortcoming of current monitoring techniques. Moreover, in preterm infants, the removal of adhesive electrodes cause epidermal stripping, skin disruption, and with it pain. This paper proposes a new algorithm for estimation of RR in thermal videos of moderate preterm infants. It uses the temperature modulation around the nostrils over the respiratory cycle to extract this vital parameter. To compensate movement artifacts the approach incorporates a tracking algorithm. In addition, a new reliable and accurate algorithm for robust estimation of local (breath-to-breath) intervals was included. To evaluate the performance of this approach, thermal recordings of four moderate preterm infants were acquired. Results were compared with RR derived from body surface electrocardiography. The results showed an excellent agreement between thermal imaging and gold standard. On average, the relative error between both monitoring techniques was 3.42%. In summary, infrared thermography may be a clinically relevant alternative to conventional sensors, due to its high thermal resolution and outstanding characteristics.
Eddy diffusion coefficients and their upper limits based on application of the similarity theory
Directory of Open Access Journals (Sweden)
M. N. Vlasov
2015-07-01
Full Text Available The equation for the diffusion velocity in the mesosphere and the lower thermosphere (MLT includes the terms for molecular and eddy diffusion. These terms are very similar. For the first time, we show that, by using the similarity theory, the same formula can be obtained for the eddy diffusion coefficient as the commonly used formula derived by Weinstock (1981. The latter was obtained by taking, as a basis, the integral function for diffusion derived by Taylor (1921 and the three-dimensional Kolmogorov kinetic energy spectrum. The exact identity of both formulas means that the eddy diffusion and heat transport coefficients used in the equations, both for diffusion and thermal conductivity, must meet a criterion that restricts the outer eddy scale to being much less than the scale height of the atmosphere. This requirement is the same as the requirement that the free path of molecules must be much smaller than the scale height of the atmosphere. A further result of this criterion is that the eddy diffusion coefficients Ked, inferred from measurements of energy dissipation rates, cannot exceed the maximum value of 3.2 × 106 cm2 s−1 for the maximum value of the energy dissipation rate of 2 W kg−1 measured in the mesosphere and the lower thermosphere (MLT. This means that eddy diffusion coefficients larger than the maximum value correspond to eddies with outer scales so large that it is impossible to use these coefficients in eddy diffusion and eddy heat transport equations. The application of this criterion to the different experimental data shows that some reported eddy diffusion coefficients do not meet this criterion. For example, the large values of these coefficients (1 × 107 cm2 s−1 estimated in the Turbulent Oxygen Mixing Experiment (TOMEX do not correspond to this criterion. The Ked values inferred at high latitudes by Lübken (1997 meet this criterion for summer and winter polar data, but the Ked values for summer at low latitudes
Liu, Zhijian; Liu, Kejun; Li, Hao; Zhang, Xinyu; Jin, Guangya; Cheng, Kewei
2015-01-01
Measurements of heat collection rate and heat loss coefficient are crucial for the evaluation of in service water-in-glass evacuated tube solar water heaters. However, conventional measurement requires expensive detection devices and undergoes a series of complicated procedures. To simplify the measurement and reduce the cost, software based on artificial neural networks for measuring heat collection rate and heat loss coefficient of water-in-glass evacuated tube solar water heaters was developed. Using multilayer feed-forward neural networks with back-propagation algorithm, we developed and tested our program on the basis of 915measuredsamples of water-in-glass evacuated tube solar water heaters. This artificial neural networks-based software program automatically obtained accurate heat collection rateand heat loss coefficient using simply "portable test instruments" acquired parameters, including tube length, number of tubes, tube center distance, heat water mass in tank, collector area, angle between tubes and ground and final temperature. Our results show that this software (on both personal computer and Android platforms) is efficient and convenient to predict the heat collection rate and heat loss coefficient due to it slow root mean square errors in prediction. The software now can be downloaded from http://t.cn/RLPKF08. PMID:26624613
International Nuclear Information System (INIS)
Lee, Seung Moo; Won, Jaihyung; Yim, Soyoung; Park, Se Jun; Choi, Jongsik; Kim, Jeongtae; Lee, Hyeondeok; Byun, Dongjin
2012-01-01
The effect of deposition and thermal annealing temperatures on the dry etch rate of a-C:H films was investigated to increase our fundamental understanding of the relationship between thermal annealing and dry etch rate and to obtain a low dry etch rate hard mask. The hydrocarbon contents and hydrogen concentration were decreased with increasing deposition and annealing temperatures. The I(D)/I(G) intensity ratio and extinction coefficient of the a-C:H films were increased with increasing deposition and annealing temperatures because of the increase of sp 2 bonds in the a-C:H films. There was no relationship between the density of the unpaired electrons and the deposition temperature, or between the density of the unpaired electrons and the annealing temperature. However, the thermally annealed a-C:H films had fewer unpaired electrons compared with the as-deposited ones. Transmission electron microscopy analysis showed the absence of any crystallographic change after thermal annealing. The density of the as-deposited films was increased with increasing deposition temperature. The density of the 600 °C annealed a-C:H films deposited under 450 °C was decreased but at 550 °C was increased, and the density of all 800 °C annealed films was increased. The dry etch rate of the as-deposited a-C:H films was negatively correlated with the deposition temperature. The dry etch rate of the 600 °C annealed a-C:H films deposited at 350 °C and 450 °C was faster than that of the as-deposited film and that of the 800 °C annealed a-C:H films deposited at 350 °C and 450 °C was 17% faster than that of the as-deposited film. However, the dry etch rate of the 550 °C deposited a-C:H film was decreased after annealing at 600 °C and 800 °C. The dry etch rate of the as-deposited films was decreased with increasing density but that of the annealed a-C:H films was not. These results indicated that the dry etch rate of a-C:H films for dry etch hard masks can be further decreased by
Shizgal, Bernie D.; Chikhaoui, Aziz
2006-06-01
The present paper considers a detailed analysis of the nonequilibrium effects for a model reactive system with the Chapman-Eskog (CE) solution of the Boltzmann equation as well as an explicit time dependent solution. The elastic cross sections employed are a hard sphere cross section and the Maxwell molecule cross section. Reactive cross sections which model reactions with and without activation energy are used. A detailed comparison is carried out with these solutions of the Boltzmann equation and the approximation introduced by Cukrowski and coworkers [J. Chem. Phys. 97 (1992) 9086; Chem. Phys. 89 (1992) 159; Physica A 188 (1992) 344; Chem. Phys. Lett. A 297 (1998) 402; Physica A 275 (2000) 134; Chem. Phys. Lett. 341 (2001) 585; Acta Phys. Polonica B 334 (2003) 3607.] based on the temperature of the reactive particles. We show that the Cukrowski approximation has limited applicability for the large class of reactive systems studied in this paper. The explicit time dependent solutions of the Boltzmann equation demonstrate that the CE approach is valid only for very slow reactions for which the corrections to the equilibrium rate coefficient are very small.
Theoretical estimation of Photons flow rate Production in quark gluon interaction at high energies
Al-Agealy, Hadi J. M.; Hamza Hussein, Hyder; Mustafa Hussein, Saba
2018-05-01
photons emitted from higher energetic collisions in quark-gluon system have been theoretical studied depending on color quantum theory. A simple model for photons emission at quark-gluon system have been investigated. In this model, we use a quantum consideration which enhances to describing the quark system. The photons current rate are estimation for two system at different fugacity coefficient. We discussion the behavior of photons rate and quark gluon system properties in different photons energies with Boltzmann model. The photons rate depending on anisotropic coefficient : strong constant, photons energy, color number, fugacity parameter, thermal energy and critical energy of system are also discussed.
Heat transfer corrected isothermal model for devolatilization of thermally-thick biomass particles
DEFF Research Database (Denmark)
Luo, Hao; Wu, Hao; Lin, Weigang
Isothermal model used in current computational fluid dynamic (CFD) model neglect the internal heat transfer during biomass devolatilization. This assumption is not reasonable for thermally-thick particles. To solve this issue, a heat transfer corrected isothermal model is introduced. In this model......, two heat transfer corrected coefficients: HT-correction of heat transfer and HR-correction of reaction, are defined to cover the effects of internal heat transfer. A series of single biomass devitalization case have been modeled to validate this model, the results show that devolatilization behaviors...... of both thermally-thick and thermally-thin particles are predicted reasonable by using heat transfer corrected model, while, isothermal model overestimate devolatilization rate and heating rate for thermlly-thick particle.This model probably has better performance than isothermal model when it is coupled...
Directory of Open Access Journals (Sweden)
Asif Mahmood
Full Text Available Solar energy is the cleanest, renewable and most abundant source of energy available on earth. The main use of solar energy is to heat and cool buildings, heat water and to generate electricity. There are two types of solar energy collection system, the photovoltaic systems and the solar thermal collectors. The efficiency of any solar thermal system depend on the thermophysical properties of the operating fluids and the geometry/length of the system in which fluid is flowing. In the present research a simplified mathematical model for the solar thermal collectors is considered in the form of non-uniform unsteady stretching surface. The flow is induced by a non-uniform stretching of the porous sheet and the uniform magnetic field is applied in the transverse direction to the flow. The non-Newtonian Maxwell fluid model is utilized for the working fluid along with slip boundary conditions. Moreover the high temperature effect of thermal radiation and temperature dependent thermal conductivity are also included in the present model. The mathematical formulation is carried out through a boundary layer approach and the numerical computations are carried out for cu-water and TiO2-water nanofluids. Results are presented for the velocity and temperature profiles as well as the skin friction coefficient and Nusselt number and the discussion is concluded on the effect of various governing parameters on the motion, temperature variation, velocity gradient and the rate of heat transfer at the boundary. Keywords: Solar energy, Thermal collectors, Maxwell-nanofluid, Thermal radiation, Partial slip, Variable thermal conductivity
Liu, Zhijian; Li, Hao; Tang, Xindong; Zhang, Xinyu; Lin, Fan; Cheng, Kewei
2016-01-01
Heat collection rate and heat loss coefficient are crucial indicators for the evaluation of in service water-in-glass evacuated tube solar water heaters. However, the direct determination requires complex detection devices and a series of standard experiments, wasting too much time and manpower. To address this problem, we previously used artificial neural networks and support vector machine to develop precise knowledge-based models for predicting the heat collection rates and heat loss coefficients of water-in-glass evacuated tube solar water heaters, setting the properties measured by "portable test instruments" as the independent variables. A robust software for determination was also developed. However, in previous results, the prediction accuracy of heat loss coefficients can still be improved compared to those of heat collection rates. Also, in practical applications, even a small reduction in root mean square errors (RMSEs) can sometimes significantly improve the evaluation and business processes. As a further study, in this short report, we show that using a novel and fast machine learning algorithm-extreme learning machine can generate better predicted results for heat loss coefficient, which reduces the average RMSEs to 0.67 in testing.
Recommended data on proton-ion collision rate coefficients for Fe X-Fe XV ions
International Nuclear Information System (INIS)
Skobelev, I.; Murakami, I.; Kato, T.
2006-01-01
The proton-ion collisions are important for excitation of some ion levels in a high-temperature low density plasma. In the present work evaluation of data obtained for proton-induced transitions in Fe X - Fe XV ions with the help of different theoretical methods is carried out. It is suggested a simple analytical formula with 7 parameters allowing to describe dependency of proton rate coefficient on proton temperature in an enough wide temperature range. The values of free parameters have been determined by fitting of approximation formula to numerical data and are presented for recommended data together with fitting accuracies. By comparing of proton collision rates with electron ones it is shown that proton impact excitation processes may be important for Fe X, XI, XIII-XV ions. The results obtained can be used for plasma kinetics calculations and for development of spectroscopy methods of plasma diagnostics. (author)
Pépino, Marc; Goyer, Katerine; Magnan, Pierre
2015-11-01
Temperature is the primary environmental factor affecting physiological processes in ectotherms. Heat-transfer models describe how the fish's internal temperature responds to a fluctuating thermal environment. Specifically, the rate coefficient (k), defined as the instantaneous rate of change in body temperature in relation to the difference between ambient and body temperature, summarizes the combined effects of direct thermal conduction through body mass, passive convection (intracellular and intercellular fluids) and forced convective heat transfer (cardiovascular system). The k-coefficient is widely used in fish ecology to understand how body temperature responds to changes in water temperature. The main objective of this study was to estimate the k-coefficient of brook charr equipped with internal temperature-sensitive transmitters in controlled laboratory experiments. Fish were first transferred from acclimation tanks (10°C) to tanks at 14, 19 or 23°C (warming experiments) and were then returned to the acclimation tanks (10°C; cooling experiments), thus producing six step changes in ambient temperature. We used non-linear mixed models to estimate the k-coefficient. Model comparisons indicated that the model incorporating the k-coefficient as a function of absolute temperature difference (dT: 4, 9 and 13°C) best described body temperature change. By simulating body temperature in a heterogeneous thermal environment, we provide theoretical predictions of maximum excursion duration between feeding and resting areas. Our simulations suggest that short (i.e. behaviour adopted by cold freshwater fish species to sustain body temperature below a critical temperature threshold, enabling them to exploit resources in an unfavourable thermal environment. © 2015. Published by The Company of Biologists Ltd.
Torr, D. G.; Orsini, N.
1978-01-01
The Atmosphere Explorer (AE) data are reexamined in the light of new laboratory measurements of the N2(+) recombination rate coefficient alpha. The new measurements support earlier measurements which yielded values of alpha significantly lower than the AE values. It is found that the values for alpha determined from the satellite data can be reconciled with the laboratory measurements, if the charge exchange rate coefficient for O(+)(2D) with N2 is less than one-quarter of that derived in the laboratory by Rutherford and Vroom (1971).
International Nuclear Information System (INIS)
Hall, G.; Marsden, B.J.; Fok, A.; Smart, J.
2002-01-01
In the 1960s, J.H.W. Simmons derived a theoretical relationship between the coefficient of thermal expansion (CTE) and dimensional changes in irradiated graphite. At low irradiation dose, the theory was shown to be consistent with experimental observations. However, at higher doses the results diverge. Despite this, modified versions of this theory have been used as the basis of the design and life prediction calculations for graphite-moderated reactors. This paper revisits Simmons's theory, summarising the assumptions made in its derivation. The paper then modifies and applies the theory to the dimensional change and CTE change behaviour in isotropic nuclear graphite, making use of trends in irradiated behaviour recently derived using finite element analyses. The importance of these issues to present HTR technology is that the life of HTR graphite components is related to their irradiated dimensional change behaviour. A more in depth understanding of this behaviour will allow suitable graphite material to be selected or new graphite types to be developed. (author)
Measured thermal and fast neutron fluence rates ATR Cycle 101-B, October 11, 1993--November 27, 1993
International Nuclear Information System (INIS)
Murray, R.K.; Rogers, J.W.
1994-01-01
This report contains the thermal (2200 m/s) and fast (E>lMeV) neutron fluence rate data for ATR Cycle 101-B which were measured by the Radiation Measurements Laboratory (RML) as requested by the Power Reactor Programs (ATR Experiments) Radiation Measurements Work Order. This report contains fluence rate values corresponding to the particular elevations (relative to the 80 ft. core elevation) where the measurements were taken. The data in this report consists of (1) a table of the ATR power history and distribution, (2) a hard copy listing of all thermal and fast neutron fluence rates, (3) plots of both the thermal and fast neutron fluence rates, and (4) a magnetic record (3.5 inch diskette) containing a listing of only the fast neutron fluence rates, their assigned elevations proper header identification of all monitor positions contained herein
Low-temperature thermal expansion
International Nuclear Information System (INIS)
Collings, E.W.
1986-01-01
This chapter discusses the thermal expansion of insulators and metals. Harmonicity and anharmonicity in thermal expansion are examined. The electronic, magnetic, an other contributions to low temperature thermal expansion are analyzed. The thermodynamics of the Debye isotropic continuum, the lattice-dynamical approach, and the thermal expansion of metals are discussed. Relative linear expansion at low temperatures is reviewed and further calculations of the electronic thermal expansion coefficient are given. Thermal expansions are given for Cu, Al and Ti. Phenomenologic thermodynamic relationships are also discussed
Compositional dependence of absorption coefficient and band-gap for Nb2O5-SiO2 mixture thin films
International Nuclear Information System (INIS)
Sancho-Parramon, Jordi; Janicki, Vesna; Zorc, Hrvoje
2008-01-01
The absorption coefficient of composite films consisting of niobia (Nb 2 O 5 ) and silica (SiO 2 ) mixtures is studied for photon energies around the band gap. The films were deposited by co-evaporation and their composition was varied by changing the ratio of deposition rates of the two materials. Both, as-deposited and thermally annealed films were characterized by different techniques: the absorption coefficient was determined by spectrophotometric measurements and the structural properties were investigated using infrared spectroscopy, transmission electron microscopy and X-ray diffraction. The correlation between the variations of absorption properties and film composition and structure is established. The absorption coefficients determined experimentally are compared with the results derived from effective medium theories in order to evaluate the suitability of these theories for the studied composites
International Nuclear Information System (INIS)
Wu, Jianhua; Zhang, Hailong; Zhang, Yang; Li, Jianwei; Wang, Xitao
2012-01-01
Highlights: ► Al–Cu/diamond composites have been produced by a squeeze casting method. ► Cu alloying is an effective approach to promoting interface bonding between metal matrix and diamond. ► Alloying Cu to Al matrix improves thermal conductivity and reduces coefficient of thermal expansion of the composites. -- Abstract: Al–Cu matrix composites reinforced with diamond particles (Al–Cu/diamond composites) have been produced by a squeeze casting method. Cu content added to Al matrix was varied from 0 to 3.0 wt.% to detect the effect on thermal conductivity and thermal expansion behavior of the resultant Al–Cu/diamond composites. The measured thermal conductivity for the Al–Cu/diamond composites increased from 210 to 330 W/m/K with increasing Cu content from 0 to 3.0 wt.%. Accordingly, the coefficient of thermal expansion (CTE) was tailored from 13 × 10 −6 to 6 × 10 −6 /K, which is compatible with the CTE of semiconductors in electronic packaging applications. The enhanced thermal conductivity and reduced coefficient of thermal expansion were ascribed to strong interface bonding in the Al–Cu/diamond composites. Cu addition has lowered the melting point and resulted in the formation of Al 2 Cu phase in Al matrix. This is the underlying mechanism responsible for the strengthening of Al–Cu/diamond interface. The results show that Cu alloying is an effective approach to promoting interface bonding between Al and diamond.
Thermal degradation of deoxynivalenol during maize bread baking.
Numanoglu, E; Gökmen, V; Uygun, U; Koksel, H
2012-01-01
The thermal degradation of deoxynivalenol (DON) was determined at isothermal baking conditions within the temperature range of 100-250°C, using a crust-like model, which was prepared with naturally contaminated maize flour. No degradation was observed at 100°C. For the temperatures of 150, 200 and 250°C, thermal degradation rate constants (k) were calculated and temperature dependence of DON degradation was observed by using Arrhenius equation. The degradation of DON obeyed Arrhenius law with a regression coefficient of 0.95. A classical bread baking operation was also performed at 250°C for 70 min and the rate of DON degradation in the bread was estimated by using the kinetic data derived from the model study. The crust and crumb temperatures recorded during bread baking were used to calculate the thermal degradation rate constants (k) and partial DON degradations at certain time intervals. Using these data, total degradation at the end of the entire baking process was predicted for both crust and crumb. This DON degradation was consistent with the experimental degradation data, confirming the accuracy of kinetic constants determined by means of the crust-like model.
International Nuclear Information System (INIS)
Arregui-Mena, José David; Margetts, Lee; Griffiths, D.V.; Lever, Louise; Hall, Graham; Mummery, Paul M.
2015-01-01
In this paper, the authors test the hypothesis that tiny spatial variations in material properties may lead to significant pre-service stresses in virgin graphite bricks. To do this, they have customised ParaFEM, an open source parallel finite element package, adding support for stochastic thermo-mechanical analysis using the Monte Carlo Simulation method. For an Advanced Gas-cooled Reactor brick, three heating cases have been examined: a uniform temperature change; a uniform temperature gradient applied through the thickness of the brick and a simulated temperature profile from an operating reactor. Results are compared for mean and stochastic properties. These show that, for the proof-of-concept analyses carried out, the pre-service von Mises stress is around twenty times higher when spatial variability of material properties is introduced. The paper demonstrates that thermal gradients coupled with material incompatibilities may be important in the generation of stress in nuclear graphite reactor bricks. Tiny spatial variations in coefficient of thermal expansion (CTE) and Young's modulus can lead to the presence of thermal stresses in bricks that are free to expand. - Highlights: • Open source software has been modified to include random variability in CTE and Young's modulus. • The new software closely agrees with analytical solutions and commercial software. • Spatial variations in CTE and Young's modulus produce stresses that do not occur with mean values. • Material variability may induce pre-service stress in virgin graphite.
Energy Technology Data Exchange (ETDEWEB)
Arregui-Mena, José David, E-mail: jose.arreguimena@postgrad.manchester.ac.uk [School of Mechanical, Aerospace, and Civil Engineering, University of Manchester, Oxford Road, Manchester, M13 9PL (United Kingdom); Margetts, Lee, E-mail: lee.margetts@manchester.ac.uk [School of Mechanical, Aerospace, and Civil Engineering, University of Manchester, Oxford Road, Manchester, M13 9PL (United Kingdom); Griffiths, D.V., E-mail: d.v.griffiths@mines.edu [Colorado School of Mines, 1500 Illinois St, Golden, CO 80401 (United States); Lever, Louise, E-mail: louise.lever@manchester.ac.uk [Research Computing, University of Manchester, Oxford Road, Manchester, M13 9PL (United Kingdom); Hall, Graham, E-mail: graham.n.hall@manchester.ac.uk [School of Mechanical, Aerospace, and Civil Engineering, University of Manchester, Oxford Road, Manchester, M13 9PL (United Kingdom); Mummery, Paul M., E-mail: paul.m.mummery@manchester.ac.uk [School of Mechanical, Aerospace, and Civil Engineering, University of Manchester, Oxford Road, Manchester, M13 9PL (United Kingdom)
2015-10-15
In this paper, the authors test the hypothesis that tiny spatial variations in material properties may lead to significant pre-service stresses in virgin graphite bricks. To do this, they have customised ParaFEM, an open source parallel finite element package, adding support for stochastic thermo-mechanical analysis using the Monte Carlo Simulation method. For an Advanced Gas-cooled Reactor brick, three heating cases have been examined: a uniform temperature change; a uniform temperature gradient applied through the thickness of the brick and a simulated temperature profile from an operating reactor. Results are compared for mean and stochastic properties. These show that, for the proof-of-concept analyses carried out, the pre-service von Mises stress is around twenty times higher when spatial variability of material properties is introduced. The paper demonstrates that thermal gradients coupled with material incompatibilities may be important in the generation of stress in nuclear graphite reactor bricks. Tiny spatial variations in coefficient of thermal expansion (CTE) and Young's modulus can lead to the presence of thermal stresses in bricks that are free to expand. - Highlights: • Open source software has been modified to include random variability in CTE and Young's modulus. • The new software closely agrees with analytical solutions and commercial software. • Spatial variations in CTE and Young's modulus produce stresses that do not occur with mean values. • Material variability may induce pre-service stress in virgin graphite.
Ng, Maggie; Mok, Daniel K W; Lee, Edmond P F; Dyke, John M
2017-09-07
A theoretical study, involving the calculation of reaction enthalpies, activation energies, mechanisms, and rate coefficients, was made of the reaction of hydroxyl radicals with methyl nitrate, an important process for methyl nitrate removal in the earth's atmosphere. Four reaction channels were considered: formation of H 2 O + CH 2 ONO 2 , CH 3 OOH + NO 2 , CH 3 OH + NO 3 , and CH 3 O + HNO 3 . For all channels, geometry optimization and frequency calculations were performed at the M06-2X/6-31+G** level, while relative energies were improved at the UCCSD(T*)-F12/CBS level. The major channel is found to be the H abstraction channel, to give the products H 2 O + CH 2 ONO 2 . The reaction enthalpy (ΔH 298 K RX ) of this channel is computed as -17.90 kcal mol -1 . Although the other reaction channels are also exothermic, their reaction barriers are high (>24 kcal mol -1 ), and therefore these reactions do not contribute to the overall rate coefficient in the temperature range considered (200-400 K). Pathways via three transition states were identified for the H abstraction channel. Rate coefficients were calculated for these pathways at various levels of variational transition state theory including tunneling. The results obtained are used to distinguish between two sets of experimental rate coefficients, measured in the temperature range of 200-400 K, one of which is approximately an order of magnitude greater than the other. This comparison, as well as the temperature dependence of the computed rate coefficients, shows that the lower experimental values are favored. The implications of the results to atmospheric chemistry are discussed.
Hnida, Katarzyna E; Pilarczyk, Kacper; Knutelski, Marcin; Marzec, Mateusz; Gajewska, Marta; Kosonowski, Artur; Chlebda, Damian; Lis, Bartłomiej; Przybylski, Marek
2018-04-06
The growing demand for clean energy catalyzes the development of new devices capable of generating electricity from renewable energy resources. One of the possible approaches focuses on the use of thermoelectric materials (TE), which may utilize waste heat, water, and solar thermal energy to generate electrical power. An improvement of the performance of such devices may be achieved through the development of composites made of an organic matrix filled with nanostructured thermoelectric materials working in a synergetic way. The first step towards such designs requires a better understanding of the fundamental interactions between available materials. In this paper, this matter is investigated and the questions regarding the change of electrical and thermal properties of nanocomposites based on low-conductive polypyrrole enriched with bismuth nanowires of well-defined geometry and morphology is answered. It is clearly demonstrated that the electrical conductivity and the Seebeck coefficient may be tuned either simultaneously or separately within particular Bi NWs content ranges, and that both parameters may be increased at the same time. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
New rate coefficients of CS in collision with para- and ortho-H2 and astrophysical implications
Denis-Alpizar, Otoniel; Stoecklin, Thierry; Guilloteau, Stéphane; Dutrey, Anne
2018-05-01
Astronomers use the CS molecule as a gas mass tracer in dense regions of the interstellar medium, either to measure the gas density through multi-line observations or the level of turbulence. This necessarily requires the knowledge of the rates coefficients with the most common colliders in the interstellar medium, He and H2. In the present work, the close coupling collisional rates are computed for the first thirty rotational states of CS in collision with para- and ortho-H2 using a recent rigid rotor potential energy surface. Some radiative transfer calculations, using typical astrophysical conditions, are also performed to test this new set of data and to compare with the existing ones.
Nanoscale Thermoelectrics: A Study of the Absolute Seebeck Coefficient of Thin Films
Mason, Sarah J.
The worlds demand for energy is ever increasing. Likewise, the environmental impact of climate change due generating that energy through combustion of fossil fuels is increasingly alarming. Due to these factors new sources of renewable energies are constantly being sought out. Thermoelectric devices have the ability to generate clean, renewable, energy out of waste heat. However promising that is, their inefficiency severely inhibits applicability and practical use. The usefulness of a thermoelectric material increases with the dimensionless quantity, ZT, which depends on the Seebeck coefficient and electrical and thermal conductivity. These characteristic material parameters have interdependent energy transport contributions that classically prohibit the optimization of one with out the detriment of another. Encouraging advancements of ZT have occurred in the past ten years due to the decoupling of the thermal and electrical conductivity. Further advancements are necessary in order to produce applicable devices. One auspicious way of decoupling or tuning energy transport properties, is through size reduction to the nanoscale. However, with reduced dimensions come complications in measuring material properties. Measurements of properties such as the Seebeck coefficient, S, are primarily contingent upon the measurement apparatus. The Seebeck coefficient is defined as the amount of voltage generated by a thermal gradient. Measuring a thermally generated voltage by traditional methods gives, the voltage measured as a linear function of the Seebeck coefficient of the leads and of the material being tested divided by the applied thermal gradient. If accurate values of the Seebeck coefficients of the leads are available, simple subtraction provides the answer. This is rarely the case in nanoscale measurement devices with leads exclusively made from thin film materials that do not have well known bulk-like thermopower values. We have developed a technique to directly
International Nuclear Information System (INIS)
Davidson, Sean R H; Sherar, Michael D
2003-01-01
Urethral cooling catheters are used to prevent thermal damage to the urethra during thermal therapy of the prostate. Quantification of a catheter's heat transfer characteristics is necessary for prediction of the catheter's influence on the temperature and thermal dose distribution in periurethral tissue. Two cooling catheters with different designs were examined: the Dornier Urowave catheter and a prototype device from BSD Medical Corp. A convection coefficient, h, was used to characterize the cooling ability of each catheter. The value of the convection coefficient (h = 330 W m -2 deg C -1 for the Dornier catheter, h = 160 W m -2 deg C -1 for the BSD device) was obtained by comparing temperatures measured in a tissue-equivalent phantom material to temperatures predicted by a finite element method simulation of the phantom experiments. The coefficient was found to be insensitive to the rate of coolant flow inside the catheter between 40 and 120 ml min -1 . The convection coefficient method for modelling urethral catheters was incorporated into simulations of microwave heating of the prostate. Results from these simulations indicate that the Dornier device is significantly more effective than the BSD catheter at cooling the tissue surrounding the urethra
Directory of Open Access Journals (Sweden)
Paweł Sędłak
2017-01-01
Full Text Available Laboratorial two-body wear testing was carried out in order to assess effects of polypropylene modification by impregnating it with oils on friction coefficient and wear in comparison to those parameters of unmodified polypropylene, Teflon, and polyamide during operation under conditions of sliding friction without lubrication. Wear behaviour of the tested specimens was investigated using ASTM G77-98 standard wear test equipment. Recording program made it possible to visualise and record the following parameters: rotational speed and load, linear wear, friction coefficient, temperature of the specimen, and ambient temperature. In addition, wear mechanisms of the analysed materials were determined with use of scanning electron microscopy. In the case of the remaining tested polymers, the most important mechanism of wear was adhesion (PP, PTFE, PA 6.6, and PA MoS2, microcutting (PTFE, PA 6.6, and PA MoS2, fatigue wear (PTFE, forming “roll-shaped particles” combined with plastic deformation (PA 6.6 and PA MoS2, and thermal wear (PP. Impregnation of polypropylene with engine oil, gear oil, or RME results in significant reduction of friction coefficient and thus of friction torque, in relation to not only unmodified polypropylene but also the examined polyamide and Teflon.
Barforoush, M. S. M.; Saedodin, S.
2018-01-01
This article investigates the thermal performance of convective-radiative annular fins with a step reduction in local cross section (SRC). The thermal conductivity of the fin's material is assumed to be a linear function of temperature, and heat transfer coefficient is assumed to be a power-law function of surface temperature. Moreover, nonzero convection and radiation sink temperatures are included in the mathematical model of the energy equation. The well-known differential transformation method (DTM) is used to derive the analytical solution. An exact analytical solution for a special case is derived to prove the validity of the obtained results from the DTM. The model provided here is a more realistic representation of SRC annular fins in actual engineering practices. Effects of many parameters such as conduction-convection parameters, conduction-radiation parameter and sink temperature, and also some parameters which deal with step fins such as thickness parameter and dimensionless parameter describing the position of junction in the fin on the temperature distribution of both thin and thick sections of the fin are investigated. It is believed that the obtained results will facilitate the design and performance evaluation of SRC annular fins.
Transport coefficients in Lorentz plasmas with the power-law kappa-distribution
International Nuclear Information System (INIS)
Jiulin, Du
2013-01-01
Transport coefficients in Lorentz plasma with the power-law κ-distribution are studied by means of using the transport equation and macroscopic laws of Lorentz plasma without magnetic field. Expressions of electric conductivity, thermoelectric coefficient, and thermal conductivity for the power-law κ-distribution are accurately derived. It is shown that these transport coefficients are significantly modified by the κ-parameter, and in the limit of the parameter κ→∞ they are reduced to the standard forms for a Maxwellian distribution
Thermal conductivity and diffusivity of biomaterials measured with self-heated thermistors
Valvano, J. W.; Cochran, J. R.; Diller, K. R.
1985-05-01
This paper presents an experimental method to measure the thermal conductivity and thermal diffusivity of biomaterials. Self-heated thermistor probes, inserted into the tissue of interest, are used to deliver heat as well as to monitor the rate of heat removal. An empirical calibration procedure allows accurate thermal-property measurements over a wide range of tissue temperatures. Operation of the instrument in three media with known thermal properties shows the uncertainty of measurements to be about 2%. The reproducibility is 0.5% for the thermal-conductivity measurements and 2% for the thermal-diffusivity measurements. Thermal properties were measured in dog, pig, rabbit, and human tissues. The tissues included kidney, spleen, liver, brain, heart, lung, pancreas, colon cancer, and breast cancer. Thermal properties were measured for 65 separate tissue samples at 3, 10, 17, 23, 30, 37, and 45°C. The results show that the temperature coefficient of biomaterials approximates that of water.
Thermal Performance of the Storage Brick Containing Microencapsulated PCM
International Nuclear Information System (INIS)
Lee, Dong Gyu
1998-02-01
The utilization of microencapsulated phase change materials(PCMs) provides several advantages over conventional PCM application. The heat storage system, as well as heat recovery system, can be built to a smaller size than the normal systems for a given thermal cycling capacity. This microencapsulated PCM technique has not yet been commercialized, however. In this work sodium acetate trihydrate(CH 3 COONa · 3H 2 O) was selected for the PCM and was encapsulated. This microencapsulated PCM was mixed with cement mortar for utilization as a floor heating system. In this experiment performed here the main purpose was to investigate the thermal performance of a storage brick with microencapsulated PCM concentration. The thermal performance of this storage brick is dependent on PCM concentration, flow rate and cooling temperature of the heat transfer fluid, etc. The results showed that cycle time was shortened as the PCM content was increased and as the mass flow rate was increased. The same effect was obtained when the cooling temperature was decreased. For each thermal storage brick the overall heat transfer coefficient(U-value) was constant for a 0% brick, but was increased with time for the bricks containing microencapsulated PCM. For the same mass flow rate, as the cooling temperature decreased, the amount of heat withdrawn increased, and in particular a critical cooling temperature was found for each thermal storage brick. The average effectiveness of each thermal storage brick was found to be approximately 48%, 51% and 58% respectively
Directory of Open Access Journals (Sweden)
Omar Rodriguez
2016-12-01
Full Text Available Silica-based and borate-based glass series, with increasing amounts of TiO2 incorporated, are characterized in terms of their mechanical properties relevant to their use as metallic coating materials. It is observed that borate-based glasses exhibit CTE (Coefficient of Thermal Expansion closer to the substrate’s (Ti6Al4V CTE, translating into higher mode I critical strain energy release rates of glasses and compressive residual stresses and strains at the coating/substrate interface, outperforming the silica-based glasses counterparts. An increase in the content of TiO2 in the glasses results in an increase in the mode I critical strain energy release rate for both the bulk glass and for the coating/substrate system, proving that the addition of TiO2 to the glass structure enhances its toughness, while decreasing its bulk hardness. Borate-based glass BRT3, with 15 mol % TiO2 incorporated, exhibits superior properties overall compared to the other proposed glasses in this work, as well as 45S5 Bioglass® and Pyrex.
International Nuclear Information System (INIS)
Ferguson, W George
2009-01-01
The behaviour of metals as a function of rate of loading, strain rate, and temperature is discussed in terms of previous work by the author. Strain rates range from 10 -3 s -1 , obtained in a standard tensile testing machine, to 10 2 s -1 obtained in a hydraulic piston driven machine and up to 10 4 s -1 , very high strain rates with a Kolsky split Hopkinson bar using shear type loading. At rates less 10 3 s -1 the strength is a function of strain rate and temperature, is thermally activated and governed by the stress-assisted thermal activation of dislocations across short-range barriers in the crystal. At very high strain rates however the behaviour is controlled by interaction of dislocations with either phonons or electrons, giving a strength proportional to strain rate. The compressive strength of small clear samples of wood, Pinus radiata and Kahikatea, determined over the strain rate range 10 -3 s -1 to 10 3 s -1 as a function of strain rate, temperature and moisture content shows the behaviour to again be thermally activated with the strength a function of stain rate, temperature and moisture content. A rate theory of deformation is developed where the yield behaviour of wood is assumed to result from the stress-assisted thermally activated motion of elementary fibrils over short-range barriers. The moisture is assumed to affect the bond energy between elementary fibrils and the barrier energy is taken to be a linear decreasing function of increasing moisture content and the moisture to act like a plasticiser in separating the elementary fibrils. The theory more than adequately explains the observed behaviour.
Directory of Open Access Journals (Sweden)
Balla Hyder H.
2015-01-01
Full Text Available Cu and Zn-water nanofluid is a suspension of the Cu and Zn nanoparticles with the size 50 nm in the water base fluid for different volume fractions to enhance its Thermophysical properties. The determination and measuring the enhancement of Thermophysical properties depends on many limitations. Nanoparticles were suspended in a base fluid to prepare a nanofluid. A coated transient hot wire apparatus was calibrated after the building of the all systems. The vibro-viscometer was used to measure the dynamic viscosity. The measured dynamic viscosity and thermal conductivity with all parameters affected on the measurements such as base fluids thermal conductivity, volume factions, and the temperatures of the base fluid were used as input to the Artificial Neural Fuzzy inference system to modeling both dynamic viscosity and thermal conductivity of the nanofluids. Then, the ANFIS modeling equations were used to calculate the enhancement in heat transfer coefficient using CFD software. The heat transfer coefficient was determined for flowing flow in a circular pipe at constant heat flux. It was found that the thermal conductivity of the nanofluid was highly affected by the volume fraction of nanoparticles. A comparison of the thermal conductivity ratio for different volume fractions was undertaken. The heat transfer coefficient of nanofluid was found to be higher than its base fluid. Comparisons of convective heat transfer coefficients for Cu and Zn nanofluids with the other correlation for the nanofluids heat transfer enhancement are presented. Moreover, the flow demonstrates anomalous enhancement in heat transfer nanofluids.
International Nuclear Information System (INIS)
Valdés, José R.; Rodríguez, José M.; Saumell, Javier; Pütz, Thomas
2014-01-01
Highlights: • We develop a methodology for the parametric modelling of flow in hydraulic valves. • We characterize the flow coefficients with a generic function with two parameters. • The parameters are derived from CFD simulations of the generic geometry. • We apply the methodology to two cases from the automotive brake industry. • We validate by comparing with CFD results varying the original dimensions. - Abstract: The main objective of this work is to develop a methodology for the parametric modelling of the flow rate in hydraulic valve systems. This methodology is based on the derivation, from CFD simulations, of the flow coefficient of the critical restrictions as a function of the Reynolds number, using a generalized square root function with two parameters. The methodology is then demonstrated by applying it to two completely different hydraulic systems: a brake master cylinder and an ABS valve. This type of parametric valve models facilitates their implementation in dynamic simulation models of complex hydraulic systems
Santos, M V; Sansinena, M; Zaritzky, N; Chirife, J
2012-01-01
In oocyte vitrification, plunging directly into liquid nitrogen favor film boiling and strong nitrogen vaporization. A survey of literature values of heat transfer coefficients (h) for film boiling of small metal objects with different geometries plunged in liquid nitrogen revealed values between 125 to 1000 W per per square m per K. These h values were used in a numerical simulation of cooling rates of two oocyte vitrification devices (open-pulled straw and Cryotop), plunged in liquid and slush nitrogen conditions. Heat conduction equation with convective boundary condition was considered a linear mathematical problem and was solved using the finite element method applying the variational formulation. COMSOL Multiphysics was used to simulate the cooling process of the systems. Predicted cooling rates for OPS and Cryotop when cooled at -196 degree C (liquid nitrogen) or -207 degree C (average for slush nitrogen) for heat transfer coefficients estimated to be representative of film boiling, indicated lowering the cooling temperature produces only a maximum 10 percent increase in cooling rates; confirming the main benefit of plunging in slush over liquid nitrogen does not arise from their temperature difference. Numerical simulations also demonstrated that a hypothetical four-fold increase in the cooling rate of vitrification devices when plunging in slush nitrogen would be explained by an increase in heat transfer coefficient. This improvement in heat transfer (i.e., high cooling rates) in slush nitrogen is attributed to less or null film boiling when a sample is placed in slush (mixture of liquid and solid nitrogen) because it first melts the solid nitrogen before causing the liquid to boil and form a film.
Mechanical, Hygric and Thermal Properties of Flue Gas Desulfurization Gypsum
Directory of Open Access Journals (Sweden)
P. Tesárek
2004-01-01
Full Text Available The reference measurements of basic mechanical, thermal and hygric parameters of hardened flue gas desulfurization gypsum are carried out. Moisture diffusivity, water vapor diffusion coefficient, thermal conductivity, volumetric heat capacity and linear thermal expansion coefficient are determined with the primary aim of comparison with data obtained for various types of modified gypsum in the future.
Calculation of fuel and moderator temperature coefficients in APR1400 nuclear reactor by MVP code
International Nuclear Information System (INIS)
Pham Tuan Nam; Le Thi Thu; Nguyen Huu Tiep; Tran Viet Phu
2014-01-01
In this project, these fuel and moderator temperature coefficients were calculated in APR1400 nuclear reactor by MVP code. APR1400 is an advanced water pressurized reactor, that was researched and developed by Korea Experts, its electric power is 1400 MW. The neutronics calculations of full core is very important to analysis and assess a reactor. Results of these calculation is input data for thermal-hydraulics calculations, such as fuel and moderator temperature coefficients. These factors describe the self-safety characteristics of nuclear reactor. After obtaining these reactivity parameters, they were used to re-run the thermal hydraulics calculations in LOCA and RIA accidents. These thermal-hydraulics results were used to analysis effects of reactor physics parameters to thermal hydraulics situation in nuclear reactors. (author)
Mixed Convection Flow along a Stretching Cylinder in a Thermally Stratified Medium
Directory of Open Access Journals (Sweden)
Swati Mukhopadhyay
2012-01-01
Full Text Available An analysis for the axisymmetric laminar boundary layer mixed convection flow of a viscous and incompressible fluid towards a stretching cylinder immersed in a thermally stratified medium is presented in this paper. Similarity transformation is employed to convert the governing partial differential equations into highly nonlinear ordinary differential equations. Numerical solutions of these equations are obtained by a shooting method. It is found that the heat transfer rate at the surface is lower for flow in a thermally stratified medium compared to that of an unstratified medium. Moreover, both the skin friction coefficient and the heat transfer rate at the surface are larger for a cylinder compared to that for a flat plate.
International Nuclear Information System (INIS)
Egorov, Gennadiy I.; Makarov, Dmitriy M.; Kolker, Arkadiy M.
2013-01-01
Highlights: ► Molar isothermal compressions and molar isobaric expansions were evaluated. ► Coefficients of thermal pressure and internal pressure were obtained. ► Concentration dependences of coefficients under study display extremes. ► Temperature and pressure dependences of internal pressure of the mixture were linear. -- Abstract: Molar isothermal compressions, molar isobaric expansions, molar coefficients of thermal pressure, and internal pressure were calculated over the whole concentration range of {water (1) + tert-butanol (2)} mixture at pressures from 0.1 to 100 MPa and temperatures from 278.15 to 323.15 K. It was revealed that the extremes, observed on concentration dependences of molar isothermal compression K T,m and molar isobaric expansion E P,m of the mixture, became more pronounced with pressure growth and temperature lowering. Values of molar thermal pressure coefficients of the mixture sharply rose at compositions with small TBA mole fraction and then decreased practically linearly with the alcohol content increasing. Temperature and pressure dependences of the mixture internal pressure were almost linear, and at low TBA concentrations changed significantly from the dependences of water, tert-butanol and their mixtures at large alcohol content
Rate coefficients for the reactions of ions with polar molecules at interstellar temperatures
International Nuclear Information System (INIS)
Adams, N.G.; Smith, D.; Clary, D.C.
1985-01-01
A theory has been developed recently which predicts that the rate coefficients, k, for the reactions of ions with polar molecules at low temperatures will be much greater than the canonical value of 10 -9 cm 3 s -1 . The new theory indicates that k is greatest for low-lying rotational sates and increases rapidly with decreasing temperature. We refer to recent laboratory measurements which validate the theory, present calculated values of k for the reactions of H + 3 ions with several polar molecules, and discuss their significance to interstellar chemistry. For the reactions of ions with molecules having large dipole moments, we recommend that k values as large as 10 -7 cm 3 s -1 should be used in ion-chemical models of low-temperature interstellar clouds
Neoclassical transport coefficients for tokamaks with bean-shaped flux surfaces
International Nuclear Information System (INIS)
Chang, C.S.; Kaye, S.M.
1990-11-01
Simple analytic representations of the neoclassical transport coefficients for indented flux surfaces are presented. It is shown that a transport coefficient for an indented flux surface can be expressed in terms of a linear combination of the previously known transport coefficients for two nonindented flux surfaces. Numerical calculations based on actual equilibria from the PBX-M tokamak indicate that, even for modestly indented flux surfaces, the ion neoclassical thermal transport can be over a factor of two smaller than in a circular plasma with the same midplane radius or with the equivalent areas. 6 refs., 5 figs., 1 tab
Origami structures for tunable thermal expansion
Boatti, Elisa; Bertoldi, Katia
Materials with engineered thermal expansion, capable of achieving targeted and extreme area/volume changes in response to variations in temperature, are important for a number of aerospace, optical, energy, and microelectronic applications. While most of the proposed structures with tunable coefficient of thermal expansion consist of bi-material 2D or 3D lattices, here we propose a periodic metastructure based on a bilayer Miura-Ori origami fold. We combine experiments and simulations to demonstrate that by tuning the geometrical and mechanical parameters an extremely broad range of thermal expansion coefficients can be obtained, spanning both negative and positive values. Additionally, the thermal properties along different directions can be adjusted independently. Differently from all previously reported systems, the proposed structure is non-porous.
Bon, S.A.F.; Chambard, G.; German, A.L.
1999-01-01
The rate coefficient for alkoxyamine C-O bond homolysis has been determined over a range of temperatures for both 2-tert-butoxy-1-phenyl-1-(1-oxy-2,2,6,6-tetramethylpiperidinyl)ethane (1) and a polystyrene-TEMPO (approximately 75 units) adduct using quantitative ESR. In a thermostated solution of
Amide temperature coefficients in the protein G B1 domain
International Nuclear Information System (INIS)
Tomlinson, Jennifer H.; Williamson, Mike P.
2012-01-01
Temperature coefficients have been measured for backbone amide 1 H and 15 N nuclei in the B1 domain of protein G (GB1), using temperatures in the range 283–313 K, and pH values from 2.0 to 9.0. Many nuclei display pH-dependent coefficients, which were fitted to one or two pK a values. 1 H coefficients showed the expected behaviour, in that hydrogen-bonded amides have less negative values, but for those amides involved in strong hydrogen bonds in regular secondary structure there is a negative correlation between strength of hydrogen bond and size of temperature coefficient. The best correlation to temperature coefficient is with secondary shift, indicative of a very approximately uniform thermal expansion. The largest pH-dependent changes in coefficient are for amides in loops adjacent to sidechain hydrogen bonds rather than the amides involved directly in hydrogen bonds, indicating that the biggest determinant of the temperature coefficient is temperature-dependent loss of structure, not hydrogen bonding. Amide 15 N coefficients have no clear relationship with structure.
Directory of Open Access Journals (Sweden)
Boping Li
2015-01-01
Full Text Available At present, studies on the surface tension of air tunnel terrazzo under wind load and how regularly it is affected by temperature are relatively less, and the measured results of the thermal expansion coefficient of terrazzo have not yet been given. In this paper, based on the top terrazzo surface structure of the inner wall of the wind tunnel, the tensile performance tests of terrazzo surface layer are conducted, while the thermal expansion coefficient of the six terrazzo test blocks were tested. The tests and analysis show that the construction of terrazzo surface, based on the proposed construction process, can effectively guarantee the reliable cement performance for the binding layer between mortar and concrete base layer, terrazzo surface layer and the cement mortar layer. And the thermal expansion coefficient of terrazzo can be valued at 1.06e-5/ºC.
Multifunctional Lattices with Low Thermal Expansion and Low Thermal Conductivity
Xu, Hang; Liu, Lu; Pasini, Damiano
Systems in space are vulnerable to large temperature changes when travelling into and out of the Earth's shadow. Variations in temperature can lead to undesired geometric changes in susceptible applications requiring very fine precision. In addition, temperature-sensitive electronic equipment hosted in a satellite needs adequate thermal-control to guarantee a moderate ambient temperature. To address these specifications, materials with low coefficient of thermal expansion (CTE) and low coefficient of thermal conductivity (CTC) over a wide range of temperatures are often sought, especially for bearing components in satellites. Besides low CTE and low CTC, these materials should also provide desirable stiffness, strength and extraordinarily low mass. This work presents ultralightweight bi-material lattices with tunable CTE and CTC, besides high stiffness and strength. We show that the compensation of the thermal expansion and joint rotation at the lattice joints can be used as an effective strategy to tailor thermomechanical performance. Proof-of-concept lattices are fabricated from Al and Ti alloy sheets via a simple snap-fit technique and vacuum brazing, and their CTE and CTC are assessed via a combination of experiments and theory. Corresponding Author.
Energy Technology Data Exchange (ETDEWEB)
Crowther, David J.
1990-03-06
This research thesis addresses the field of fluid-wall thermal exchanges in which the notion of exchange coefficient is notably useful to design, size and optimise devices. A first part reports a bibliographical study which gives an overview of solutions envisaged to determine the convection coefficient in permanent regime with the use of flow sensors, as well as in transient regime. Then, the author reports the development of an unsteady method which is based on the analysis of the cooling kinetics of the front face of a convecting wall, after a unique energetic perturbation (an infinitely brief pulse, or a finite duration energy step). This method is applied to the general case (wall with finite thickness) and to the case of a semi-infinite wall which is typical of materials which are weak thermal conductors. This is extended to the case of good thermal conductors by considering a thermally thin wall. After a detailed description of the experimental bench, above-mentioned solutions are applied to insulating and good thermal conducting materials. In order to validate results of an analysis in transient regime, they are compared with measurements performed in permanent regime with a flow-metering technique. The study of the principle of the dissipation-based flow sensor, and its operation are reported. Experimental results are presented for both methods (pulse and flow sensor), and compared in order to highlight the interest of the unsteady method [French] Difficile a mesurer, le coefficient de convection reste cependant une grandeur necessaire au calcul et a l'optimisation de tout systeme thermique. L'amelioration des capteurs thermiques permet aujourd'hui de concevoir une methode optique, utilisable a distance, et non destructive. Nous proposons dans ce but, un procede de mesure en regime transitoire base sur la radiometrie photothermique impulsionnelle. L'analyse du regime de relaxation d'une paroi, apres une brusque elevation de temperature, permet de remonter
International Nuclear Information System (INIS)
Dalle Donne, M.; Dorner, S.
1980-12-01
Measurements have been performed of the density and volumetric thermal expansion coefficient of liquid sodium tetraborate (borax) and of sodium metaborate both pure and with two different amounts of UO 2 dissolved in each. These data are required for the design of core-catchers based on sodium borates. The measurements have been performed with the buoyancy method in the temperature range from 850 0 C to 1325 0 C. The data for the pure borax and for the sodium metaborate agree reasonably well with the data from the literature, giving confidence that the measurements are correct and the new data for the salts with UO 2 are reliable. (orig.) [de
Jedamzik, Ralf; Westerhoff, Thomas
2017-09-01
The coefficient of thermal expansion (CTE) and its spatial homogeneity from small to large formats is the most important property of ZERODUR. Since more than a decade SCHOTT has documented the excellent CTE homogeneity. It started with reviews of past astronomical telescope projects like the VLT, Keck and GTC mirror blanks and continued with dedicated evaluations of the production. In recent years, extensive CTE measurements on samples cut from randomly selected single ZERODUR parts in meter size and formats of arbitrary shape, large production boules and even 4 m sized blanks have demonstrated the excellent CTE homogeneity in production. The published homogeneity data shows single ppb/K peak to valley CTE variations on medium spatial scale of several cm down to small spatial scale of only a few mm mostly at the limit of the measurement reproducibility. This review paper summarizes the results also in respect to the increased CTE measurement accuracy over the last decade of ZERODUR production.
THERMAL CONSOLIDATION OF LAYERED POROUS HALF-SPACE TO VARIABLE THERMAL LOADING
Institute of Scientific and Technical Information of China (English)
BAI Bing
2006-01-01
An analytical method was derived for the thermal consolidation of layered,saturated porous half-space to variable thermal loading with time. In the coupled governing equations of linear thermoelastic media, the influences of thermo-osmosis effect and thermal filtration effect were introduced. Solutions in Laplace transform space were first obtained and then numerically inverted. The responses of a double-layered porous space subjected to exponential decaying thermal loading were studied. The influences of the differences between the properties of the two layers (e.g., the coefficient of thermal consolidation, elastic modulus) on thermal consolidation were discussed. The studies show that the coupling effects of displacement and stress fields on temperature field can be completely neglected, however, thc thermo-osmosis effect has an obvious influence on thermal responses.
International Nuclear Information System (INIS)
Suplicz, A.; Szabo, F.; Kovacs, J.G.
2013-01-01
Highlights: • BN, talc and TiO 2 in 30 vol% were compounded with polypropylene matrix. • According to the DSC measurements, the fillers are good nucleating agents. • The thermal conductivity of the fillers influences the cooling rate of the melt. • The higher the cooling rate is, the lower the crystallinity in the polymer matrix. - Abstract: Three different nano- and micro-sized ceramic powders (boron-nitride (BN), talc and titanium-dioxide (TiO 2 )) in 30 vol% have been compounded with a polypropylene (PP) matrix. Scanning electron microscopy (SEM) shows that the particles are dispersed smoothly in the matrix and larger aggregates cannot be discovered. The cooling gradients and the cooling rate in the injection-molded samples were estimated with numerical simulations and finite element analysis software. It was proved with differential scanning calorimetry (DSC) measurements that the cooling rate has significant influence on the crystallinity of the compounds. At a low cooling rate BN works as a nucleating agent so the crystallinity of the compound is higher than that of unfilled PP. On the other hand, at a high cooling rate, the crystallinity of the compound is lower than that of unfilled PP because of its higher thermal conductivity. The higher the thermal conductivity is, the higher the real cooling rate in the material, which influences the crystallization kinetics significantly
A study of temperature coefficients of reactivity for a Savannah River Site tritium-producing charge
International Nuclear Information System (INIS)
George, D.L.; Frost, R.L.
1991-01-01
Temperature coefficients of reactivity have been calculated for the Mark 22 assembly in the K-14 charge at the Savannah River Site. Temperature coefficients are the most important reactivity feedback mechanism in SRS reactors; they are used in all safety analyses performed in support of the Safety Analysis Report, and in operations to predict reactivity changes with control rod moves. The effects of the radial location of the assembly in the reactor, isotope depletion, and thermal expansion of the metal components on the temperature coefficients have also been investigated. With the exception of the dead space coefficient, all of the regional temperature coefficients were found to be negative or zero. All of the temperature coefficients become more negative with isotopic depletion over the fuel cycle. Coefficients also become more negative with increasing radial distance of the assembly from the center of the core; this is proven from first principles and confirmed by calculations. It was found that axial and radial thermal expansion effects on the metal fuel and target tubes counteract one another, indicating these effects do not need to be considered in future temperature coefficient calculations for the Mark 22 assembly. The moderator coefficient was found to be nonlinear with temperature; thus, the values derived for accidents involving increases in moderator temperature are significantly different than those for decreases in moderator temperature, although the moderator coefficient is always negative
Coupled electrochemical thermal modelling of a novel Li-ion battery pack thermal management system
International Nuclear Information System (INIS)
Basu, Suman; Hariharan, Krishnan S.; Kolake, Subramanya Mayya; Song, Taewon; Sohn, Dong Kee; Yeo, Taejung
2016-01-01
Highlights: • Three-dimensional electrochemical thermal model of Li-ion battery pack using computational fluid dynamics (CFD). • Novel pack design for compact liquid cooling based thermal management system. • Simple temperature estimation algorithm for the cells in the pack using the results from the model. • Sensitivity of the thermal performance to contact resistance has been investigated. - Abstract: Thermal management system is of critical importance for a Li-ion battery pack, as high performance and long battery pack life can be simultaneously achieved when operated within a narrow range of temperature around the room temperature. An efficient thermal management system is required to keep the battery temperature in this range, despite widely varying operating conditions. A novel liquid coolant based thermal management system, for 18,650 battery pack has been introduced herein. This system is designed to be compact and economical without compromising safety. A coupled three-dimensional (3D) electrochemical thermal model is constructed for the proposed Li-ion battery pack. The model is used to evaluate the effects of different operating conditions like coolant flow-rate and discharge current on the pack temperature. Contact resistance is found to have the strongest impact on the thermal performance of the pack. From the numerical solution, a simple and novel temperature correlation of predicting the temperatures of all the individual cells given the temperature measurement of one cell is devised and validated with experimental results. Such coefficients have great potential of reducing the sensor requirement and complexity in a large Li-ion battery pack, typical of an electric vehicle.
Ballesteros, Bernabé; Ceacero-Vega, Antonio A; Jiménez, Elena; Albaladejo, José
2015-04-01
As the result of biogenic and anthropogenic activities, large quantities of chemical compounds are emitted into the troposphere. Alkanes, in general, and cycloalkanes are an important chemical class of hydrocarbons found in diesel, jet and gasoline, vehicle exhaust emissions, and ambient air in urban areas. In general, the primary atmospheric fate of organic compounds in the gas phase is the reaction with hydroxyl radicals (OH). The oxidation by Cl atoms has gained importance in the study of atmospheric reactions because they may exert some influence in the boundary layer, particularly in marine and coastal environments, and in the Arctic troposphere. The aim of this paper is to study of the atmospheric reactivity of methylcylohexanes with Cl atoms and OH radicals under atmospheric conditions (in air at room temperature and pressure). Relative kinetic techniques have been used to determine the rate coefficients for the reaction of Cl atoms and OH radicals with methylcyclohexane, cis-1,4-dimethylcyclohexane, trans-1,4-dimethylcyclohexane, and 1,3,5-trimethylcyclohexane at 298 ± 2 K and 720 ± 5 Torr of air by Fourier transform infrared) spectroscopy and gas chromatography-mass spectrometry (GC-MS) in two atmospheric simulation chambers. The products formed in the reaction under atmospheric conditions were investigated using a 200-L Teflon bag and employing the technique of solid-phase microextraction coupled to a GC-MS. The rate coefficients obtained for the reaction of Cl atoms with the studied compounds are the following ones (in units of 10(-10) cm(3) molecule(-1) s(-1)): (3.11 ± 0.16), (2.89 ± 0.16), (2.89 ± 0.26), and (2.61 ± 0.42), respectively. For the reactions with OH radicals the determined rate coefficients are (in units of 10(-11) cm(3) molecule(-1) s(-1)): (1.18 ± 0.12), (1.49 ± 0.16), (1.41 ± 0.15), and (1.77 ± 0.23), respectively. The reported error is twice the standard deviation. A detailed
Directory of Open Access Journals (Sweden)
Havlik Jan
2017-01-01
Full Text Available This article deals with the experimental determination of heat transfer coefficients. The calculation of heat transfer coefficients constitutes a crucial issue in design and sizing of heat exchangers. The Wilson plot method and its modifications based on measured experimental data utilization provide an appropriate tool for the analysis of convection heat transfer processes and the determination of convection coefficients in complex cases. A modification of the Wilson plot method for shell-and-tube condensers is proposed. The original Wilson plot method considers a constant value of thermal resistance on the condensation side. The heat transfer coefficient on the cooling side is determined based on the change in thermal resistance for different conditions (fluid velocity and temperature. The modification is based on the validation of the Nusselt theory for calculating the heat transfer coefficient on the condensation side. A change of thermal resistance on the condensation side is expected and the value is part of the calculation. It is possible to improve the determination accuracy of the criterion equation for calculation of the heat transfer coefficient using the proposed modification. The criterion equation proposed by this modification for the tested shell-and-tube condenser achieves good agreement with the experimental results and also with commonly used theoretical methods.
Electric Motor Thermal Management R&D. Annual Report
Energy Technology Data Exchange (ETDEWEB)
Bennion, Kevin [National Renewable Energy Lab. (NREL), Golden, CO (United States)
2016-04-01
With the push to reduce component volumes, lower costs, and reduce weight without sacrificing performance or reliability, the challenges associated with thermal management increase for power electronics and electric motors. Thermal management for electric motors will become more important as the automotive industry continues the transition to more electrically dominant vehicle propulsion systems. The transition to more electrically dominant propulsion systems leads to higher-power duty cycles for electric drive systems. Thermal constraints place significant limitations on how electric motors ultimately perform, and as thermal management improves, there will be a direct trade-off between motor performance, efficiency, cost, and the sizing of electric motors to operate within the thermal constraints. The goal of this research project is to support broad industry demand for data, analysis methods, and experimental techniques to improve and better understand motor thermal management. Work in FY15 focused on two areas related to motor thermal management: passive thermal performance and active convective cooling. Passive thermal performance emphasized the thermal impact of materials and thermal interfaces among materials within an assembled motor. The research tasks supported the publication of test methods and data for thermal contact resistances and direction-dependent thermal conductivity within an electric motor. Active convective cooling focused on measuring convective heat-transfer coefficients using automatic transmission fluid (ATF). Data for average convective heat transfer coefficients for direct impingement of ATF jets was published. Also, experimental hardware for mapping local-scale and stator-scale convective heat transfer coefficients for ATF jet impingement were developed.
Bystrov, N. S.; Emelianov, A. V.; Eremin, A. V.; Yatsenko, P. I.
2018-05-01
The kinetics of the dissociation of CF3I behind shock waves was experimentally investigated. The reaction CF3I + Ar → CF3 + I + Ar was studied at temperatures between 900 and 1250 K and pressures of 2–3 bar. For this purpose, the time profiles of the concentration of atomic iodine were measured using a highly sensitive atomic resonance absorption spectroscopy method at a wavelength of 183.04 nm. From these data, the experimental value of the dissociation rate constant of CF3I was obtained: . We found that the investigated range of pressures and temperatures for the CF3I dissociation lies in the pressure transition region. Based on the Rice-Ramsperger–Kassel–Marcus theory, the threshold high and low-pressure rate constants ( and k 0) and falloff curves are calculated for the temperatures of 950–1200 K. As a result of this calculation, the threshold rate constants could be evaluated in the forms: and , and the center broadening factor, which takes into account the contribution of strong and weak collisions in the transition region, is .
Flood, T R; Waldron, M; Jeffries, O
2017-07-01
The study investigated the effect of a non-thermal cooling agent, L-menthol, on exercise at a fixed subjective rating of perceived exertion (RPE) in a hot environment. Eight male participants completed two trials at an exercise intensity between 'hard' and 'very hard', equating to 16 on the RPE scale at ~35 °C. Participants were instructed to continually adjust their power output to maintain an RPE of 16 throughout the exercise trial, stopping once power output had fallen by 30%. In a randomized crossover design, either L-menthol or placebo mouthwash was administered prior to exercise and at 10 min intervals. Power output, [Formula: see text]O 2 , heart rate, core and skin temperature was monitored, alongside thermal sensation and thermal comfort. Isokinetic peak power sprints were conducted prior to and immediately after the fixed RPE trial. Exercise time was greater (23:23 ± 3:36 vs. 21:44 ± 2:32 min; P = 0.049) and average power output increased (173 ± 24 vs. 167 ± 24 W; P = 0.044) in the L-menthol condition. Peak isokinetic sprint power declined from pre-post trial in the L-menthol l (9.0%; P = 0.015) but not in the placebo condition (3.4%; P = 0.275). Thermal sensation was lower in the L-menthol condition (P = 0.036), despite no changes in skin or core temperature (P > 0.05). These results indicate that a non-thermal cooling mouth rinse lowered thermal sensation, resulting in an elevated work rate, which extended exercise time in the heat at a fixed RPE.
Mahmood, Asif; Aziz, Asim; Jamshed, Wasim; Hussain, Sajid
Solar energy is the cleanest, renewable and most abundant source of energy available on earth. The main use of solar energy is to heat and cool buildings, heat water and to generate electricity. There are two types of solar energy collection system, the photovoltaic systems and the solar thermal collectors. The efficiency of any solar thermal system depend on the thermophysical properties of the operating fluids and the geometry/length of the system in which fluid is flowing. In the present research a simplified mathematical model for the solar thermal collectors is considered in the form of non-uniform unsteady stretching surface. The flow is induced by a non-uniform stretching of the porous sheet and the uniform magnetic field is applied in the transverse direction to the flow. The non-Newtonian Maxwell fluid model is utilized for the working fluid along with slip boundary conditions. Moreover the high temperature effect of thermal radiation and temperature dependent thermal conductivity are also included in the present model. The mathematical formulation is carried out through a boundary layer approach and the numerical computations are carried out for cu-water and TiO2 -water nanofluids. Results are presented for the velocity and temperature profiles as well as the skin friction coefficient and Nusselt number and the discussion is concluded on the effect of various governing parameters on the motion, temperature variation, velocity gradient and the rate of heat transfer at the boundary.
Yang, H. Q.; West, Jeff
2015-01-01
Current reduced-order thermal model for cryogenic propellant tanks is based on correlations built for flat plates collected in the 1950's. The use of these correlations suffers from: inaccurate geometry representation; inaccurate gravity orientation; ambiguous length scale; and lack of detailed validation. The work presented under this task uses the first-principles based Computational Fluid Dynamics (CFD) technique to compute heat transfer from tank wall to the cryogenic fluids, and extracts and correlates the equivalent heat transfer coefficient to support reduced-order thermal model. The CFD tool was first validated against available experimental data and commonly used correlations for natural convection along a vertically heated wall. Good agreements between the present prediction and experimental data have been found for flows in laminar as well turbulent regimes. The convective heat transfer between tank wall and cryogenic propellant, and that between tank wall and ullage gas were then simulated. The results showed that commonly used heat transfer correlations for either vertical or horizontal plate over predict heat transfer rate for the cryogenic tank, in some cases by as much as one order of magnitude. A characteristic length scale has been defined that can correlate all heat transfer coefficients for different fill levels into a single curve. This curve can be used for the reduced-order heat transfer model analysis.
Lee, Ya-Ju; Chou, Chun-Yang; Huang, Chun-Ying; Yao, Yung-Chi; Haung, Yi-Kai; Tsai, Meng-Tsan
2017-10-31
The coefficient of thermal expansion (CTE) is a physical quantity that indicates the thermal expansion value of a material upon heating. For advanced thermal management, the accurate and immediate determination of the CTE of packaging materials is gaining importance because the demand for high-power lighting-emitting diodes (LEDs) is currently increasing. In this study, we used optical coherence tomography (OCT) to measure the CTE of an InGaN-based (λ = 450 nm) high-power LED encapsulated in polystyrene resin. The distances between individual interfaces of the OCT images were observed and recorded to derive the instantaneous CTE of the packaged LED under different injected currents. The LED junction temperature at different injected currents was established with the forward voltage method. Accordingly, the measured instantaneous CTE of polystyrene resin varied from 5.86 × 10 -5 °C -1 to 14.10 × 10 -5 °C -1 in the junction temperature range 25-225 °C and exhibited a uniform distribution in an OCT scanning area of 200 × 200 μm. Most importantly, this work validates the hypothesis that OCT can provide an alternative way to directly and nondestructively determine the spatially resolved CTE of the packaged LED device, which offers significant advantages over traditional CTE measurement techniques.
Energy Technology Data Exchange (ETDEWEB)
Barrera, M. T., E-mail: mariate9590@gmail.com; Barros, H.; Pino, F.; Sajo-Bohus, L. [Universidad Simón Bolívar, Nuclear Physics Laboratory, Sartenejas, Caracas (Venezuela, Bolivarian Republic of); Dávila, J. [Física Médica C. A. and Universidad Central de Venezuela, Caracas (Venezuela, Bolivarian Republic of)
2015-07-23
LINAC VARIAN 2100 is where energetic electrons produce Bremsstrahlung radiation, with energies above the nucleon binding energy (E≈5.5MeV). This radiation induce (γ,n) and (e,e’n) reactions mainly in the natural tungsten target material (its total photoneutron cross section is about 4000 mb in a energy range from 9-17 MeV). These reactions may occur also in other components of the system (e.g. multi leaf collimator). During radiation treatment the human body may receive an additional dose inside and outside the treated volume produced by the mentioned nuclear reactions. We measured the neutron density at the treatment table using nuclear track detectors (PADC-NTD). These covered by a boron-converter are employed, including a cadmium filter, to determine the ratio between two groups of neutron energy, i.e. thermal and epithermal. The PADC-NTD detectors were exposed to the radiation field at the iso-center during regular operation of the accelerator. Neutron are determined indirectly by the converting reaction {sup 10}B(n,α){sup 7}Li the emerging charged particle leave their kinetic energy in the PADC forming a latent nuclear track, enlarged by chemical etching (6N, NaOH, 70°C). Track density provides information on the neutron density through calibration coefficient (∼1.6 10{sup 4} neutrons /track) obtained by a californium source. We report the estimation of the thermal and epithermal neutron field and its gradient for photoneutrons produced in radiotherapy treatments with 18 MV linear accelerators. It was obsered that photoneutron production have higher rate at the iso-center.
International Nuclear Information System (INIS)
Mihajlov, A A; Ignjatovic, Lj M; Djuric, Z; Ljepojevic, N N
2004-01-01
This paper presents the results of semi-classical calculations of rate coefficients of (n - n')-mixing processes in collisions of Rydberg atoms H*(n) with H(1s) atoms. These processes have been modelled by the mechanism of the resonant energy exchange within the electron component of the H*(n) + H collisional system. The calculations of the rate coefficients, based on this model, were performed for the series of principal quantum numbers, n and n', and atomic, T a , and electronic, T e , temperatures. It was shown that these processes can be of significant influence on the populations of Rydberg atoms in weakly ionized plasmas (ionization degree ∼ -4 ), and therefore have to be included in appropriate models of such plasmas
International Nuclear Information System (INIS)
Byung Ryul Jung; Ho Cheol Jang; Byung Jin Lee; Se Jin Baik; Woo Hyun Jang
2005-01-01
Most of Pressurized Water Reactors (PWRs) utilize the venturi meters (VMs) to measure the feedwater (FW) flow rate to the steam generator in the calorimetric measurement, which is used in the reactor thermal power (RTP) estimation. However, measurement drifts have been experienced due to some anomalies on the venturi meter (generally called the venturi meter fouling). The VM's fouling tends to increase the measured pressure drop across the meter, which results in indication of increased feedwater flow rate. Finally, the reactor thermal power is overestimated and the actual reactor power is to be reduced to remain within the regulatory limits. To overcome this VM's fouling problem, the Ultrasonic Flow Meter (UFM) has recently been gaining attention in the measurement of the feedwater flow rate. This paper presents the applicability of a UFM based feedwater flow rate in the estimation of reactor thermal power uncertainty. The FW and RTP uncertainties are compared in terms of sensitivities between the VM- and UFM-based feedwater flow rates. Data from typical Optimized Power Reactor 1000 (OPR1000) plants are used to estimate the uncertainty. (authors)
Heat transfer coefficient of cryotop during freezing.
Li, W J; Zhou, X L; Wang, H S; Liu, B L; Dai, J J
2013-01-01
Cryotop is an efficient vitrification method for cryopreservation of oocytes. It has been widely used owing to its simple operation and high freezing rate. Recently, the heat transfer performance of cryotop was studied by numerical simulation in several studies. However, the range of heat transfer coefficient in the simulation is uncertain. In this study, the heat transfer coefficient for cryotop during freezing process was analyzed. The cooling rates of 40 percent ethylene glycol (EG) droplet in cryotop during freezing were measured by ultra-fast measurement system and calculated by numerical simulation at different value of heat transfer coefficient. Compared with the results obtained by two methods, the range of the heat transfer coefficient necessary for the numerical simulation of cryotop was determined, which is between 9000 W/(m(2)·K) and 10000 W/(m (2)·K).
Directory of Open Access Journals (Sweden)
Hongbo Y.
2015-06-01
Full Text Available The thermal decomposition of magnesium-aluminum layered double hydroxides (LDHs was investigated by thermogravimetry analysis and differential scanning calorimetry (DSC methods in argon environment. The influence of heating rates (including 2.5, 5, 10, 15 and 20K/min on the thermal behavior of LDHs was revealed. By the methods of Kissinger and Flynn-Wall-Ozawa, the thermal kinetic parameters of activation energy and pre-exponential factor for the exothermic processes under non-isothermal conditions were calculated using the analysis of corresponding DSC curves.
Hamzah, Esah; Ourdjini, Ali; Ali, Mubarak; Akhter, Parvez; Hj. Mohd Toff, Mohd Radzi; Abdul Hamid, Mansor
In the present study, the effect of various N2 gas flow rates on friction coefficient and surface roughness of TiN-coated D2 tool steel was examined by a commercially available cathodic arc physical vapor deposition (CAPVD) technique. A Pin-on-Disc test was carried out to study the Coefficient of friction (COF) versus sliding distance. A surface roughness tester measured the surface roughness parameters. The minimum values for the COF and surface roughness were recorded at a N2 gas flow rate of 200 sccm. The increase in the COF and surface roughness at a N2 gas flow rate of 100 sccm was mainly attributed to an increase in both size and number of titanium particles, whereas the increase at 300 sccm was attributed to a larger number of growth defects generated during the coating process. These ideas make it possible to optimize the coating properties as a function of N2 gas flow rate for specific applications, e.g. cutting tools for automobiles, aircraft, and various mechanical parts.
Duong, Minh V; Nguyen, Hieu T; Mai, Tam V-T; Huynh, Lam K
2018-01-03
Master equation/Rice-Ramsperger-Kassel-Marcus (ME/RRKM) has shown to be a powerful framework for modeling kinetic and dynamic behaviors of a complex gas-phase chemical system on a complicated multiple-species and multiple-channel potential energy surface (PES) for a wide range of temperatures and pressures. Derived from the ME time-resolved species profiles, the macroscopic or phenomenological rate coefficients are essential for many reaction engineering applications including those in combustion and atmospheric chemistry. Therefore, in this study, a least-squares-based approach named Global Minimum Profile Error (GMPE) was proposed and implemented in the MultiSpecies-MultiChannel (MSMC) code (Int. J. Chem. Kinet., 2015, 47, 564) to extract macroscopic rate coefficients for such a complicated system. The capability and limitations of the new approach were discussed in several well-defined test cases.
Garel, F.; Kaminski, E.; Tait, S.; Limare, A.
2011-12-01
During an effusive volcanic eruption, the crisis management is mainly based on the prediction of lava flows advance and its velocity. As the spreading of lava flows is mainly controlled by its rheology and the eruptive mass flux, the key question is how to evaluate them during the eruption (rather than afterwards.) A relationship between the heat flux lost by the lava at its surface and the eruption rate is likely to exist, based on the first-order argument that higher eruption rates should correspond to larger power radiated by a lava flow. The semi-empirical formula developed by Harris and co-workers (e.g. Harris et al., Bull. Volc. 2007) is currently used to estimate lava flow rate from satellite surveys yielding the surface temperatures and area of the lava flow field. However, this approach is derived from a static thermal budget of the lava flow and does not explicitly model the time-evolution of the surface thermal signal. Here we propose laboratory experiments and theoretical studies of the cooling of a viscous axisymmetric gravity current fed at constant flux rate. We first consider the isoviscous case, for which the spreading is well-know. The experiments using silicon oil and the theoretical model both reveal the establishment of a steady surface thermal structure after a transient time. The steady state is a balance between surface cooling and heat advection in the flow. The radiated heat flux in the steady regime, a few days for a basaltic lava flow, depends mainly on the effusion rate rather than on the viscosity. In this regime, one thermal survey of the radiated power could provide a consistent estimate of the flow rate if the external cooling conditions (wind) are reasonably well constrained. We continue to investigate the relationship between the thermal radiated heat flux and the effusion rate by using in the experiments fluids with temperature-dependent viscosity (glucose syrup) or undergoing solidification while cooling (PEG wax). We observe a
Energy Technology Data Exchange (ETDEWEB)
Azevedo, Luis Fernando A.; Farias, Paula S.C.; Martins, Fabio J.W.A.; Rabello, Pedro C.; Barros Junior, Julio M. [Pontificia Universidade Catolica (PUC-Rio), RJ (Brazil). Dept. de Engenharia Mecanica; Lopes Junior, Fernando M.; Silva Junior, Jose Fernando; Castro, Adriana M.; Santos, Augusto A.; Pessanha, Maikon C.R. [Technip, Rio de Janeiro, RJ (Brazil)
2009-12-19
The present paper describes a methodology successfully employed to determine the Thermal Exchange Coefficient - TEC - for insulated sub sea flexible lines up to a pressure level of 200 bar. In this methodology, controlled internal electrical heating was employed, together with temperature sensors installed at the inner and outer surfaces of the line. The instrumented line sample was placed in a hyperbaric chamber filled with water. Two methods were employed in parallel to determine the line TEC value. In the first method, the TEC value was determined by direct measurement of the radial heat flux by the use of heat flux sensors. The readings of these sensors, together with the inner-to-outer surface temperature difference and geometric parameters, yielded the desired TEC value. In the second method, the radial heat flux was obtained as the difference between the total energy generated by the electrical heater installed in the interior of the sample and the heat losses through the end connectors, evaluated by the readings of temperature sensors installed in covers that surrounded the end connectors. The knowledge of the cover geometry, thermal properties and the temperature readings allowed for an accurate estimate of the heat lost through the covers. Both measuring methods were backed by a detailed uncertainty analysis. A calibration procedure of the second method was performed from zero to 100 bar, the pressure range where the calibration of the heat flux sensor is valid. Beyond 100 bar and up to 200 bar, the TEC values were obtained by the second method, corrected by the calibration procedure extrapolated from the 0-100 bar range. The TEC values obtained were valid under an uncertainty level of {+-} 5%. (author)
Negative thermal expansion materials: technological key for control of thermal expansion.
Takenaka, Koshi
2012-02-01
Most materials expand upon heating. However, although rare, some materials contract upon heating. Such negative thermal expansion (NTE) materials have enormous industrial merit because they can control the thermal expansion of materials. Recent progress in materials research enables us to obtain materials exhibiting negative coefficients of linear thermal expansion over -30 ppm K -1 . Such giant NTE is opening a new phase of control of thermal expansion in composites. Specifically examining practical aspects, this review briefly summarizes materials and mechanisms of NTE as well as composites containing NTE materials, based mainly on activities of the last decade.
Negative thermal expansion materials: technological key for control of thermal expansion
Directory of Open Access Journals (Sweden)
Koshi Takenaka
2012-01-01
Full Text Available Most materials expand upon heating. However, although rare, some materials contract upon heating. Such negative thermal expansion (NTE materials have enormous industrial merit because they can control the thermal expansion of materials. Recent progress in materials research enables us to obtain materials exhibiting negative coefficients of linear thermal expansion over −30 ppm K−1. Such giant NTE is opening a new phase of control of thermal expansion in composites. Specifically examining practical aspects, this review briefly summarizes materials and mechanisms of NTE as well as composites containing NTE materials, based mainly on activities of the last decade.
Negative thermal expansion materials: technological key for control of thermal expansion
International Nuclear Information System (INIS)
Takenaka, Koshi
2012-01-01
Most materials expand upon heating. However, although rare, some materials contract upon heating. Such negative thermal expansion (NTE) materials have enormous industrial merit because they can control the thermal expansion of materials. Recent progress in materials research enables us to obtain materials exhibiting negative coefficients of linear thermal expansion over −30 ppm K −1 . Such giant NTE is opening a new phase of control of thermal expansion in composites. Specifically examining practical aspects, this review briefly summarizes materials and mechanisms of NTE as well as composites containing NTE materials, based mainly on activities of the last decade. (topical review)
Vibrational and Thermal Properties of Oxyanionic Crystals
Korabel'nikov, D. V.
2018-03-01
The vibrational and thermal properties of dolomite and alkali chlorates and perchlorates were studied in the gradient approximation of density functional theory using the method of a linear combination of atomic orbitals (LCAO). Long-wave vibration frequencies, IR and Raman spectra, and mode Gruneisen parameters were calculated. Equation-of-state parameters, thermodynamic potentials, entropy, heat capacity, and thermal expansion coefficient were also determined. The thermal expansion coefficient of dolomite was established to be much lower than for chlorates and perchlorates. The temperature dependence of the heat capacity at T > 200 K was shown to be generally governed by intramolecular vibrations.
Collective effects on transport coefficients of relativistic nuclear matter. Pt. 2
International Nuclear Information System (INIS)
Mornas, L.
1993-04-01
The transport coefficients (thermal conductivity, shear and bulk viscosities) of symmetric nuclear matter and neutron matter are calculated in the Walecka model with a Boltzmann-Uehling-Uhlenbeck collision term by means of a Chapman-Enskog expansion in first order. The order of magnitude of the influence of collective effects induced by the presence of the mean σ and ω fields on these coefficients is evaluated. (orig.). 9 figs
Directory of Open Access Journals (Sweden)
Huang Chen-Hung
2016-01-01
Full Text Available Due to recent rapid commercial and industrial development, mechanical equipment is supplemented massively in the factory and thus mechanical operation causes noise which distresses living at home. In livelihood, neighborhood, transportation equipment, jobsite construction noises impact on quality of life not only factory noise. This study aims to preparation technique and property evaluation of porous sound-absorbing/thermal-insulating composites. Hollow three-dimensional crimp PET fibers blended with low-melting PET fibers were fabricated into hollow PET/low-melting PET nonwoven after opening, blending, carding, lapping and needle-bonding process. Then, hollow PET/low-melting PET nonwovens were laminated into sound-absorbing/thermal-insulating composites by changing sequence of needle-bonding and thermal-treatment. The optimal thermal-treated sequence was found by tensile strength, tearing strength, sound-absorbing coefficient and thermal conductivity coefficient tests of porous composites.
Energy Technology Data Exchange (ETDEWEB)
Layden, B.; Cairns, Iver H.; Robinson, P. A. [School of Physics, University of Sydney, Sydney, NSW 2006 (Australia)
2013-08-15
Electrostatic decay of Langmuir waves into Langmuir and ion sound waves (L→L′+S) and scattering of Langmuir waves off thermal ions (L+i→L′+i′, also called “nonlinear Landau damping”) are important nonlinear weak-turbulence processes. The rates for these processes depend on the quadratic longitudinal response function α{sup (2)} (or, equivalently, the quadratic longitudinal susceptibility χ{sup (2)}), which describes the second-order response of a plasma to electrostatic wave fields. Previous calculations of these rates for an unmagnetized Maxwellian plasma have relied upon an approximate form for α{sup (2)} that is valid where two of the wave fields are fast (i.e., v{sub φ}=ω/k≫V{sub e} where ω is the angular frequency, k is the wavenumber, and V{sub e} is the electron thermal speed) and one is slow (v{sub φ}≪V{sub e}). Recently, an exact expression was derived for α{sup (2)} that is valid for any phase speeds of the three waves in an unmagnetized Maxwellian plasma. Here, this exact α{sup (2)} is applied to the calculation of the three-dimensional rates for electrostatic decay and scattering off thermal ions, and the resulting exact rates are compared with the approximate rates. The calculations are performed using previously derived three-dimensional rates for electrostatic decay given in terms of a general α{sup (2)}, and newly derived three-dimensional rates for scattering off thermal ions; the scattering rate is derived assuming a Maxwellian ion distribution, and both rates are derived assuming arc distributions for the wave spectra. For most space plasma conditions, the approximate rate is found to be accurate to better than 20%; however, for sufficiently low Langmuir phase speeds (v{sub φ}/V{sub e}≈3) appropriate to some spatial domains of the foreshock regions of planetary bow shocks and type II solar radio bursts, the use of the exact rate may be necessary for accurate calculations. The relative rates of electrostatic decay
Energy Technology Data Exchange (ETDEWEB)
Hajilar, Shahin, E-mail: shajilar@iastate.edu [Department of Civil, Construction and Environmental Engineering, Iowa State University, Ames, IA 50011-1066 (United States); Shafei, Behrouz, E-mail: shafei@iastate.edu [Department of Civil, Construction and Environmental Engineering, Department of Materials Science and Engineering, Iowa State University, Ames, IA 50011-1066 (United States)
2016-12-15
The structural, thermal, and mechanical properties of portlandite, the primary solid phase of ordinary hydrated cement paste, are investigated using the molecular dynamics method. To understand the effects of temperature on the structural properties of portlandite, the coefficients of thermal expansion of portlandite are determined in the current study and validated with what reported from the experimental tests. The atomic structure of portlandite equilibrated at various temperatures is then subjected to uniaxial tensile strains in the three orthogonal directions and the stress-strain curves are developed. Based on the obtained results, the effect of the direction of straining on the mechanical properties of portlandite is investigated in detail. Structural damage analysis is performed to reveal the failure mechanisms in different directions. The energies of the fractured surfaces are calculated in different directions and compared to those of the ideal surfaces available in the literature. The key mechanical properties, including tensile strength, Young's modulus, and fracture strain, are extracted from the stress-strain curves. The sensitivity of the obtained mechanical properties to temperature and strain rate is then explored in a systematic way. This leads to valuable information on how the structural and mechanical properties of portlandite are affected under various exposure conditions and loading rates. - Graphical abstract: Fracture mechanism of portlandite under uniaxial strain in the z-direction. - Highlights: • The structural, thermal, and mechanical properties of portlandite are investigated. • The coefficients of thermal expansion are determined. • The stress-strain relationships are studied in three orthogonal directions. • The effects of temperature and strain rate on mechanical properties are examined. • The plastic energy required for fracture in the crystalline structure is reported.
Kim, Jaehyun; Fleming, Evan; Zhou, Yuanyuan; Shi, Li
2018-03-01
Two different four-probe thermal and thermoelectric measurement methods have been reported for measuring the thermal conductivity, Seebeck coefficient, and electrical conductivity of suspended thin films and nanostructures with microfabricated electro-thermal transducers. The thermal contact resistance was extracted from the measured thermoelectric voltage drop at the contacts in the earlier four-probe method based on the assumption of constant thermal and thermoelectric properties along the sample. In comparison, the latter four-probe method can directly obtain the contact thermal resistance together with the intrinsic sample thermal resistance without making this assumption. Here, the measurement theory and data reduction processes of the latter four-probe measurement method are re-examined and improved. The measured thermal conductivity result of this improved method on representative thin film samples are found to agree with those obtained from the earlier four-probe method, which has obtained similar Seebeck coefficient and electrical conductivity as those measured with a different method for a supported thin film. The agreement provides further validation of the latest four-probe thermal transport measurement method of thin films and nanostructures.
Variational RRKM calculation of thermal rate constant for C–H bond fission reaction of nitro methane
Directory of Open Access Journals (Sweden)
Afshin Taghva Manesh
2017-02-01
Full Text Available The present work provides quantitative results for the rate constants of unimolecular C–H bond fission reactions in the nitro methane at elevated temperatures up to 2000 K. In fact, there are three different hydrogen atoms in the nitro methane. The potential energy surface for each C–H bond fission reaction of nitro methane was investigated by ab initio calculations. The geometry and vibrational frequencies of the species involved in this process were optimized at the MP2 level of theory, using the cc-pvdz basis set. Since C–H bond fission channel is a barrierless reaction, we have used variational RRKM theory to predict rate coefficients. By means of calculated rate coefficients at different temperatures, the Arrhenius expression of the channel over the temperature range of 100–2000 K is k(T = 5.9E19∗exp(−56274.6/T.
International Nuclear Information System (INIS)
Schwartz, S.E.
1988-10-01
Although it has been recognized for some time that the rate of reactive uptake of gases in cloudwater can depend on the value of the mass-accommodation coefficient (α) describing interfacial mass transport (MT), definitive evaluation of such rates is only now becoming possible with the availability of measurements of α for gases of atmospheric interest at air-water interfaces. Examination of MT limitation to the rate of in-cloud aqueous-phase oxidation of SO 2 by O 3 and H 2 O 2 shows that despite the low value of α/sub O3/ (5 /times/ 10/sup /minus/4/), interfacial MT of this species is not limiting under essentially all conditions of interest; the high values of α for SO 2 (≥ 0.2) and H 2 O 2 (≥ 0.08) indicate no interfacial MT limitation for these species also. Although gas- and aqueous-phase MT can be limiting under certain extremes of conditions, treating the system as under chemical kinetic control is generally an excellent approximation. Interfacial MT limitation also is found not to hinder the rate of H 2 O 2 formation by aqueous-phase disproportionation of HO 2 . Finally, the rapid uptake of N 2 O 5 by cloud droplets implies that the yield of aqueous HNO 3 from in-cloud gas-phase oxidation of NO 2 by O 3 can be substantial even under daytime conditions. This report consists of copies of viewgraphs prepared for this presentation
Setting time and thermal expansion of two endodontic cements.
Santos, Alailson D; Araújo, Eudes B; Yukimitu, Keizo; Barbosa, José C; Moraes, João C S
2008-09-01
The purpose of this study was to evaluate the setting time and the thermal expansion coefficient of 2 endodontic cements, MTA-Angelus and a novel cement called CER. The setting time was determined in accordance to ANSI/ADA specifications no. 57. Three samples of 10 mm diameter and 2 mm thickness were prepared for each cement. The thermal expansion measurements were performed by strain gauge technique. Four samples of each cement were prepared using silicone rings of 5 mm diameter and 2 mm thickness. The data were analyzed statistically using the Student t test. The setting time obtained for the MTA-Angelus and CER cements was 15 (SD 1) min and 7 (SD 1) min, respectively. The linear coefficient of thermal expansion was 8.86 (SD 0.28) microstrain/ degrees C for MTA-Angelus and 11.76 (SD 1.20) microstrain/ degrees C for CER. The statistical analysis showed significant difference (P linear coefficient of thermal expansion between the 2 cements. The CER cement has a coefficient of expansion similar to dentin, which could contribute to a decrease of microleakage degree.
Cancellation of infrared and mass singularities in the thermal di-lepton rate
International Nuclear Information System (INIS)
Altherr, T.; Becherrawy, T.
1989-03-01
We give a rigorous proof that, at first order in α s , the thermal di-lepton rate is free of infrared and mass singularities. The calculation is performed for massive quarks in the real-time formalism with the n-dimensional regularization scheme. The cancellation is shown to occur within each topology
Thermal properties of andesite from Popocatepetl and Volcán de Colima, México.
Cardenas-Sanchez, Enrique; De la Cruz-Reina, Servando; Varley, Nick
2015-04-01
The thermal conductivity (K), specific heat (Cp) and the coefficient of heat transfer surface (H) are the basic parameters to describe the process of cooling a volcanic rock fragment released in an explosive event. The analysis of the cooling process by conduction, convection and radiation of heat in volcanic rock fragments, has been limited to basalts, and various minerals such as olivine, pyroxene, quartz, etc. (Miao & Chen, 2014; Branlund & Hofmeister, 2012; Romine et al, 2012;. Schön, 2011; Stroberg et al, 2010;. Schatz & Simmons, 1972). There are no detailed studies on the thermal properties of the andesites, abundant in continental stratovolcanoes, and particularly susceptible from lava domes with frequent destruction processes, such as Popocatepetl and Volcan de Colima. Previously, we developed an algorithm for calculation of the grain-size distribution, degree of fragmentation, the thermal energy released and its possible correlation with Volcanic Explosive Index (VEI) from the cooling curves of fragments from vulcanian and strombolian explosions. These curves were obtained from sequences of time over incandescent deposits recorded at selected pixel thermal images of vulcanian activity in the Popocatepetl and Volcan de Colima, Mexico. However, the model was limited by the lack of thermal parameters of the andesites, forcing a first approximation using basalts data. We present a simple model for the cooling process using andesites samples from Popocatépetl and Volcan de Colima. First, the samples were subjected to a rounding process to minimize surface effects. Then, heated to 800 ° C were extracted from the muffle and cooling rate is measured. The thermal conductivity and coefficient of surface heat are determined using a thermal camera and three thermocouples embedded at various depths within the sample. An inversion method was implemented to determine the thermal properties parameters , by comparing the observed data regarding cooling model for a solid
Thermal/structural analysis of radiators for heavy-duty trucks
International Nuclear Information System (INIS)
Mao Shaolin; Cheng, Changrui; Li Xianchang; Michaelides, Efstathios E.
2010-01-01
A thermal/structural coupling approach is applied to analyze thermal performance and predict the thermal stress of a radiator for heavy-duty transportation cooling systems. Bench test and field test data show that non-uniform temperature gradient and dynamic pressure loads may induce large thermal stress on the radiator. A finite element analysis (FEA) tool is used to predict the strains and displacement of radiator based on the solid wall temperature, wall-based fluid film heat transfer coefficient and pressure drop. These are obtained from a computational fluid dynamics (CFD) simulation. A 3D simulation of turbulent flow and coupled heat transfer between the working fluids poses a major difficulty because the range of length scales involved in heavy-duty radiators varies from few millimeters of the fin pitch and/or tube cross-section to several meters for the overall size of the radiator. It is very computational expensive, if not impossible, to directly simulate the turbulent heat transfer between fins and the thermal boundary layer in each tube. In order to overcome the computational difficulties, a dual porous zone (DPZ) method is applied, in which fins in the air side and turbulators in the water side are treated as porous region. The parameters involved in the DPZ method are tuned based on experimental data in prior. A distinguished advantage of the porous medium method is its effectiveness of modeling wide-range characteristic scale problems. A parametric study of the impact of flow rate on the heat transfer coefficient is presented. The FEA results predict the maximum value of stress/strain and target locations for possible structural failure and the results obtained are consistent with experimental observations. The results demonstrate that the coupling thermal/structural analysis is a powerful tool applied to heavy-duty cooling product design to improve the radiator thermal performance, durability and reliability under rigid working environment.
Thermal expansion of quaternary nitride coatings
Tasnádi, Ferenc; Wang, Fei; Odén, Magnus; Abrikosov, Igor A.
2018-04-01
The thermal expansion coefficient of technologically relevant multicomponent cubic nitride alloys are predicted using the Debye model with ab initio elastic constants calculated at 0 K and an isotropic approximation for the Grüneisen parameter. Our method is benchmarked against measured thermal expansion of TiN and Ti(1-x)Al x N as well as against results of molecular dynamics simulations. We show that the thermal expansion coefficients of Ti(1-x-y)X y Al x N (X = Zr, Hf, Nb, V, Ta) solid solutions monotonously increase with the amount of alloying element X at all temperatures except for Zr and Hf, for which they instead decrease for y≳ 0.5 .
Directory of Open Access Journals (Sweden)
Ming Li
2017-01-01
Full Text Available The effects of coal layered combustion and the heat injection rate on adjacent rock were examined in the process of underground coal gasification and coal-bed methane mining. Dynamic Brazilian disk tests were conducted on coal sandstone at 800°C and slow cooling from different heating rates by means of a Split Hopkinson Pressure Bar (SHPB test system. It was discovered that thermal conditions had significant effects on the physical and mechanical properties of the sandstone including longitudinal wave velocity, density, and dynamic linear tensile strength; as the heating rates increased, the thermal expansion of the sandstone was enhanced and the damage degree increased. Compared with sandstone at ambient temperature, the fracture process of heat-treated sandstone was more complicated. After thermal treatment, the specimen had a large crack in the center and cracks on both sides caused by loading; the original cracks grew and mineral particle cracks, internal pore geometry, and other defects gradually appeared. With increasing heating rates, the microscopic fracture mode transformed from ductile fracture to subbrittle fracture. It was concluded that changes in the macroscopic mechanical properties of the sandstone were result from changes in the composition and microstructure.
Pulsational stabilities of a star in thermal imbalance: comparison between the methods
International Nuclear Information System (INIS)
Vemury, S.K.
1978-01-01
The stability coefficients for quasi-adiabatic pulsations for a model in thermal imbalance are evaluated using the dynamical energy (DE) approach, the total (kinetic plus potential) energy (TE) approach, and the small amplitude (SA) approaches. From a comparison among the methods, it is found that there can exist two distinct stability coefficients under conditions of thermal imbalance as pointed out by Demaret. It is shown that both the TE approaches lead to one stability coefficient, while both the SA approaches lead to another coefficient. The coefficient obtained through the energy approaches is identified as the one which determines the stability of the velocity amplitudes.For a prenova model with a thin hydrogen-burning shell in thermal imbalance, several radial modes are found to be unstable both for radial displacements and for velocity amplitudes. However, a new kind of pulsational instability also appears, viz., while the radial displacements are unstable, the velocity amplitudes may be stabilized through the thermal imbalance terms
A gain-coefficient switched Alexandrite laser
International Nuclear Information System (INIS)
Lee, Chris J; Van der Slot, Peter J M; Boller, Klaus-J
2013-01-01
We report on a gain-coefficient switched Alexandrite laser. An electro-optic modulator is used to switch between high and low gain states by making use of the polarization dependent gain of Alexandrite. In gain-coefficient switched mode, the laser produces 85 ns pulses with a pulse energy of 240 mJ at a repetition rate of 5 Hz.
Effect of flow rate on the adsorption coefficient of radioactive krypton on activated carbon
International Nuclear Information System (INIS)
Sun, L.S.C.; Underhill, D.W.
1981-01-01
For some time, there have been questions relative to the effect of carrier gas velocity on the adsorption coefficient for radioactive noble gases on activated charcoal. Resolution of these questions is particularly important in terms of developing standard procedures for determining such coefficients under laboratory conditions. Studies at the Harvard Air Cleaning Laboratory appear to confirm that the adsorption coefficient for radioactive krypton on activated charcoal is independent of the velocity of the carrier gas
Entransy analysis on the thermal performance of flat plate solar air collectors
Institute of Scientific and Technical Information of China (English)
Jie Deng; Xudong Yang; Yupeng Xu; Ming Yang
2017-01-01
Based on the thermo-electric analogy (the so-called thermal entransy analysis), the unified airside convective heat transfer coefficient for different sorts of flat plate solar air collectors (FPSACs) is identified in terms of colector aperture area. In addition, the colector thermodynamic characteristic matching coefficient is defined to depict the matching property of collector thermal performance between the collector airside heat transfer and the total heat losses. It is found that the airside convective heat transfer coefficient can be experimentally determined by collector thermal performance test method to compare the airside thermal performances of FPSACs with different types of airflow structures. Moreover, the smaler the colector thermodynamic characteristic matching coefficient is, the better the thermodynamic perfect degree of a FPSAC is. The minimum limit value of the collector thermodynamic matching coefficient is close to zero but it can not vanish in practical engineering. Parameter sensitivity analysis on the total entransy dissipation and the entransy increment of a general FPSAC is also undertaken. The results indicate that the effective way of decreasing total entransy dissipation and enhancing the useful entransy increment is improving the efficiency intercept of the FPSAC. This is equivalent to the cognition result of thermal analysis. However, the evaluation indices identified by the thermal entransy analysis can not be extracted by singular thermal analysis.
Lepton asymmetry rate from quantum field theory: NLO in the hierarchical limit
Energy Technology Data Exchange (ETDEWEB)
Bödeker, D.; Sangel, M., E-mail: bodeker@physik.uni-bielefeld.de, E-mail: msangel@physik.uni-bielefeld.de [Fakultät für Physik, Universität Bielefeld, 33501 Bielefeld (Germany)
2017-06-01
The rates for generating a matter-antimatter asymmetry in extensions of the Standard Model (SM) containing right-handed neutrinos are the most interesting and least trivial co\\-efficients in the rate equations for baryogenesis through thermal leptogenesis. We obtain a relation of these rates to finite-temperature real-time correlation functions, similar to the Kubo formulas for transport coefficients. Then we consider the case of hierarchical masses for the sterile neutrinos. At leading order in their Yukawa couplings we find a simple master formula which relates the rates to a single finite temperature three-point spectral function. It is valid to all orders in g , where g denotes a SM gauge or quark Yukawa coupling. We use it to compute the rate for generating a matter-antimatter asymmetry at next-to-leading order in g in the non-relativistic regime. The corrections are of order g {sup 2}, and they amount to 4% or less.
International Nuclear Information System (INIS)
Tsuji, Masashi; Aoki, Yukinori; Shimazu, Yoichiro; Yamasaki, Masatoshi; Hanayama, Yasushi
2006-01-01
A method to evaluate the moderator coefficient (MTC) and the Doppler coefficient through experimental procedures performed during reactor physics tests of PWR power plants is proposed. This method combines isothermal temperature coefficient (ITC) measurement experiments and reactor power transient experiments at low power conditions for dynamic identification. In the dynamic identification, either one of temperature coefficients can be determined in such a way that frequency response characteristics of the reactivity change observed by a digital reactivity meter is reproduced from measured data of neutron count rate and the average coolant temperature. The other unknown coefficient can also be determined by subtracting the coefficient obtained from the dynamic identification from ITC. As the proposed method can directly estimate the Doppler coefficient, the applicability of the conventional core design codes to predict the Doppler coefficient can be verified for new types of fuels such as mixed oxide fuels. The digital simulation study was carried out to show the feasibility of the proposed method. The numerical analysis showed that the MTC and the Doppler coefficient can be estimated accurately and even if there are uncertainties in the parameters of the reactor kinetics model, the accuracies of the estimated values are not seriously impaired. (author)
Calculating the heat transfer coefficient of frame profiles with internal cavities
DEFF Research Database (Denmark)
Noyé, Peter Anders; Laustsen, Jacob Birck; Svendsen, Svend
2004-01-01
. The heat transfer coefficient is determined by two-dimensional numerical calculations and by measurements. Calculations are performed in Therm (LBNL (2001)), which is developed at Lawrence Berkeley National Laboratory, USA. The calculations are performed in accordance with the future European standards...... correspondence between measured and calculated values. Hence, when determining the heat transfer coefficient of frame profiles with internal cavities by calculations, it is necessary to apply a more detailed radiation exchange model than described in the prEN ISO 10077-2 standard. The ISO-standard offers......Determining the energy performance of windows requires detailed knowledge of the thermal properties of their different elements. A series of standards and guidelines exist in this area. The thermal properties of the frame can be determined either by detailed two-dimensional numerical methods...
Low thermal conductivity skutterudites
Energy Technology Data Exchange (ETDEWEB)
Fleurial, J P; Caillat, T; Borshchevsky, A
1997-07-01
Recent experimental results on semiconductors with the skutterudite crystal structure show that these materials possess attractive transport properties and have a good potential for achieving ZT values substantially larger than for state-of-the-art thermoelectric materials. Both n-type and p-type conductivity samples have been obtained, using several preparation techniques. Associated with a low hole effective mass, very high carrier mobilities, low electrical resistivities and moderate Seebeck coefficients are obtained in p-type skutterudites. For a comparable doping level, the carrier mobilities of n-type samples are about an order of magnitude lower than the values achieved on p-type samples. However, the much larger electron effective masses and Seebeck coefficients on p-type samples. However, the much larger electron effective masses and Seebeck coefficients make n-type skutterudite promising candidates as well. Unfortunately, the thermal conductivities of the binary skutterudites compounds are too large, particularly at low temperatures, to be useful for thermoelectric applications. Several approaches to the reduction of the lattice thermal conductivity in skutterudites are being pursued: heavy doping, formation of solid solutions and alloys, study of novel ternary and filled skutterudite compounds. All those approaches have already resulted in skutterudite compositions with substantially lower thermal conductivity values in these materials. Recently, superior thermoelectric properties in the moderate to high temperature range were achieved for compositions combining alloying and filling of the skutterudite structure. Experimental results and mechanisms responsible for low thermal conductivity in skutterudites are discussed.
Energy Technology Data Exchange (ETDEWEB)
Bian, Nicolas H.; Kontar, Eduard P. [School of Physics and Astronomy, University of Glasgow, Glasgow G12 8QQ (United Kingdom); Emslie, A. Gordon, E-mail: n.bian@physics.gla.ac.uk, E-mail: emslieg@wku.edu [Department of Physics and Astronomy, Western Kentucky University, Bowling Green, KY 42101 (United States)
2016-06-20
The transport of the energy contained in electrons, both thermal and suprathermal, in solar flares plays a key role in our understanding of many aspects of the flare phenomenon, from the spatial distribution of hard X-ray emission to global energetics. Motivated by recent RHESSI observations that point to the existence of a mechanism that confines electrons to the coronal parts of flare loops more effectively than Coulomb collisions, we here consider the impact of pitch-angle scattering off turbulent magnetic fluctuations on the parallel transport of electrons in flaring coronal loops. It is shown that the presence of such a scattering mechanism in addition to Coulomb collisional scattering can significantly reduce the parallel thermal and electrical conductivities relative to their collisional values. We provide illustrative expressions for the resulting thermoelectric coefficients that relate the thermal flux and electrical current density to the temperature gradient and the applied electric field. We then evaluate the effect of these modified transport coefficients on the flare coronal temperature that can be attained, on the post-impulsive-phase cooling of heated coronal plasma, and on the importance of the beam-neutralizing return current on both ambient heating and the energy loss rate of accelerated electrons. We also discuss the possible ways in which anomalous transport processes have an impact on the required overall energy associated with accelerated electrons in solar flares.
Thermal-Responsive Polymers for Enhancing Safety of Electrochemical Storage Devices.
Yang, Hui; Leow, Wan Ru; Chen, Xiaodong
2018-03-01
Thermal runway constitutes the most pressing safety issue in lithium-ion batteries and supercapacitors of large-scale and high-power density due to risks of fire or explosion. However, traditional strategies for averting thermal runaway do not enable the charging-discharging rate to change according to temperature or the original performance to resume when the device is cooled to room temperature. To efficiently control thermal runaway, thermal-responsive polymers provide a feasible and reversible strategy due to their ability to sense and subsequently act according to a predetermined sequence when triggered by heat. Herein, recent research progress on the use of thermal-responsive polymers to enhance the thermal safety of electrochemical storage devices is reviewed. First, a brief discussion is provided on the methods of preventing thermal runaway in electrochemical storage devices. Subsequently, a short review is provided on the different types of thermal-responsive polymers that can efficiently avoid thermal runaway, such as phase change polymers, polymers with sol-gel transitions, and polymers with positive temperature coefficients. The results represent the important development of thermal-responsive polymers toward the prevention of thermal runaway in next-generation smart electrochemical storage devices. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Non-thermal escape rates of atmospheric H and D from Mars using MAVEN data
Gacesa, M.; Zahnle, K. J.
2017-12-01
Geological evidence suggests that an ocean of liquid water existed on Mars until at least middle to late Noachian era (4.1 to 3.8 Ga) and possibly, at least episodically, as late as Hesperian. Between 67% and 87% of the total primordial amount of water, equal to about 70 to 110 meters equivalent (spread over the entire Mars' surface), is believed to have escape to space, while about 35 meters remains on or beneath the surface as water ice. Establishing better constraints on these numbers and identifying the responsible atmospheric loss processes remains the major objective of NASA's Mars Atmosphere and Volatile EvolutioN (MAVEN) mission. The ratio of atmospheric Deuterium and Hydrogen (D/H) on Mars is one of the best indicators of water loss to space. While majority of H and D escape through thermal Jeans escape, up to 10% of D can escape to space via non-thermal mechanisms, such as collisions with superthermal neutral atoms. In this study, we present new estimates of non-thermal escape rates of light molecules of interest to the water evolution, including H2, HD, OH, and OD, based on recent measurements of atmospheric density and temperature profiles by MAVEN. The escape mechanisms considered include photochemical sources of hot O, as well as collisions with energetic neutral atoms produced in charge-exchange of solar wind ions with atmospheric gases1,2. Energy transport and escape rates are modeled using quantum reactive scattering formalism3 and seasonal variations are illustrated. Finally, a simple estimate of the role of the non-thermal escape mechanisms in previous eras is given. We conclude that D escape rates can be affected by the non-thermal processes with consequences on the estimates of primordial water inventory based on the D/H ratio. [1] N. Lewkow and V. Kharchenko, Astroph. J., 790, 98 (2014) [2] M. Gacesa, N. Lewkow, V. Kharchenko, Icarus 284, 90 (2017) [3] M. Gacesa and V. Kharchenko, Geophys. Res. Lett., 39, L10203 (2012)
International Nuclear Information System (INIS)
Botto, D.; Zucca, S.; Gola, M.M.
2003-01-01
In the literature many works have been written dealing with the task of on-line calculation of temperature and thermal stress for machine components and structures, in order to evaluate fatigue damage accumulation and estimate residual life. One of the most widespread methodologies is the Green's function technique (GFT), by which machine parameters such as fluid temperatures, pressures and flow rates are converted into metal temperature transients and thermal stresses. However, since the GFT is based upon the linear superposition principle, it cannot be directly used in the case of varying heat transfer coefficients. In the present work, a different methodology is proposed, based upon CMS for temperature transient calculation and upon the GFT for the related thermal stress evaluation. This new approach allows variable heat transfer coefficients to be accounted for. The methodology is applied for two different case studies, taken from the literature: a thick pipe and a nozzle connected to a spherical head, both subjected to multiple convective boundary conditions
Heat Transfer Coefficient at Cast-Mold Interface During Centrifugal Casting: Calculation of Air Gap
Bohacek, Jan; Kharicha, Abdellah; Ludwig, Andreas; Wu, Menghuai; Karimi-Sibaki, Ebrahim
2018-06-01
During centrifugal casting, the thermal resistance at the cast-mold interface represents a main blockage mechanism for heat transfer. In addition to the refractory coating, an air gap begins to form due to the shrinkage of the casting and the mold expansion, under the continuous influence of strong centrifugal forces. Here, the heat transfer coefficient at the cast-mold interface h has been determined from calculations of the air gap thickness d a based on a plane stress model taking into account thermoelastic stresses, centrifugal forces, plastic deformations, and a temperature-dependent Young's modulus. The numerical approach proposed here is rather novel and tries to offer an alternative to the empirical formulas usually used in numerical simulations for a description of a time-dependent heat transfer coefficient h. Several numerical tests were performed for different coating thicknesses d C, rotation rates Ω, and temperatures of solidus T sol. Results demonstrated that the scenario at the interface is unique for each set of parameters, hindering the possibility of employing empirical formulas without a preceding experiment being performed. Initial values of h are simply equivalent to the ratio of the coating thermal conductivity and its thickness ( 1000 Wm-2 K-1). Later, when the air gap is formed, h drops exponentially to values at least one order of magnitude smaller ( 100 Wm-2 K-1).
Thermally-induced bowing of CANDU fuel elements
International Nuclear Information System (INIS)
Suk, H.C.; Sim, K.S.; Park, J.H.; Park, G.S.
1995-01-01
Considering only the thermally-induced bending moments which are generated both within the sheath and between the fuel and sheath by an asymmetric temperature distribution with respect to the axis of an element, a generalized and explicit analytical formula for the thermally-induced bending is developed in this paper, based on the cases of 1) the bending of an empty tube treated by neglecting of the fuel/sheath mechanical interaction and 2) the fuel/sheath interaction due to the pellet and sheath temperature variations. In each of the cases, the temperature asymmetries in sheath are modelled to be caused by the combined effects of (i) non-uniform coolant temperature due to imperfect coolant mixing, (ii) variable sheath/coolant heat transfer coefficient, (iii) asymmetric heat generation due to neutron flux gradients across an element and so as to inclusively cover the uniform temperature distributions within the fuel and sheath with respect to the axial centerline. Investigating the relative importance of the various parameters affecting fuel element bowing, the element bowing is found to be greatly affected with the variations of element length, sheath diameter, pellet/sheath mechanical interaction and neutron flux depression factors, pellet thermal expansion coefficient, pellet/sheath heat transfer coefficient in comparison with those of other parameters such as sheath thickness, film heat transfer coefficient, sheath thermal expansion coefficient, and sheath and pellet thermal conductivities. Also, the element bowing of the standard 37-element bundle and CANFLEX 43-element bundle for the use in CANDU-6 reactors was analyzed with the formula, which could help to demonstrate the integrity of the fuel. All the required input data for the analyses were generated in terms of the reactor operation conditions on the reactor physics, thermal hydraulics and fuel performance by using various CANDU computer codes. The analysis results indicate that the CANFLEX 43-element
Thermal expansion and thermal conductivity characteristics of Cu–Al2O3 nanocomposites
International Nuclear Information System (INIS)
Fathy, A.; El-Kady, Omyma
2013-01-01
Highlights: ► The copper–alumina composites were prepared by powder metallurgy (P/M) method with nano-Cu/Al 2 O 3 powders. ► The Al 2 O 3 content was added by 2.5, 7.5 and 12.5 wt.% to the Cu matrix to detect its effect on thermal conductivity and thermal expansion behavior of the resultant Cu/Al 2 O 3 nanocomposites. ► The results showed that alumina nanoparticles (30 nm) were distributed in the copper matrix in a homogeneous manner. ► The measured thermal conductivity for the Cu–Al 2 O 3 nanocomposites decreased from 384 to 78.1 W/m K with increasing Al 2 O 3 content from 0 to 12.5 wt.%. ► Accordingly, the coefficient of thermal expansion (CTE) was tailored from 33 × 10 −6 to 17.74 × 10 −6 /K, which is compatible with the CTE of semiconductors in electronic packaging applications. - Abstract: Copper–alumina composites were prepared by powder metallurgy (P/M) technology. Nano-Cu/Al 2 O 3 powders, was deoxidized from CuO/Al 2 O 3 powders which synthesized by thermochemical technique by addition of Cu powder to an aqueous solution of aluminum nitrate. The Al 2 O 3 content was added by 2.5, 7.5 and 12.5 wt.% to the Cu matrix to detect its effect on thermal conductivity and thermal expansion behavior of the resultant Cu/Al 2 O 3 nanocomposites. The results showed that alumina nanoparticles (30 nm) were distributed in the copper matrix in a homogeneous manner. The measured thermal conductivity for the Cu–Al 2 O 3 nanocomposites decreased from 384 to 78.1 W/m K with increasing Al 2 O 3 content from 0 to 12.5 wt.%. The large variation in the thermal conductivities can be related to the microstructural characteristics of the interface between Al 2 O 3 and the Cu-matrix. Accordingly, the coefficient of thermal expansion (CTE) was tailored from 33 × 10 −6 to 17.74 × 10 −6 /K, which is compatible with the CTE of semiconductors in electronic packaging applications. The reduction of thermal conductivity and coefficient of thermal expansion were
Design of materials with extreme thermal expansion using a three-phase topology optimization method
DEFF Research Database (Denmark)
Sigmund, Ole; Torquato, S.
1997-01-01
Composites with extremal or unusual thermal expansion coefficients are designed using a three-phase topology optimization method. The composites are made of two different material phases and a void phase. The topology optimization method consists in finding the distribution of material phases...... materials having maximum directional thermal expansion (thermal actuators), zero isotropic thermal expansion, and negative isotropic thermal expansion. It is shown that materials with effective negative thermal expansion coefficients can be obtained by mixing two phases with positive thermal expansion...
Energy Technology Data Exchange (ETDEWEB)
Mihajlov, A A [Institute of Physics, PO Box 57, 11001 Belgrade (Serbia and Montenegro); Ignjatovic, Lj M [Institute of Physics, PO Box 57, 11001 Belgrade (Serbia and Montenegro); Djuric, Z [Silvaco Data Systems, Compass Point, St Ives PE27 5JL (United Kingdom); Ljepojevic, N N [Silvaco Data Systems, Compass Point, St Ives PE27 5JL (United Kingdom)
2004-11-28
This paper presents the results of semi-classical calculations of rate coefficients of (n - n')-mixing processes in collisions of Rydberg atoms H*(n) with H(1s) atoms. These processes have been modelled by the mechanism of the resonant energy exchange within the electron component of the H*(n) + H collisional system. The calculations of the rate coefficients, based on this model, were performed for the series of principal quantum numbers, n and n', and atomic, T{sub a}, and electronic, T{sub e}, temperatures. It was shown that these processes can be of significant influence on the populations of Rydberg atoms in weakly ionized plasmas (ionization degree {approx}<10{sup -4}), and therefore have to be included in appropriate models of such plasmas.
Thermal expansion of spinel-type Si3N4
DEFF Research Database (Denmark)
Paszkowics, W.; Minkikayev, R.; Piszora, P.
2004-01-01
The lattice parameter and thermal expansion coefficient (TEC) for the spinel-type Si3N4 phase prepared under high-pressure and high-temperature conditions are determined for 14 K......The lattice parameter and thermal expansion coefficient (TEC) for the spinel-type Si3N4 phase prepared under high-pressure and high-temperature conditions are determined for 14 K...
Ivanov, Mikhail V; Babikov, Dmitri
2012-05-14
Efficient method is proposed for computing thermal rate constant of recombination reaction that proceeds according to the energy transfer mechanism, when an energized molecule is formed from reactants first, and is stabilized later by collision with quencher. The mixed quantum-classical theory for the collisional energy transfer and the ro-vibrational energy flow [M. Ivanov and D. Babikov, J. Chem. Phys. 134, 144107 (2011)] is employed to treat the dynamics of molecule + quencher collision. Efficiency is achieved by sampling simultaneously (i) the thermal collision energy, (ii) the impact parameter, and (iii) the incident direction of quencher, as well as (iv) the rotational state of energized molecule. This approach is applied to calculate third-order rate constant of the recombination reaction that forms the (16)O(18)O(16)O isotopomer of ozone. Comparison of the predicted rate vs. experimental result is presented.
Theoretical Time Dependent Thermal Neutron Spectra and Reaction Rates in H2O and D2O
International Nuclear Information System (INIS)
Purohit, S.N.
1966-04-01
The early theoretical and experimental time dependent neutron thermalization studies were limited to the study of the transient spectrum in the diffusion period. The recent experimental measurements of the time dependent thermal neutron spectra and reaction rates, for a number of moderators, have generated considerable interest in the study of the time dependent Boltzmann equation. In this paper we present detailed results for the time dependent spectra and the reaction rates for resonance detectors using several scattering models of H 2 O and D 2 O. This study has been undertaken in order to interpret the integral time dependent neutron thermalization experiments in liquid moderators which have been performed at the AB Atomenergi. The proton gas and the deuteron gas models are inadequate to explain the measured reaction rates in H 2 O and D 2 O. The bound models of Nelkin for H 2 O and of Butler for D 2 O give much better agreement with the experimental results than the gas models. Nevertheless, some disagreement between theoretical and experimental results still persists. This study also indicates that the bound model of Butler and the effective mass 3. 6 gas model of Brown and St. John give almost identical reaction rates. It is also surprising to note that the calculated reaction rate for Cd for the Butler model appears to be in better agreement with the experimental results of D 2 O than of the Nelkin model with H 2 O experiments. The present reaction rate studies are sensitive enough so as to distinguish between the gas model and the bound model of a moderator. However, to investigate the details of a scattering law (such as the effect of the hindered rotations in H 2 O and D 2 O and the weights of different dynamical modes) with the help of these studies would require further theoretical as well as experimental investigations. Theoretical results can be further improved by improving the source for thermal neutrons, the group structure and the scattering
Thermal characteristics of rocks for high-level waste repository
International Nuclear Information System (INIS)
Shimooka, Kenji; Ishizaki, Kanjiro; Okamoto, Masamichi; Kumata, Masahiro; Araki, Kunio; Amano, Hiroshi
1980-12-01
Heat released by the radioactive decay of high-level waste in an underground repository causes a long term thermal disturbance in the surrounding rock mass. Several rocks constituting geological formations in Japan were gathered and specific heat, thermal conductivity, thermal expansion coefficient and compressive strength were measured. Thermal analysis and chemical analysis were also carried out. It was found that volcanic rocks, i.e. Andesite and Basalt had the most favorable thermal characteristics up to around 1000 0 C and plutonic rock, i.e. Granite had also favorable characteristics under 573 0 C, transition temperature of quartz. Other igneous rocks, i.e. Rhyolite and Propylite had a problem of decomposition at around 500 0 C. Sedimentary rocks, i.e. Zeolite, Tuff, Sandstone and Diatomite were less favorable because of their decomposition, low thermal conductivity and large thermal expansion coefficient. (author)
Metabolic rate and thermal conductance of lemmings from high-arctic Canada and Siberia
Klaassen, M.R.J.; Agrell, J.; Lindström, A.
2002-01-01
The arctic climate places high demands on the energy metabolism of its inhabitants. We measured resting (RMR) and basal metabolic rates (BMR), body temperatures, and dry and wet thermal conductances in summer morphs of the lemmings Dicrostonyx groenlandicus and Lemmus trimucronatus in arctic Canada,
Xie, Haiwei; Zhang, Yan
2018-03-01
The relationship between dynamic infrared (IR) thermal images and blood perfusion rate of the tongues of anaemia patients was investigated. Blood perfusion rates at multiple locations on the tongues of 62 anaemia patients and 70 control subjects were measured. For both groups of subjects, dynamic IR thermal images were also recorded within 16 s after the mouth opened. The results showed that the blood perfusion rates at different sites (apex, middle, left side and right side) on the tongues in anaemia patients (3.49, 3.71, 3.85 and 3.77 kg/s m-3) were significantly lower than those at the corresponding sites in control subjects (4.45, 4.66, 4.81 and 4.70 kg/s m-3). After the mouth opened, the tongue temperature decreased more rapidly in anaemia patients than in control subjects. To analyse the heat transfer mechanism, a transient heat transfer model of the tongue was developed. The tongue temperatures in anaemia patients and control subjects were calculated using this model and compared to the tongue temperatures measured by the IR thermal imager. The relationship between the tongue surface temperature and the tongue blood perfusion rate was analysed. The simulation results indicated that the low blood perfusion rate and the correlated changes in anaemia patients can cause faster temperature decreases of the tongue surface.
Directory of Open Access Journals (Sweden)
Gupta Nishi
2016-01-01
Full Text Available Seth's transition theory is applied to the problem of thermal creep transition stresses and strain rates in a thin rotating disc with shaft having variable density by finite deformation. Neither the yield criterion nor the associated flow rule is assumed here. The results obtained here are applicable to compressible materials. If the additional condition of incompressibility is imposed, then the expression for stresses corresponds to those arising from Tresca yield condition. Thermal effect decreased value of radial stress at the internal surface of the rotating isotropic disc made of compressible material as well as incompressible material and this value of radial stress further much increases with the increase in angular speed. With the introduction of thermal effects, the maximum value of strain rates further increases at the internal surface for compressible materials as compare to incompressible material.
International Nuclear Information System (INIS)
Ohki, Naohisa; Harayama, Yasuo; Takeda, Tsuneo; Izumi, Fumio.
1977-12-01
In safety evaluation of a fuel rod, estimation of the stored energy in the fuel rod is indispensable. For this estimation, the temperature distribution in the fuel rod is calculated. Most important in determination of the temperature distribution is the gap heat transfer coefficient (gap conductance) between pellet surface and cladding inner surface. Under fuel rod operating condition, the mixed gas in the gap is composed of He, Xe and Kr. He is initial seald gas. Xe and Kr are fission-product gases, of which the quantities depend on the fuel burn-up. In program GAPCON series (GAPCON and GAPCON-THERMAL-1 and -2) and FREG-3, these quantities are given as a function of the irradiation time, power rating and neutron flux in estimation of the thermal conductivity of the mixed gas. The methods of calculating the quantities of Xe and Kr in the programs have been examined. Input of the neutron flux which influences F.P. gas production rates is better than the determination from the fuel-rod power rating. (auth.)
Thermal expansion of two-dimensional itinerant nearly ferromagnetic metal
International Nuclear Information System (INIS)
Konno, R; Hatayama, N; Takahashi, Y; Nakano, H
2009-01-01
Thermal expansion of two-dimensional itinerant nearly ferromagnetic metal is investigated according to the recent theoretical development of magneto-volume effect for the three-dimensional weak ferromagnets. We particularly focus on the T 2 -linear thermal expansion of magnetic origin at low temperatures, so far disregarded by conventional theories. As the effect of thermal spin fluctuations we have found that the T-linear thermal expansion coefficient shows strong enhancement by assuming the double Lorentzian form of the non-interacting dynamical susceptibility justified in the small wave-number and low frequency region. It grows faster in proportional to y -1/2 as we approach the magnetic instability point than two-dimensional nearly antiferromagnetic metals with ln(1/y s ) dependence, where y and y s are the inverses of the reduced uniform and staggered magnetic susceptibilities, respectively. Our result is consistent with the Grueneisen's relation between the thermal expansion coefficient and the specific heat at low temperatures. In 2-dimensional electron gas we find that the thermal expansion coefficient is divergent with a finite y when the higher order term of non-interacting dynamical susceptibility is taken into account.
International Nuclear Information System (INIS)
Sadowski, P.W.; Matthews, R.A.
1986-06-01
Sweet gum and sycamore leaf packs were packs were placed in a thermally stressed, a post-thermal, and an ambient stream located on the Savannah River Plant, South Carolina, and in the Savannah River below the mouth of each stream. Processing rates for the leaf packs were determined over a 77-day period from December 1982 to March 1983. Due to inundation of the sampling sites by river flooding, temperatures in the stream receiving thermal effluent were reduced after day 24. Sweet gum leaves decomposed considerably faster than did sycamore leaves, particularly in the thermal creek. An exponential decay model was used to demonstrate significant differences in loss of ash-free dry weight from leaf packs in thermally stressed and nonthermal creeks. Differences in leaf processing rates between creek sites were greatest during periods of therma stress. Within each leaf species, leaf processing rates were not significantly different between nonthermal sites, nor between sites in the Savannah River
Choi, Hyoung-Seuk; Choi, Soon-Mok; Choi, Duck-Kyun
2016-01-01
A Pb-free PTC (positive temperature coefficient thermistor) heater was developed in the Ba0.97(Bi0.5Na0.5)0.03TiO3 system especially for automotive part applications. The reliability was verified by using a thermal cycling test designed on the basis of the result from a quality function deployment (QFD) analysis. We compared the thermal cycling test results from the newly-developed Pb-free PTC heaters with the results from PTC heaters currently on the market, namely, PTC heaters containing Pb. Life prediction and stress-strength relationships were analyzed together with a thermal diffusivity evaluation. We discuss the potential failure mechanisms during the thermal cycling test, focusing on the fact that electrical degradation in PTC materials is closely related to mechanical degradation due to the internal stress in the materials that comes from repeated phase changes. Different grain size distributions on the sintered bulks were considered to a key factor for explaining the different results of the reliability tests between the new Pb-free PTC heaters developed in this study and the commercial PTC heaters containing Pb.
Thermal sensation and comfort with transient metabolic rates
DEFF Research Database (Denmark)
Goto, Tomonobu; Toftum, Jørn; Dear, R. d.
2002-01-01
This study investigated the effect on thermal perceptions and preferences of controlled metabolic excursions of various intensities (20%, 40%, 60% relative work load) and durations (3-30 min) imposed on subjects that alternated between sedentary activity and exercise on a treadmill. The thermal...... environment was held constant at a temperature corresponding to PMV=0 at sedentary activity. Even low activity changes of short duration (1 min at 20% relative work load) affected thermal perceptions. However, after circa 15 min of constant activity, subjective thermal responses approximated the steady...
Pawlak, Mariusz; Ben-Asher, Anael; Moiseyev, Nimrod
2018-01-09
We present a simple expression and its derivation for reaction rate coefficients for cold anisotropic collision experiments based on adiabatic variational theory and time-independent non-Hermitian scattering theory. We demonstrate that only the eigenenergies of the resulting one-dimensional Schrödinger equation for different complex adiabats are required. The expression is applied to calculate the Penning ionization rate coefficients of an excited metastable helium atom with molecular hydrogen in an energy range spanning from hundreds of kelvins down to the millikelvin regime. Except for trivial quantities like the masses of the nuclei and the bond length of the diatomic molecule participating in the collision, one needs as input data only the complex potential energy surface (CPES). In calculations, we used recently obtained ab initio CPES by D. Bhattacharya et al. ( J. Chem. Theory Comput. 2017 , 13 , 1682 - 1690 ) without fitting parameters. The results show good accord with current measurements ( Nat. Phys. 2017 , 13 , 35 - 38 ).
Directory of Open Access Journals (Sweden)
Huann-Ming Chou
2015-01-01
Full Text Available The electrical industries have been fast developing over the past decades. Moreover, the trend of microelements and packed division multiplex is obviously for the electrical industry. Hence, the high heat dissipative and the electrical insulating device have been popular and necessary. The thermal conduct coefficient of aluminum nitride (i.e., AlN is many times larger than the other materials. Moreover, the green technology of composite with phase change materials (i.e., PCMs is worked as a constant temperature cooler. Therefore, PCMs have been used frequently for saving energy and the green environment. Based on the above statements, it does show great potential in heat dissipative for the AlN film compositing with PCM. Therefore, this paper is focused on the research of thermal contact resistance and heat transfer between the AlN/PCM pairs. According to the experimental results, the heat transfer decreases and the thermal contact resistance increases under the melting process of PCM. However, the suitable parameters such as contact pressures can be used to improve the above defects.
The Heat Transfer Coefficient of Recycled Concrete Bricks Combination with EPS Insulation Board Wall
Directory of Open Access Journals (Sweden)
Jianhua Li
2015-01-01
Full Text Available Four tectonic forms samples were conducted to test their heat transfer coefficients. By analyzing and comparing the test values and theoretical values of the heat transfer coefficient, a corrected-value calculation method for determining the heat transfer coefficient was proposed; the proposed method was proved to be reasonably correct. The results indicated that the recycled concrete brick wall heat transfer coefficient is higher than that of the clay brick wall, the heat transfer coefficient of recycled concrete brick wall could be effectively reduced when combined with the EPS insulation board, and the sandwich insulation type was better than that of external thermal insulation type.
Anisotropic Thermal Behavior of Silicone Polymer, DC 745
Energy Technology Data Exchange (ETDEWEB)
Adams, Jillian Cathleen [Univ. of Oregon, Eugene, OR (United States). Dept. of Chemistry; Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Torres, Joseph Angelo [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Volz, Heather Michelle [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Gallegos, Jennifer Marie [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Yang, Dali [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
2016-09-02
In material applications, it is important to understand how polymeric materials behave in the various environments they may encounter. One factor governing polymer behavior is processing history. Differences in fabrication will result in parts with varied or even unintended properties. In this work, the thermal expansion behavior of silicone DC 745 is studied. Thermomechanical analysis (TMA) is used to determine changes in sample dimension resulting from changes in temperature. This technique can measure thermal events such as the linear coefficient of thermal expansion (CTE), melting, glass transitions, cure shrinkage, and internal relaxations. Using a thermomechanical analyzer (Q400 TMA), it is determined that DC 745 expands anisotropically when heated. This means that the material has a different CTE depending upon which direction is being measured. In this study, TMA experiments were designed in order to confirm anisotropic thermal behavior in multiple DC 745 samples of various ages and lots. TMA parameters such as temperature ramp rate, preload force, and temperature range were optimized in order to ensure the most accurate and useful data. A better understanding of the thermal expansion of DC 745 will allow for more accurate modeling of systems using this material.
Dose rate effect on the yield of radiation induced response with thermal fading
International Nuclear Information System (INIS)
Chernov, V.; Rogalev, B.; Barboza-Flores, M.
2005-01-01
A model describing the dependences of the accumulation of thermally unstable radiation induced defects on the dose and dose rate is proposed. The model directly takes into account the track nature of the ionizing radiation represented as accumulation processes of defects in tracks averaged over a crystal volume considering various degrees of overlapping in space and time. The accumulation of the defects in the tracks is phenomenologically described. General expressions are obtained that allows radiation yield simulation of defects involving known creation and transformation processes. The cases considered, of linear accumulation (constant increment of the defects in tracks) and accumulation with saturation (complete saturation of the defects in one track), lead to a set of linear dose dependences with saturation, which are routinely used in luminescence and ESR dating. The accumulation, with increase of sensitivity in regions overlapped by two or more tracks, gave a set of dose dependences, from linear-sublinear-linear-saturation, distinctive of quartz up to linear-supralinear-linear-saturation. It is shown that the effect of the dose rate on dose dependences is determined by a dimensionless parameter a=Pτ/D0, where P is the dose rate, τ is the defect lifetime and D0 is the track dose. At a-bar 1 the dose rate influences basically the accumulation of thermally unstable defects. In the reverse case the dose dependences did not seems to be influenced by the dose rate
Thermal conductivity of different colored compomers.
Guler, Cigdem; Keles, Ali; Guler, Mehmet S; Karagoz, Sendogan; Cora, Ömer N; Keskin, Gul
2017-11-10
Compomers are mostly used in primary dentition. The thermal conductivity properties of traditional or colored compomers have not been investigated in detail so far. The aim of this in vitro study was to assess and compare the thermal conductivities of traditional and colored compomers. Two sets of compomers - namely, Twinky Star (available in berry, lemon, green, silver, blue, pink, gold and orange shades) and Dyract Extra (available in B1, A3 and A2 shades) - were included in this study. All of the traditional and colored compomers were applied to standard molds and polymerized according to the manufacturers' instructions. Three samples were prepared from each compomer. Measurements were conducted using a heat conduction test setup, and the coefficient of heat conductivity was calculated for each material. The heat conductivity coefficients were statistically analyzed using Kruskal-Wallis and Duncan tests. Uncertainty analysis was also performed on the calculated coefficients of heat conductivity. Statistically significant differences were found (p<0.05) between the thermal conductivity properties of the traditional and colored compomers examined. Among all of the tested compomers, the silver shade compomer exhibited the highest coefficient of heat conductivity (p<0.05), while the berry shade exhibited the lowest coefficient (p<0.05). Uncertainty analyses revealed that 6 out of 11 samples showed significant differences. The silver shade compomer should be avoided in deep cavities. The material properties could be improved for colored compomers.
Gupta, Roop N.; Yos, Jerrold M.; Thompson, Richard A.; Lee, Kam-Pui
1990-01-01
Reaction rate coefficients and thermodynamic and transport properties are reviewed and supplemented for the 11-species air model which can be used for analyzing flows in chemical and thermal nonequilibrium up to temperatures of 3000 K. Such flows will likely occur around currently planned and future hypersonic vehicles. Guidelines for determining the state of the surrounding environment are provided. Curve fits are given for the various species properties for their efficient computation in flowfield codes. Approximate and more exact formulas are provided for computing the properties of partially ionized air mixtures in a high energy environment. Limitations of the approximate mixing laws are discussed for a mixture of ionized species. An electron number-density correction for the transport properties of the charged species is obtained. This correction has been generally ignored in the literature.
International Nuclear Information System (INIS)
Uh, J. H.; Kim, E. K.; Kim, S. O.
2003-01-01
The design characteristics and the decay heat removal capacity according to the type of DHR (Decay Heat Removal) system in LMR are quantitatively analyzed, and the general relationship between the rated core thermal power and decay heat removal capacity is created in this study. Based on these analyses results, a feasibility of designing a larger thermal rating KALIMER plant is investigated in view of decay heat removal capacity, and DRC (Direct Reactor Cooling) type DHR system which rejects heat from the reactor pool to air is proper to satisfy the decay heat removal capacity for a large thermal rating plant above 1,000 MWth. Some defects, however, including the heat loss under normal plant operation and the lack of reliance associated with system operation should be resolved in order to adopt the total passive concept. Therefore, the new concept of DHR system for a larger thermal rating KALIMER design, named as PDRC (passive decay heat removal circuit), is established in this study. In the newly established concept of PDRC, the Na-Na heat exchanger is located above the sodium cold pool and is prevented from the direct sodium contact during normal operation. This total passive feature has the superiority in the aspect of the minimizing the normal heat loss and the increasing the operation reliance of DHR system by removing either any operator action or any external operation signal associated with system operation. From this study, it is confirmed that the new concept of PDRC is useful to the designing of a large thermal rating power plant of KALIMER-600 in view of decay heat removal capability
International Nuclear Information System (INIS)
Drozdowicz, K.
1999-01-01
Macroscopic parameters for a description of the thermal neutron transport in finite volumes are considered. A very good correspondence between the theoretical and experimental parameters of hydrogenous media is attained. Thermal neutrons in the medium possess an energy distribution, which is dependent on the size (characterized by the geometric buckling) and on the neutron transport properties of the medium. In a hydrogenous material the thermal neutron transport is dominated by the scattering cross section which is strongly dependent on energy. A monoenergetic treatment of the thermal neutron group (admissible for other materials) leads in this case to a discrepancy between theoretical and experimental results. In the present paper the theoretical definitions of the pulsed thermal neutron parameters (the absorption rate, the diffusion coefficient, and the diffusion cooling coefficient) are based on Nelkin's analysis of the decay of a neutron pulse. Problems of the experimental determination of these parameters for a hydrogenous medium are discussed. A theoretical calculation of the pulsed parameters requires knowledge of the scattering kernel. For thermal neutrons it is individual for each hydrogenous material because neutron scattering on hydrogen nuclei bound in a molecule is affected by the molecular dynamics (characterized with internal energy modes which are comparable to the incident neutron energy). Granada's synthetic model for slow-neutron scattering is used. The complete up-dated formalism of calculation of the energy transfer scattering kernel after this model is presented in the paper. An influence of some minor variants within the model on the calculated differential and integral neutron parameters is shown. The theoretical energy-dependent scattering cross section (of Plexiglas) is compared to experimental results. A particular attention is paid to the calculation of the diffusion cooling coefficient. A solution of an equation, which determines the
International Nuclear Information System (INIS)
Palmer, B.J.
1994-01-01
A method to calculate the thermal diffusivity D T from spontaneous fluctuations in the local heat energy density is presented. Calculations of the thermal diffusivity are performed for the Lennard-Jones fluid, carbon dioxide, and water. The results for the Lennard-Jones fluid are in agreement with calculations of the thermal conductivity using Green-Kubo relations and nonequilibrium molecular-dynamics techniques. The results for carbon dioxide and water give thermal diffusivities within a factor of 2 of the experimental values
Sinha, Nitish; Singh, Arun K.; Singh, Trilok N.
2018-05-01
In this article, we study numerically the dynamic stability of the rate, state, temperature, and pore pressure friction (RSTPF) model at a rock interface using standard spring-mass sliding system. This particular friction model is a basically modified form of the previously studied friction model namely the rate, state, and temperature friction (RSTF). The RSTPF takes into account the role of thermal pressurization including dilatancy and permeability of the pore fluid due to shear heating at the slip interface. The linear stability analysis shows that the critical stiffness, at which the sliding becomes stable to unstable or vice versa, increases with the coefficient of thermal pressurization. Critical stiffness, on the other hand, remains constant for small values of either dilatancy factor or hydraulic diffusivity, but the same decreases as their values are increased further from dilatancy factor (˜ 10^{ - 4} ) and hydraulic diffusivity (˜ 10^{ - 9} {m}2 {s}^{ - 1} ) . Moreover, steady-state friction is independent of the coefficient of thermal pressurization, hydraulic diffusivity, and dilatancy factor. The proposed model is also used for predicting time of failure of a creeping interface of a rock slope under the constant gravitational force. It is observed that time of failure decreases with increase in coefficient of thermal pressurization and hydraulic diffusivity, but the dilatancy factor delays the failure of the rock fault under the condition of heat accumulation at the creeping interface. Moreover, stiffness of the rock-mass also stabilizes the failure process of the interface as the strain energy due to the gravitational force accumulates in the rock-mass before it transfers to the sliding interface. Practical implications of the present study are also discussed.
Chromium effect on the Young modulus and thermoelastic coefficient of elinvars
International Nuclear Information System (INIS)
Sazykina, A.V.; Khomenko, O.A.
1976-01-01
The effect was studied of thermal and thermal-mechanical treatment upon the elastic modules and its temperature coefficient in iron-nickel Elinvars with different chromium contents (from 0 to 6.7%). It has been shown that doping with chromium results in an increase in the modulus of elasticity of Elinvars after hardening. The elastic modulus of alloys containing no chromium increases after a cold plastic deformation (drawing), whereas that of chromous Elinvars decreases upon such a treatment. It has been established that the elastic modulus of hardened and cold drawn after hardening Elinvars increases upon ageing. An increase in chromium content in iron-nickel Elinvars reduces the effect of the temperature of ageing upon the thermoelastic coefficient during the usual heat treatment and the thermalmechanical treatment and lowers its sensitivity to the influence of an external magnetic field [ru
International Nuclear Information System (INIS)
Moeller, S.V.
1982-09-01
The determination of the heat transfer coefficient of the pins of the Spallation Neutron Source is a very important problem for the development of this facility, as data for thermal and structural studies. For this purpose, a test apparatus was built, in scale 1:1, for the simulation of the thermal and hydraulical conditions of the Neutron Source. This apparatus is a pin bank, with one of the pins electrically heated. Performance of measurements gave the values for the heat transfer coefficient, here presented in the Nusselt Number form, and its local distribution. Results show the linear dependence of Nusselt Number on Reynolds Number, for a constant heat production. (orig.) [de
Qiu, Guo Yu; Zhao, Ming
2010-03-01
Remote monitoring of soil evaporation and soil water status is necessary for water resource and environment management. Ground based remote sensing can be the bridge between satellite remote sensing and ground-based point measurement. The primary object of this study is to provide an algorithm to estimate evaporation and soil water status by remote sensing and to verify its accuracy. Observations were carried out in a flat field with varied soil water content. High-resolution thermal images were taken with a thermal camera; soil evaporation was measured with a weighing lysimeter; weather data were recorded at a nearby meteorological station. Based on the thermal imaging and the three-temperatures model (3T model), we developed an algorithm to estimate soil evaporation and soil water status. The required parameters of the proposed method were soil surface temperature, air temperature, and solar radiation. By using the proposed method, daily variation in soil evaporation was estimated. Meanwhile, soil water status was remotely monitored by using the soil evaporation transfer coefficient. Results showed that the daily variation trends of measured and estimated evaporation agreed with each other, with a regression line of y = 0.92x and coefficient of determination R(2) = 0.69. The simplicity of the proposed method makes the 3T model a potentially valuable tool for remote sensing.
A Formula for the Coefficient of Thermal Expansion of Crude Oils ...
African Journals Online (AJOL)
A new formula for the calculation of the coefficient of world crude oils has been developed. The formula is semi theoretical. The empirical part was obtained by regression calculation of the Formation Volume Factor of the gas free crude oil at reservoir temperature. Comparison of the calculated values of the Formation ...
Cool-down flow-rate limits imposed by thermal stresses in LNG pipelines
Novak, J. K.; Edeskuty, F. J.; Bartlit, J. R.
Warm cryogenic pipelines are usually cooled to operating temperature by a small, steady flow of the liquid cryogen. If this flow rate is too high or too low, undesirable stresses will be produced. Low flow-rate limits based on avoidance of stratified two-phase flow were calculated for pipelines cooled with liquid hydrogen or nitrogen. High flow-rate limits for stainless steel and aluminum pipelines cooled by liquid hydrogen or nitrogen were determined by calculating thermal stress in thick components vs flow rate and then selecting some reasonable stress limits. The present work extends these calculations to pipelines made of AISI 304 stainless steel, 6061 aluminum, or ASTM A420 9% nickel steel cooled by liquid methane or a typical natural gas. Results indicate that aluminum and 9% nickel steel components can tolerate very high cool-down flow rates, based on not exceeding the material yield strength.
Directory of Open Access Journals (Sweden)
Kambiz Raoufi
2011-01-01
Full Text Available A finite element model is used to examine how the properties of cementitious mortar are related to the stress development in the dual ring test. The results of this investigation are used to explain the thermal cracking behavior of mixtures containing prewetted lightweight aggregates (LWA by quantifying the contribution of several material properties individually. In addition to the beneficial effects of using the LWA as an internal curing agent to reduce the autogenous shrinkage of concrete, the LWA also helps to reduce the potential for thermal cracking due to a lower elastic modulus and increased stress relaxation. The rate of stress development, age of cracking, and magnitude of the temperature drop necessary to induce cracking in a dual ring specimen are dependent on a variety of factors, including the coefficient of thermal expansion of both the cementitious mortar and the restraining rings, elastic modulus of the mortar, creep effect of the mortar, and rate of thermal loading. Depending on the rate of cooling, cracking may or may not occur. The slowest rate of cooling (2.5∘C/h minimizes the effects of creep while cooling rates faster than 8∘C/h can produce a thermal gradient through the mortar cross-section that needs to be considered.
Measurement of specific heat and specific absorption rate by nuclear magnetic resonance
Energy Technology Data Exchange (ETDEWEB)
Gultekin, David H., E-mail: david.gultekin@aya.yale.edu [Department of Electrical Engineering, Yale University, New Haven, CT 06520 (United States); Department of Medical Physics, Memorial Sloan-Kettering Cancer Center, New York, NY 10065 (United States); Department of Radiology, Memorial Sloan-Kettering Cancer Center, New York, NY 10065 (United States); Institute of Imaging Science, Vanderbilt University, Nashville, TN 37232 (United States); Gore, John C. [Department of Biomedical Engineering, Vanderbilt University, Nashville, TN 37232 (United States); Department of Radiology and Radiological Sciences, Vanderbilt University, Nashville, TN 37232 (United States); Department of Molecular Physiology and Biophysics, Vanderbilt University, Nashville, TN 37232 (United States); Department of Physics and Astronomy, Vanderbilt University, Nashville, TN 37232 (United States); Institute of Imaging Science, Vanderbilt University, Nashville, TN 37232 (United States)
2010-05-20
We evaluate a nuclear magnetic resonance (NMR) method of calorimetry for the measurement of specific heat (c{sub p}) and specific absorption rate (SAR) in liquids. The feasibility of NMR calorimetry is demonstrated by experimental measurements of water, ethylene glycol and glycerol using any of three different NMR parameters (chemical shift, spin-spin relaxation rate and equilibrium nuclear magnetization). The method involves heating the sample using a continuous wave laser beam and measuring the temporal variation of the spatially averaged NMR parameter by non-invasive means. The temporal variation of the spatially averaged NMR parameter as a function of thermal power yields the ratio of the heat capacity to the respective nuclear thermal coefficient, from which the specific heat can be determined for the substance. The specific absorption rate is obtained by subjecting the liquid to heating by two types of radiation, radiofrequency (RF) and near-infrared (NIR), and by measuring the change in the nuclear spin phase shift by a gradient echo imaging sequence. These studies suggest NMR may be a useful tool for measurements of the thermal properties of liquids.
Jubb, Aaron M; Gierczak, Tomasz; Baasandorj, Munkhbayar; Waterland, Robert L; Burkholder, James B
2014-05-06
Mixtures of methyl-perfluoroheptene-ethers (CH3OC7F13, MPHEs) are currently in use as replacements for perfluorinated alkanes (PFCs) and poly-ether heat transfer fluids, which are persistent greenhouse gases with lifetimes >1000 years. At present, the atmospheric processing and environmental impact from the use of MPHEs is unknown. In this work, rate coefficients at 296 K for the gas-phase reaction of the OH radical with six key isomers (including stereoisomers and enantiomers) of MPHEs used commercially were measured using a relative rate method. Rate coefficients for the six MPHE isomers ranged from ∼ 0.1 to 2.9 × 10(-12) cm(3) molecule(-1) s(-1) with a strong stereoisomer and -OCH3 group position dependence; the (E)-stereoisomers with the -OCH3 group in an α- position relative to the double bond had the greatest reactivity. Rate coefficients measured for the d3-MPHE isomer analogues showed decreased reactivity consistent with a minor contribution of H atom abstraction from the -OCH3 group to the overall reactivity. Estimated atmospheric lifetimes for the MPHE isomers range from days to months. Atmospheric lifetimes, radiative efficiencies, and global warming potentials for these short-lived MPHE isomers were estimated based on the measured OH rate coefficients along with measured and theoretically calculated MPHE infrared absorption spectra. Our results highlight the importance of quantifying the atmospheric impact of individual components in an isomeric mixture.
Direct quantum mechanical calculation of the F + H{sub 2} {yields} HF + H thermal rate constant
Energy Technology Data Exchange (ETDEWEB)
Moix, Marc [Computer Simulation and Modeling (COSMO) Lab, Parc Cientific de Barcelona, Josep Samitier 5, 08028 Barcelona (Spain); Institut de Quimica Teorica i Computacional de la UB (IQTCUB), Universitat de Barcelona (Spain); Huarte-Larranaga, Fermin [Computer Simulation and Modeling (COSMO) Lab, Parc Cientific de Barcelona, Josep Samitier 5, 08028 Barcelona (Spain); Institut de Quimica Teorica i Computacional de la UB (IQTCUB), Universitat de Barcelona (Spain)], E-mail: fhuarte@pcb.ub.es
2008-07-03
Accurate full-dimensional quantum mechanical thermal rate constant values have been calculated for the F+H{sub 2}{yields}HF+H reaction on the Stark-Werner ab initio potential energy surface. These calculations are based on a flux correlation functions and employ a rigorous statistical sampling scheme to account for the overall rotation and the MCTDH scheme for the wave packet propagation. Our results shed some light on discrepancies on the thermal rate found for previous flux correlation based calculations with respect to accurate reactive scattering results. The resonance pattern of the all-J cumulative reaction probability is analyzed in terms of the partial wave contributions.
Alonso de Mezquia, David; Wang, Zilin; Lapeira, Estela; Klein, Michael; Wiegand, Simone; Mounir Bou-Ali, M
2014-11-01
In this study, the thermodiffusion, molecular diffusion, and Soret coefficients of 12 binary mixtures composed of toluene, n-hexane and n-dodecane in the whole range of concentrations at atmospheric pressure and temperatures of 298.15 K and 308.15 K have been determined. The experimental measurements have been carried out using the Thermogravitational Column, the Sliding Symmetric Tubes and the Thermal Diffusion Forced Rayleigh Scattering techniques. The results obtained using the different techniques show a maximum deviation of 9% for the thermodiffusion coefficient, 8% for the molecular diffusion coefficient and 2% for the Soret coefficient. For the first time we report a decrease of the thermodiffusion coefficient with increasing ratio of the thermal expansion coefficient and viscosity for a binary mixture of an organic ring compound with a short n-alkane. This observation is discussed in terms of interactions between the different components. Additionally, the thermogravitational technique has been used to measure the thermodiffusion coefficients of four ternary mixtures consisting of toluene, n-hexane and n-dodecane at 298.15 K. In order to complete the study, the values obtained for the molecular diffusion coefficient in binary mixtures, and the thermodiffusion coefficient of binary and ternary mixtures have been compared with recently derived correlations.
Energy Technology Data Exchange (ETDEWEB)
Won, Jong Hyuck; Cho, Nam Zin, E-mail: nzcho@kaist.ac.kr; Park, Hae Min; Jeong, Yong Hoon, E-mail: jeongyh@kaist.ac.kr
2014-12-15
Highlights: • The graphite rod-inserted SFR fuel assembly is proposed to achieve low sodium void reactivity. • The neutronics/thermal-hydraulics analyses are performed for the proposed SFR cores. • The sodium void reactivity is improved about 960–1030 pcm compared to reference design. - Abstract: The concept of a graphite-moderating rod-inserted sodium-cooled fast reactor (SFR) fuel assembly is proposed in this study to achieve a low sodium void reactivity coefficient. Using this concept, two types of SFR cores are analyzed; the proposed SFR type 1 core has new SFR fuel assemblies at the inner/mid core regions while the proposed SFR type 2 core has a B{sub 4}C absorber sandwich in the middle of the active core region as well as new SFR fuel assemblies at the inner/mid core regions. For the proposed SFR core designs, neutronics and thermal-hydraulic analyses are performed using the DIF3D, REBUS3, and the MATRA-LMR codes. In the neutronics analysis, the sodium void reactivity coefficient is obtained in various void situations. The two types of proposed core designs reduce the sodium void reactivity coefficient by about 960–1030 pcm compared to the reference design. However, the TRU enrichment for the proposed SFR core designs is increased. In the thermal hydraulic analysis, the temperature distributions are calculated for the two types of proposed core designs and the mass flow rate is optimized to satisfy the design constraints for the highest power generating assembly. The results of this study indicate that the proposed SFR assembly design concept, which adopts graphite-moderating rods which are inserted into the fuel assembly, can feasibly minimize the sodium void reactivity coefficient. Single TRU enrichment and an identical fuel slug diameter throughout the SFR core are also achieved because the radial power peak can be flattened by varying the number of moderating rods in each core region.
In2Mo3O12: A low negative thermal expansion compound
International Nuclear Information System (INIS)
Marinkovic, Bojan A.; Ari, Monica; Jardim, Paula Mendes; Avillez, Roberto R. de; Rizzo, Fernando; Ferreira, Fabio Furlan
2010-01-01
Orthorhombic In 2 Mo 3 O 12 has low negative linear coefficient of thermal expansion (α l = -1.85 x 10 -6 o C -1 ) as evaluated by X-ray powder diffraction using a synchrotron facility. The linear coefficient of thermal expansion for orthorhombic In 2 Mo 3 O 12 is directly dependent on the inherent volume distortion parameter (υ) of InO 6 . This finding strongly corroborates the recently proposed relationship between the linear coefficient of thermal expansion in A 2 M 3 O 12 compounds (α l ) and the distortion level of AO 6 polyhedra. With the increase of inherent distortion parameter (υ) of AO 6 polyhedra, the linear coefficient of thermal expansion becomes more negative. Another important feature of AO 6 polyhedra, including InO 6 , is that their distortion increases as a function of temperature. Orthorhombic In 2 Mo 3 O 12 is stable in the studied temperature range, 370-760 o C.
Drag coefficient Variability and Thermospheric models
Moe, Kenneth
Satellite drag coefficients depend upon a variety of factors: The shape of the satellite, its altitude, the eccentricity of its orbit, the temperature and mean molecular mass of the ambient atmosphere, and the time in the sunspot cycle. At altitudes where the mean free path of the atmospheric molecules is large compared to the dimensions of the satellite, the drag coefficients can be determined from the theory of free-molecule flow. The dependence on altitude is caused by the concentration of atomic oxygen which plays an important role by its ability to adsorb on the satellite surface and thereby affect the energy loss of molecules striking the surface. The eccentricity of the orbit determines the satellite velocity at perigee, and therefore the energy of the incident molecules relative to the energy of adsorption of atomic oxygen atoms on the surface. The temperature of the ambient atmosphere determines the extent to which the random thermal motion of the molecules influences the momentum transfer to the satellite. The time in the sunspot cycle affects the ambient temperature as well as the concentration of atomic oxygen at a particular altitude. Tables and graphs will be used to illustrate the variability of drag coefficients. Before there were any measurements of gas-surface interactions in orbit, Izakov and Cook independently made an excellent estimate that the drag coefficient of satellites of compact shape would be 2.2. That numerical value, independent of altitude, was used by Jacchia to construct his model from the early measurements of satellite drag. Consequently, there is an altitude dependent bias in the model. From the sparce orbital experiments that have been done, we know that the molecules which strike satellite surfaces rebound in a diffuse angular distribution with an energy loss given by the energy accommodation coefficient. As more evidence accumulates on the energy loss, more realistic drag coefficients are being calculated. These improved drag
Modeling of Thermal Barrier Coatings
Ferguson, B. L.; Petrus, G. J.; Krauss, T. M.
1992-01-01
The project examined the effectiveness of studying the creep behavior of thermal barrier coating system through the use of a general purpose, large strain finite element program, NIKE2D. Constitutive models implemented in this code were applied to simulate thermal-elastic and creep behavior. Four separate ceramic-bond coat interface geometries were examined in combination with a variety of constitutive models and material properties. The reason for focusing attention on the ceramic-bond coat interface is that prior studies have shown that cracking occurs in the ceramic near interface features which act as stress concentration points. The model conditions examined include: (1) two bond coat coefficient of thermal expansion curves; (2) the creep coefficient and creep exponent of the bond coat for steady state creep; (3) the interface geometry; and (4) the material model employed to represent the bond coat, ceramic, and superalloy base.
Thermal Expansion of Ni3Al Intermetallic Compound: Experiment and Simulation
International Nuclear Information System (INIS)
Wang Hai-Peng; Lü Peng; Zhou Kai; Wei Bing-Bo
2016-01-01
The thermal expansion of Ni 3 Al intermetallic compound is determined by a thermal dilatometer and simulated by the molecular dynamics method. The results of the linear thermal expansion coefficients are presented from 200 K up to the maximum temperature of 1600 K. The single phase of Ni 3 Al intermetallic compound is confirmed by x-ray diffraction together with DSC melting and solidification peaks, from which the solidus and the liquidus temperatures are obtained to be 1660 and 1695 K, respectively. The measured linear thermal expansion coefficient increases from 1.5 × 10 −5 to 2.7 × 10 −5 K −1 in the experimental temperature range, in good agreement with the data obtained by the molecular dynamics simulation, just a slight difference from the temperature dependence coefficient. Furthermore, the atomic structure and position are presented to reveal the atom distribution change during thermal expansion of Ni 3 Al compound. (paper)
Molecular evolution and thermal adaptation
Chen, Peiqiu
2011-12-01
In this thesis, we address problems in molecular evolution, thermal adaptation, and the kinetics of adaptation of bacteria and viruses to elevated environmental temperatures. We use a nearly neutral fitness model where the replication speed of an organism is proportional to the copy number of folded proteins. Our model reproduces the distribution of stabilities of natural proteins in excellent agreement with experiment. We find that species with high mutation rates tend to have less stable proteins compared to species with low mutation rate. We found that a broad distribution of protein stabilities observed in the model and in experiment is the key determinant of thermal response for viruses and bacteria. Our results explain most of the earlier experimental observations: striking asymmetry of thermal response curves, the absence of evolutionary trade-off which was expected but not found in experiments, correlation between denaturation temperature for several protein families and the Optimal Growth Temperature (OGT) of their carrier organisms, and proximity of bacterial or viral OGTs to their evolutionary temperatures. Our theory quantitatively and with high accuracy described thermal response curves for 35 bacterial species. The model also addresses the key to adaptation is in weak-link genes (WLG), which encode least thermodynamically stable essential proteins in the proteome. We observe, as in experiment, a two-stage adaptation process. The first stage is a Luria-Delbruck type of selection, whereby rare WLG alleles, whose proteins are more stable than WLG proteins of the majority of the population (either due to standing genetic variation or due to an early acquired mutation), rapidly rise to fixation. The second stage constitutes subsequent slow accumulation of mutations in an adapted population. As adaptation progresses, selection regime changes from positive to neutral: Selection coefficient of beneficial mutations scales as a negative power of number of
Helioseismic Solar Cycle Changes and Splitting Coefficients
Indian Academy of Sciences (India)
tribpo
Abstract. Using the GONG data for a period over four years, we have studied the variation of frequencies and splitting coefficients with solar cycle. Frequencies and even-order coefficients are found to change signi- ficantly with rising phase of the solar cycle. We also find temporal varia- tions in the rotation rate near the solar ...
Thermal relaxation of charm in hadronic matter
Energy Technology Data Exchange (ETDEWEB)
He Min, E-mail: mhe@comp.tamu.edu [Cyclotron Institute and Department of Physics and Astronomy, Texas A and M University, College Station, TX 77843 (United States); Fries, Rainer J. [Cyclotron Institute and Department of Physics and Astronomy, Texas A and M University, College Station, TX 77843 (United States); RIKEN/BNL Research Center, Brookhaven National Laboratory, Upton, NY 11973 (United States); Rapp, Ralf [Cyclotron Institute and Department of Physics and Astronomy, Texas A and M University, College Station, TX 77843 (United States)
2011-07-18
The thermal relaxation rate of open-charm (D) mesons in hot and dense hadronic matter is calculated using empirical elastic scattering amplitudes. D-meson interactions with thermal pions are approximated by D{sup *} resonances, while scattering off other hadrons (K, {eta}, {rho}, {omega}, K{sup *}, N, {Delta}) is evaluated using vacuum scattering amplitudes as available in the literature based on effective Lagrangians and constrained by realistic spectroscopy. The thermal relaxation time of D-mesons in a hot {pi} gas is found to be around 25-50 fm/c for temperatures T=150-180 MeV, which reduces to 10-25 fm/c in a hadron-resonance gas. The latter values, argued to be conservative estimates, imply significant modifications of D-meson spectra in heavy-ion collisions. Close to the critical temperature (T{sub c}), the spatial diffusion coefficient (D{sub s}) is surprisingly similar to recent calculations for charm quarks in the Quark-Gluon Plasma using non-perturbative T-matrix interactions. This suggests a possibly continuous minimum structure of D{sub s} around T{sub c}.
Jairo A. Diaz; Julia L. Braun; Robert J. Moon; Jeffrey P. Youngblood
2015-01-01
Simultaneous control over optical and thermal properties is particularly challenging and highly desired in fields like organic electronics. Here we incorporated cellulose nanocrystals (CNCs) into polyethylene oxide (PEO) in an attempt to preserve the iridescent CNC optical reflection given by their chiral nematic organisation, while reducing the composite thermal...
Ion exchange synthesis and thermal characteristics of some [N
Indian Academy of Sciences (India)
These ionic liquids (ILs) were characterized using thermal methods, infrared spectroscopy and densitometry. Thermophysical properties such as density, coefficient of volume expansion, heat of fusion, heat capacity and thermal energy storage capacity were determined. Thermal conductivity of the samples was determined ...
Thermally driven convective cells and tokamak edge turbulence
International Nuclear Information System (INIS)
Thayer, D.R.; Diamond, P.H.
1987-07-01
A unified theory for the dynamics of thermally driven convective cell turbulence is presented. The cells are excited by the combined effects of radiative cooling and resistivity gradient drive. The model also includes impurity dynamics. Parallel thermal and impurity flows enhanced by turbulent radial duffusion regulate and saturate overlapping cells, even in regimes dominated by thermal instability. Transport coefficients and fluctuation levels characteristic of the saturated turbulence are calculated. It is found that the impurity radiation increases transport coefficients for high density plasmas, while the parallel conduction damping, elevated by radial diffusion, in turn quenches the thermal instability. The enhancement due to radiative cooling provides a resolution to the dilemma of explaining the experimental observation that potential fluctuations exceed density fluctuations in the edge plasma (e PHI/T/sub e/ > n/n 0 )
Determination of the fission coefficients in thermal nuclear reactors for antineutrino detection
Energy Technology Data Exchange (ETDEWEB)
Araujo, Lenilson M. [Coordenacao dos Programas de Pos-Graduacao de Engenharia (PEN/COPPE/UFRJ), Rio de Janeiro, RJ (Brazil). Programa de Engenharia Nuclear; Cabral, Ronaldo G., E-mail: rgcabral@ime.eb.b [Instituto Militar de Engenharia (IME), Rio de Janeiro, RJ (Brazil); Anjos, Joao C.C. dos, E-mail: janjos@cbpf.b [Centro Brasileiro de Pesquisas Fisicas (CBPF), Rio de Janeiro, RJ (Brazil). Dept. GLN - G
2011-07-01
The nuclear reactors in operation periodically need to change their fuel. It is during this process that these reactors are more vulnerable to occurring of several situations of fuel diversion, thus the monitoring of the nuclear installations is indispensable to avoid events of this nature. Considering this fact, the most promissory technique to be used for the nuclear safeguard for the nonproliferation of nuclear weapons, it is based on the detection and spectroscopy of antineutrino from fissions that occur in the nuclear reactors. The detection and spectroscopy of antineutrino, they both depend on the single contribution for the total number of fission of each actinide in the core reactor, these contributions receive the name of fission coefficients. The goal of this research is to show the computational and mathematical modeling used to determinate these coefficients for PWR reactors. (author)
Effect of gamma irradiation on density and thermal expansion changes of uniaxial oriented LLDPE
International Nuclear Information System (INIS)
Kacarevic-Popovic, Z.; Kostoski, D.; Novakovic, Lj.
1998-01-01
Complete text of publication follows. It is well known that gamma irradiation induces cross-linking in the amorphous phase of isotropic polyethylene, or chain scission in highly oriented fibers and films. Thermomechanical behavior and values of density are the reflection of the changes induced by gamma irradiation. Namely, scission of macromolecules, in general, increases thermal expansion coefficient and decreases density and vice versa. On the other hand, as it is well known, the thermal expansion behavior of oriented polymers shows marked anisotropy. It was found that many highly oriented polymers show a negative coefficient of thermal expansion in the draw direction and a positive coefficient in the transverse direction. It has been suggested that, apart from any intrinsic crystalline contribution, a significant part of the negative thermal expansion coefficients obtained for highly oriented polymers arises from the effect of entropy internal stresses in the amorphous regions. From our previous work, the thermal coefficients in draw direction of irradiated samples rise in the glass transition temperature range and it was related to the effects of cross-linking in the amorphous phase of LDPE. In our present work we observed initial decrease in density with absorbed dose, up to 35 kGy, and subsequent increase up to a dose of 500 kGy. The observed increase in thermal expansion coefficient followed the changes in density and is related to the parallel processes of chain scission and net cross-linking in the amorphous phase of LLDPE, induced by gamma irradiation
Studies on Enhancing Transverse Thermal Conductivity Carbon/Carbon Composites
National Research Council Canada - National Science Library
Manocha, Lalit M; Manocha, Satish M; Roy, Ajit
2007-01-01
The structure derived potential properties of Graphite such as high stiffness coupled with high thermal conductivity and low coefficient of thermal expansion have been better achieved in Carbon fibers...
Time evolution of tunneling in a thermal medium: Environment-driven excited tunneling
International Nuclear Information System (INIS)
Matsumoto, Sh.; Yoshimura, M.
2004-01-01
Time evolution of tunneling phenomena proceeding in a thermal medium is studied using a standard model of environmental interaction. A semiclassical probability formula for the particle motion in a metastable state of a one-dimensional system put in a thermal medium is combined with the formula of the quantum penetration factor through a potential barrier to derive the tunneling rate in the medium. The effect of environment, its influence on time evolution in particular, is clarified in our real-time formalism. A nonlinear resonance effect is shown to enhance the tunneling rate at finite times of order 2/η, with η the friction coefficient unless η is too small. In the linear approximation this effect has relevance to the parametric resonance. This effect enhances the possibility of early termination of the cosmological phase transition much prior to the typical Hubble time
Parametric study on thermal-hydraulic response following as ATWS event
International Nuclear Information System (INIS)
Suh, Jeong Kwan; Bang, Young Seok; Kim, Hho Jung
2000-01-01
A series of sensitivity calculations for the LOFT L9-3 experiment were performed using RELAP5/MOD3 code to assess parametric effects on thermal-hydraulic response in the event of Anticipated Transient Without Scram (ATWS). The base case calculation was made by the condition which gave a good agreement for the pressure of the reactor coolant system (RCS) with the experimental data. Four parameters of PORV/spray energy loss coefficient, steam generator nodalization and moderator density coefficient (MDC) were selected during the input preparation and investigated by calculating the total discharged energy through relief valves. The energy loss coefficient of the pressurizer spray valve has a significant effect on the behavior of the RCS pressure and the change of the MDC curve within 15 % at the negative region decreased the difference of the coolant temperature between the experiment and the calculation within a range of measurement uncertainty. The finer steam generator nodalization increased the primary to secondary heat transfer rate
Thermal expansion and its impacts on thermal transport in the FPU-α-β model
Directory of Open Access Journals (Sweden)
Xiaodong Cao
2015-05-01
Full Text Available We study the impacts of thermal expansion, arising from the asymmetric interparticle potential, on thermal conductance in the FPU-α-β model. A nonmonotonic dependence of the temperature gradient and thermal conductance on the cubic interaction parameter α are shown, which corresponds to the variation of the coefficient of thermal expansion. Three domains with respect to α can be identified. The results are explained based on the detailed analysis of the asymmetry of the interparticle potential. The self-consistent phonon theory, which can capture the effect of thermal expansion, is developed to support our explanation in a quantitative way. Our result would be helpful to understand the issue that whether there exist normal thermal conduction in the FPU-α-β model.
International Nuclear Information System (INIS)
Shin, So Min; Lee, Ki Seon; Park, Seoung Duck; Kwak, Jae Su
2009-01-01
Heat transfer coefficients were measured in a channel with one side dimpled surface. The sphere type dimples were fabricated, and the diameter (D) and the depth of dimple was 16 mm and 4 mm, respectively. Two channel heights of about 0.6D and 1.2D, two dimple configurations were tested. The Reynolds number based on the channel hydraulic diameter was varied from 30000 to 50000. The improved hue detection based transient liquid crystal technique was used in the heat transfer measurement. Heat transfer measurement results showed that high heat transfer was induced downstream of the dimples due to flow reattachment. Due to the flow recirculation on the upstream side in the dimple, the heat transfer coefficient was very low. As the Reynolds increased, the overall heat transfer coefficients also increased. With the same dimple arrangement, the heat transfer coefficients and the thermal performance factors were higher for the lower channel height. As the distance between the dimples became smaller, the overall heat transfer coefficient and the thermal performance factors increased
Measurement of molecular diffusion coefficients of carbon dioxide and methane in heavy oil
Energy Technology Data Exchange (ETDEWEB)
Gu, Y.; Tharanivasan, A.K.; Yang, C. [Regina Univ., SK (Canada)
2004-07-01
Vapour extraction (VAPEX) is a solvent-based thermal recovery process which is considered to be a viable process for recovering heavy oil. In order to develop a solvent-based enhanced oil recovery (EOR) operation, it is necessary to know the rate and extent of oil mobilization by the solvent. The molecular diffusion coefficient of solvent gas in heavy oil must be known. In this study, the pressure decay method was used to measure the molecular diffusivity of a gas solvent in heavy oil by monitoring the decaying pressure. The pressure decay method is a non-intrusive method in which physical contact is made between the gas solvent and the heavy oil. The pressure versus time data are measured until the heavy oil reaches complete saturation. The diffusion coefficient can be determined from the measured data and a mathematical model. In this study, the molecular diffusion coefficients of carbon dioxide-heavy oil and methane-heavy oil systems were measured and compared. The experiments were performed in closed high-pressure cells at constant reservoir temperature. An analytical solution was also obtained to predict the pressure in the gas phase and for the boundary conditions at the solvent-heavy oil interface for each solvent. Solvent diffusivity was determined by finding the best match of the numerically predicted and experimentally measured pressures.
Experimental observation of thermal-hydraulic behavior in PCCS horizontal heat exchanger
International Nuclear Information System (INIS)
Kondo, Masaya; Nakamura, Hideo; Yamamoto, Kazuhiko; Shimada, Rumi; Tokuma, Hideaki
2003-01-01
A series of thermal-hydraulic experiments have been performed using a prototypical-scale experimental facility simulating a horizontal heat exchanger of a Passive Containment Cooling System (PCCS) for next generation BWRs. The influences of multi-dimensional boiling flow in secondary water pool on primary flow in parallel tubes are investigated. The experimental results at postulated accident conditions; 0.7 MPa, steam flow rate equivalent to 1% core power with 1% non-condensable gas, show that steam condensation completes in almost the same heat transfer length in all the instrumented tubes. The secondary heat transfer coefficient is relatively small at the lower portion in the tube bundle when the flow regime is bubbly flow, and increases with elevation as the flow regime turns into churn-like flow. The primary steam flow distribution among tubes is rather insensitive to such a variation in the secondary heat transfer coefficient, since the contribution of the secondary heat transfer to the local heat resistance is 30% or less at postulated accident conditions. The influence of steam flow rate is insensitive too, while the contribution of the secondary heat transfer coefficient increases at low pressure conditions. (author)
International Nuclear Information System (INIS)
Hall, G.; Marsden, B.J.; Fok, S.L.; Smart, J.
2003-01-01
In the 1960s, a theoretical relationship between the dimensional changes and the coefficient of thermal expansion of irradiated graphite was derived by J.H.W. Simmons. The theory was shown to be comparable with experimental observations at low irradiation doses, but shown to diverge at higher irradiation doses. However, various modified versions of this theory have been used as the foundation of design and life prediction calculations for graphite-moderated reactors. This paper re-examines the Simmons relationship, summarising its derivation and assumptions. The relationship was then modified to incorporate the high dose, high strain changes that were assumed to be represented in the changes in Young's modulus with irradiation dose. By scrutinising the behaviour of finite element analyses, it was possible to use a modified Simmons relationship to predict the dimensional changes of an isotropic and anisotropic graphite to high irradiation doses. These issues are important to present high-temperature reactors (HTRs) as the life of HTR graphite components is dependent upon their dimensional change behaviour. A greater understanding of this behaviour will help in the selection and development of graphite materials
International Nuclear Information System (INIS)
Scotta, J.P.; Noguere, G.; Bernard, D.; Santamarina, A.; Damian, J.I.M.
2016-01-01
The contribution of the thermal scattering law of hydrogen in light water to isothermal temperature reactivity coefficients for UOX and MOX lattices was studied in the frame of the MISTRAL critical experiments carried out in the zero power reactor EOLE of CEA Cadarache (France). The interpretation of the core residual reactivity measured between 6 to 80 C. degrees (by step of 5 C. degrees) was performed with the Monte-Carlo code TRIPOLI-4"R. The nuclear data from the JEFF-3.1.1 library were used in the calculations. 3 different thermal scattering laws of hydrogen in light water were tested in order to evaluate their impact on the MISTRAL calculations. The thermal scattering laws of interest were firstly those recommended in JEFF-3.1.1 and ENDF/BVII.1 and also that recently produced at the atomic center of Bariloche (CAB, Argentina) with molecular dynamic simulations. The present work indicates that the calculation-to-experimental bias is (0.4 ± 0.3) pcm/C. degree in the UOX core and (1.0 ± 0.3) pcm/C. degree in the MOX cores, when the JEFF-3.1.1 library is used. An improvement is observed over the whole temperature range with the CAB model. The calculation-to-experimental bias vanishes for the UOX core (0.02 pcm/C. degree) and becomes close to 0.7 pcm/C. degree for the MOX cores. The magnitude of these bias have to be connected to the typical value of the temperature reactivity coefficient that ranges from 5 pcm/C. degree at Beginning Of Cycle (BOC) up to 50 pcm/C. degrees at End Of Cycle (EOC), in PWR conditions. (authors)
Sun, Zhixing; Shen, Zhigang; Ma, Shulin; Zhang, Xiaojing
2013-10-01
The aim of this study is to investigate the feasibility of using glass fibers, a recycled material from waste printed circuit boards (WPCB), as sound absorption and thermal insulation material. Glass fibers were obtained through a fluidized-bed recycling process. Acoustic properties of the recovered glass fibers (RGF) were measured and compared with some commercial sound absorbing materials, such as expanded perlite (EP), expanded vermiculite (EV), and commercial glass fiber. Results show that RGF have good sound absorption ability over the whole tested frequency range (100-6400 Hz). The average sound absorption coefficient of RGF is 0.86, which is prior to those of EP (0.81) and EV (0.73). Noise reduction coefficient analysis indicates that the absorption ability of RGF can meet the requirement of II rating for sound absorbing material according to national standard. The thermal insulation results show that RGF has a fair low thermal conductivity (0.046 W/m K), which is comparable to those of some insulation materials (i.e., EV, EP, and rock wool). Besides, an empirical dependence of thermal conductivity on material temperature was determined for RGF. All the results showed that the reuse of RGF for sound and thermal insulation material provided a promising way for recycling WPCB and obtaining high beneficial products.
Determination of the Rate Coefficients of the SO2 plus O plus M yields SO3 plus M Reaction
Hwang, S. M.; Cooke, J. A.; De Witt, K. J.; Rabinowitz, M. J.
2010-01-01
Rate coefficients of the title reaction R(sub 31) (SO2 +O+M yields SO3 +M) and R(sub 56) (SO2 + HO2 yields SO3 +OH), important in the conversion of S(IV) to S(VI),were obtained at T =970-1150 K and rho (sub ave) = 16.2 micro mol/cubic cm behind reflected shock waves by a perturbation method. Shock-heated H2/ O2/Ar mixtures were perturbed by adding small amounts of SO2 (1%, 2%, and 3%) and the OH temporal profiles were then measured using laser absorption spectroscopy. Reaction rate coefficients were elucidated by matching the characteristic reaction times acquired from the individual experimental absorption profiles via simultaneous optimization of k(sub 31) and k(sub 56) values in the reaction modeling (for satisfactory matches to the observed characteristic times, it was necessary to take into account R(sub 56)). In the experimental conditions of this study, R(sub 31) is in the low-pressure limit. The rate coefficient expressions fitted using the combined data of this study and the previous experimental results are k(sub 31,0)/[Ar] = 2.9 10(exp 35) T(exp ?6.0) exp(?4780 K/T ) + 6.1 10(exp 24) T(exp ?3.0) exp(?1980 K/T ) cm(sup 6) mol(exp ?2)/ s at T = 300-2500 K; k(sub 56) = 1.36 10(exp 11) exp(?3420 K/T ) cm(exp 3)/mol/s at T = 970-1150 K. Computer simulations of typical aircraft engine environments, using the reaction mechanism with the above k(sub 31,0) and k(sub 56) expressions, gave the maximum S(IV) to S(VI) conversion yield of ca. 3.5% and 2.5% for the constant density and constant pressure flow condition, respectively. Moreover, maximum conversions occur at rather higher temperatures (?1200 K) than that where the maximum k(sub 31,0) value is located (approximately 800 K). This is because the conversion yield is dependent upon not only the k(sup 31,0) and k(sup 56) values (production flux) but also the availability of H, O, and HO2 in the system (consumption flux).
Structure and thermal expansion of NbC complex carbides
International Nuclear Information System (INIS)
Khatsinskaya, I.M.; Chaporova, I.N.; Cheburaeva, R.F.; Samojlov, A.I.; Logunov, A.V.; Ignatova, I.A.; Dodonova, L.P.
1983-01-01
Alloying dependences of the crystal lattice parameters at indoor temperature and coefficient of thermal linear exspansion within a 373-1273 K range are determined for complex NbC-base carbides by the method of mathematical expemental design. It is shown that temperature changes in the linear expansion coefficient of certain complex carbides as distinct from NbC have an anomaly (minimum) within 773-973 K caused by occurring reversible phase transformations. An increase in the coefficient of thermal linear expansion and a decrease in hardness of NbC-base tungsten-, molybdenum-, vanadium- and hafnium-alloyed carbides show a weakening of a total chemical bond in the complex carbides during alloying
Directory of Open Access Journals (Sweden)
Stella Crosara Lopes
2009-04-01
Full Text Available The purpose of this study was to evaluate the metal-ceramic bond strength (MCBS of 6 metal-ceramic pairs (2 Ni-Cr alloys and 1 Pd-Ag alloy with 2 dental ceramics and correlate the MCBS values with the differences between the coefficients of linear thermal expansion (CTEs of the metals and ceramics. Verabond (VB Ni-Cr-Be alloy, Verabond II (VB2, Ni-Cr alloy, Pors-on 4 (P, Pd-Ag alloy, and IPS (I and Duceram (D ceramics were used for the MCBS test and dilatometric test. Forty-eight ceramic rings were built around metallic rods (3.0 mm in diameter and 70.0 mm in length made from the evaluated alloys. The rods were subsequently embedded in gypsum cast in order to perform a tensile load test, which enabled calculating the CMBS. Five specimens (2.0 mm in diameter and 12.0 mm in length of each material were made for the dilatometric test. The chromel-alumel thermocouple required for the test was welded into the metal test specimens and inserted into the ceramics. ANOVA and Tukey's test revealed significant differences (p=0.01 for the MCBS test results (MPa, with PI showing higher MCBS (67.72 than the other pairs, which did not present any significant differences. The CTE (10-6 oC-1 differences were: VBI (0.54, VBD (1.33, VB2I (-0.14, VB2D (0.63, PI (1.84 and PD (2.62. Pearson's correlation test (r=0.17 was performed to evaluate of correlation between MCBS and CTE differences. Within the limitations of this study and based on the obtained results, there was no correlation between MCBS and CTE differences for the evaluated metal-ceramic pairs.
Lopes, Stella Crosara; Pagnano, Valéria Oliveira; Rollo, João Manuel Domingos de Almeida; Leal, Mônica Barbosa; Bezzon, Osvaldo Luiz
2009-01-01
The purpose of this study was to evaluate the metal-ceramic bond strength (MCBS) of 6 metal-ceramic pairs (2 Ni-Cr alloys and 1 Pd-Ag alloy with 2 dental ceramics) and correlate the MCBS values with the differences between the coefficients of linear thermal expansion (CTEs) of the metals and ceramics. Verabond (VB) Ni-Cr-Be alloy, Verabond II (VB2), Ni-Cr alloy, Pors-on 4 (P), Pd-Ag alloy, and IPS (I) and Duceram (D) ceramics were used for the MCBS test and dilatometric test. Forty-eight ceramic rings were built around metallic rods (3.0 mm in diameter and 70.0 mm in length) made from the evaluated alloys. The rods were subsequently embedded in gypsum cast in order to perform a tensile load test, which enabled calculating the CMBS. Five specimens (2.0 mm in diameter and 12.0 mm in length) of each material were made for the dilatometric test. The chromel-alumel thermocouple required for the test was welded into the metal test specimens and inserted into the ceramics. ANOVA and Tukey's test revealed significant differences (p=0.01) for the MCBS test results (MPa), with PI showing higher MCBS (67.72) than the other pairs, which did not present any significant differences. The CTE (10(-6) oC(-1)) differences were: VBI (0.54), VBD (1.33), VB2I (-0.14), VB2D (0.63), PI (1.84) and PD (2.62). Pearson's correlation test (r=0.17) was performed to evaluate of correlation between MCBS and CTE differences. Within the limitations of this study and based on the obtained results, there was no correlation between MCBS and CTE differences for the evaluated metal-ceramic pairs.
A variable thickness window: Thermal and structural analyses
International Nuclear Information System (INIS)
Wang, Zhibi; Kuzay, T.M.
1994-01-01
In this paper, the finite difference formulations for variable thickness thermal analysis and variable thickness plane stress analysis are presented. In heat transfer analysis, radiation effects and temperature-dependent thermal conductivity are taken into account. While in thermal stress analysis, the thermal expansion coefficient is considered as temperature dependent. An application of the variable thickness window to an Advanced Photon Source beamline is presented
Transverse thermal magnetoresistance of potassium
International Nuclear Information System (INIS)
Newrock, R.S.; Maxfield, B.W.
1976-01-01
Results are presented of extensive thermal magnetoresistance measurements on single-crystal and polycrystalline specimens of potassium having residual resistance ratios (RRR) ranging from 1100 to 5300. Measurements were made between 2 and 9 0 K for magnetic fields up to 1.8 T. The observed thermal magnetoresistance cannot be understood on the basis of either semiclassical theories or from the electrical magnetoresistance and the Wiedemann-Franz law. A number of relationships are observed between the thermal and electrical magnetoresistances, many of which are not immediately obvious when comparing direct experimental observations. The thermal magnetoresistance W(T,H) is given reasonably well by W(T,H)T = W(T,0)T + AH + BH 2 , where both A and B are temperature-dependent coefficients. Results show that A = A 0 + A 1 T 3 , while B(T) cannot be expressed as any simple power law. A 0 is dependent on the RRR, while A 1 is independent of the RRR. Two relationships are found between corresponding coefficients in the electrical and thermal magnetoresistance: (i) the Wiedmann--Franz law relates A 0 to the Kohler slope of the electrical magnetoresistance and (ii) the temperature-dependent portions of the electrical and thermal Kohler slopes are both proportional to the electron--phonon scattering contribution to the corresponding zero-field resistance. The latter provides evidence that inelastic scattering is very important in determining the temperature-dependent linear magnetoresistances. Part, but by no means all, of the quadratic thermal resistance is accounted for by lattice thermal conduction. It is concluded that at least a portion of the anomalous electrical and thermal magnetoresistances is due to intrinsic causes and not inhomogeneities or other macroscopic defects
International Nuclear Information System (INIS)
Imre, K.; Odian, G.
1979-01-01
The effect of diffusion on radiation-initiated graft polymerization has been studied with emphasis on the single- and two-penetrant cases. When the physical properties of the penetrants are similar, the two-penetrant problems can be reduced to the single-penetrant problem by redefining the characteristic parameters of the system. The diffusion-free graft polymerization rate is assumed to be proportional to the upsilon power of the monomer concentration respectively, and, in which the proportionality constant a = k/sub p/R/sub i//sup w//k/sub t//sup z/, where k/sub p/ and k/sub t/ are the propagation and termination rate constants, respectively, and R/sub i/ is the initiation rate. The values of upsilon, w, and z depend on the particular reaction system. The results of earlier work were generalized by allowing a non-Fickian diffusion rate which predicts an essentially exponential dependence on the monomer concentration of the diffusion coefficient, D = D 0 [exp(deltaC/M)], where M is the saturation concentration. A reaction system is characterized by the three dimensionless parameters, upsilon, delta, and A = (L/2)[aM/sup (upsilon--1)//D 0 ]/sup 1/2/, where L is the polymer film thickness. Graft polymerization tends to become diffusion controlled as A increases. Larger values of delta and ν cause a reaction system to behave closer to the diffusion-free regime. Transition from diffusion-free to diffusion-controlled reaction involves changes in the dependence of the reaction rate on film thickness, initiation rate, and monomer concentration. Although the diffusion-free rate is w order in initiation rate, upsilon order in monomer, and independent of film thickness, the diffusion-controlled rate is w/2 order in initiator rate and inverse first-order in film thickness. Dependence of the diffusion-controlled rate on monomer is dependent in a complex manner on the diffusional characteristics of the reaction system. 11 figures, 4 tables
High-power electronics thermal management with intermittent multijet sprays
International Nuclear Information System (INIS)
Panão, Miguel R.O.; Correia, André M.; Moreira, António L.N.
2012-01-01
Thermal management plays a crucial role in the development of high-power electronics devices, e.g. in electric vehicles. The greatest energy demands occur during power peaks, implying dynamic thermal losses within the vehicle’s driving cycle. Therefore, the need for devising intelligent thermal management systems able to efficiently respond to these power peaks has become a technological challenge. Experiments have been performed with methanol in order to quantify the maximum heat flux removed by a multijet spray to keep the 4 cm 2 surface temperature stabilized and below the threshold of 125 °C. A multijet atomization strategy consists in producing a spray through the multiple and simultaneous impact of N j cylindrical jets. Moreover, the spray intermittency is expressed through the duty cycle (DC), which depends on the frequency and duration of injection. Results evidence that: i) a shorter time between consecutive injection cycles enables a better distribution of the mass flow rate, resulting in larger heat transfer coefficient values, as well as higher cooling efficiencies; ii) compared with continuous sprays, the analysis evidences that an intermittent spray allows benefiting more from phase-change convection. Moreover, the mass flux is mainly affecting heat transfer rather than differences induced in the spray structure by using different multijet configurations. - Highlights: ► Intermittent spray cooling (ISC) is advantageous for intelligent thermal management. ► Distributing the mass flow rate through ISC improves heat transfer. ► Multijet sprays with increasing number of jets have higher heat transfer rates. ► ISC with multijet sprays benefit more from phase-change than continuous sprays.
Determination of sedimentation rates and absorption coefficient of ...
African Journals Online (AJOL)
2+ has a higher sedimentation rate of 5.10x10-2 s-1 while Ni2+ has the lowest sedimentation rates of 1.10 x10-3. The rate of sedimentation of the metal carbonates decreased in the order: Zn2+ > Cd2+ > Cu2+ > Co2+ > Ni2+. The order ...
Thermal Properties and Thermal Analysis:
Kasap, Safa; Tonchev, Dan
The chapter provides a summary of the fundamental concepts that are needed to understand the heat capacity C P, thermal conductivity κ, and thermal expansion coefficient α L of materials. The C P, κ, and α of various classes of materials, namely, semiconductors, polymers, and glasses, are reviewed, and various typical characteristics are summarized. A key concept in crystalline solids is the Debye theory of the heat capacity, which has been widely used for many decades for calculating the C P of crystals. The thermal properties are interrelated through Grüneisen's theorem. Various useful empirical rules for calculating C P and κ have been used, some of which are summarized. Conventional differential scanning calorimetry (DSC) is a powerful and convenient thermal analysis technique that allows various important physical and chemical transformations, such as the glass transition, crystallization, oxidation, melting etc. to be studied. DSC can also be used to obtain information on the kinetics of the transformations, and some of these thermal analysis techniques are summarized. Temperature-modulated DSC, TMDSC, is a relatively recent innovation in which the sample temperature is ramped slowly and, at the same time, sinusoidally modulated. TMDSC has a number of distinct advantages compared with the conventional DSC since it measures the complex heat capacity. For example, the glass-transition temperature T g measured by TMDSC has almost no dependence on the thermal history, and corresponds to an almost step life change in C P. The new Tzero DSC has an additional thermocouple to calibrate better for thermal lags inherent in the DSC measurement, and allows more accurate thermal analysis.
Tajima, Satomi; Hayashi, Toshio; Hori, Masaru
2015-02-26
The rate coefficient of F2 + NO → F + FNO is 2 to 5 orders of magnitude higher than that of F2 + NO2 → F + FNO2 even though bond energies of FNO and FNO2 only differ by ∼0.2 eV. To understand the cause of having different rate coefficients of these two reactions, the change in total energies was calculated by varying the stereochemical arrangement of F2 with respect to NOx (x = 1 or 2) by the density functional theory (DFT), using CAM-B3LYP/6-311 G+(d) in the Gaussian program. The permitted approaching angle between the x-axis and the plane consisting of O, N, F, and ϕ plays a key role to restrict the reaction of NO2 and F2 compared to the reaction of NO and F2. This restriction in the reaction space is considered to be the main cause of different rate coefficients depending on the selection of x = 1 or 2 of the reaction of F2 + NOx → F + FNOx, which was also confirmed by the difference in Si etch rate using the F formed by those reactions.
Effect of Cattaneo-Christov heat flux on Jeffrey fluid flow with variable thermal conductivity
Hayat, Tasawar; Javed, Mehwish; Imtiaz, Maria; Alsaedi, Ahmed
2018-03-01
This paper presents the study of Jeffrey fluid flow by a rotating disk with variable thickness. Energy equation is constructed by using Cattaneo-Christov heat flux model with variable thermal conductivity. A system of equations governing the model is obtained by applying boundary layer approximation. Resulting nonlinear partial differential system is transformed to ordinary differential system. Homotopy concept leads to the convergent solutions development. Graphical analysis for velocities and temperature is made to examine the influence of different involved parameters. Thermal relaxation time parameter signifies that temperature for Fourier's heat law is more than Cattaneo-Christov heat flux. A constitutional analysis is made for skin friction coefficient and heat transfer rate. Effects of Prandtl number on temperature distribution and heat transfer rate are scrutinized. It is observed that larger Reynolds number gives illustrious temperature distribution.
Load rate dependence of the mechanical properties of thermal barrier coating systems
Energy Technology Data Exchange (ETDEWEB)
Zotov, Nikolay; Eggeler, Gunther [Institut fuer Werkstoffe, Ruhr Universitaet Bochum, 44780 Bochum (Germany); Bartsch, Marion [Institut fuer Werkstoff-Forschung, DLR Koeln, 51147 Koeln (Germany)
2009-07-01
Thermal barrier coatings (TBC), composed of yttrium-stabilized zirconia (YSZ) ceramic top coat (TC) and intermetallic NiCoCrAlY bond coat (BC) are commonly used as protective coatings of Ni-based high temperature gas engine components. Nanoindentation techniques are increasingly applied for determining the TBC mechanical properties on a nanometre scale. However, little is known about the load-rate dependence of the mechanical properties, which is important for better understanding of cyclic thermal fatigue experiments. Nanoindentations with different load rates omega were performed on polished cross-sections of TBC, deposited by EB-PVD on IN625 substrates (S), using a XP Nanoindenter (MTS) equipped with Berkovich diamond tip. The Young's modulus (E) of the TC is independent of omega, while E for the BC and the S decreases with omega. The hardness (H) of the TC and the BC increases, while H for the S decreases with omega. From the dependence of H on omega, creep power-law exponents c = 0.24(11) and c = 0.023(6) for the TC and the BC were determined. For all TBC components, a decrease with omega of the power-law exponents n and m, describing the loading and unloading nanoindentation curves, is observed.
The thermal expansion of austenitic manganese and manganese-chromium steels
International Nuclear Information System (INIS)
Richter, F.
1977-01-01
The linear coefficient of thermal expansion was determined by dilatometer for 5 Mn steels and 6 Mn-Cr steels between -196 and +500 0 C. Because of the antiferromagnetic properties, the thermal expansion of austenitic Mn and Mn-Cr steels is determined by the position of the magnetic changeover temperature (Neel temperature), which depends on the chemical composition of the steel. Below the Neel temperature, the thermal coefficient of expansion is greatly reduced by volumetric magnetostriction (Invar effect). For this reason, one can only give approximate values for thermal expansion for all Mn and Mn-Cr steels in the temperature range of -100 0 C to about +100 0 C. (GSC) [de
A thermal engine for underwater glider driven by ocean thermal energy
International Nuclear Information System (INIS)
Yang, Yanan; Wang, Yanhui; Ma, Zhesong; Wang, Shuxin
2016-01-01
Highlights: • Thermal engine with a double-tube structure is developed for underwater glider. • Isostatic pressing technology is effective to increase volumetric change rate. • Actual volumetric change rate reaches 89.2% of the theoretical value. • Long term sailing of 677 km and 27 days is achieved by thermal underwater glider. - Graphical Abstract: - Abstract: Underwater glider is one of the most popular platforms for long term ocean observation. Underwater glider driven by ocean thermal energy extends the duration and range of underwater glider powered by battery. Thermal engine is the core device of underwater glider to harvest ocean thermal energy. In this paper, (1) model of thermal engine was raised by thermodynamics method and the performance of thermal engine was investigated, (2) thermal engine with a double-tube structure was developed and isostatic pressing technology was applied to improve the performance for buoyancy driven, referencing powder pressing theory, (3) wall thickness of thermal engine was optimized to reduce the overall weight of thermal engine, (4) material selection and dimension determination were discussed for a faster heat transfer design, by thermal resistance analysis, (5) laboratory test and long term sea trail were carried out to test the performance of thermal engine. The study shows that volumetric change rate is the most important indicator to evaluating buoyancy-driven performance of a thermal engine, isostatic pressing technology is effective to improve volumetric change rate, actual volumetric change rate can reach 89.2% of the theoretical value and the average power is about 124 W in a typical diving profile. Thermal engine developed by Tianjin University is a superior thermal energy conversion device for underwater glider. Additionally, application of thermal engine provides a new solution for miniaturization of ocean thermal energy conversion.
Measured thermal and fast neutron fluence rates ATR Cycle 99-A, November 23, 1992--January 23, 1993
International Nuclear Information System (INIS)
Murray, R.K.; Rogers, J.W.
1993-03-01
This report contains the thermal (2200 m/s) and fast (E>me) neutron fluence rate data for ATR Cycle 99-A which were measured by the Radiation Measurements Laboratory (RML) as requested by the Power ReactorPrograms (ATR Experiments) Radiation Measurements Work Order. This report contains fluence rate values corresponding to the particular elevations (relative to the 80 ft. core elevation) where the measurements were taken. The data in this report consists of (1) a table of the ATR power history and distribution, (2) a hard copy listing of all thermal and fast neutron fluence rates, (3) plots of both the thermal and fast neutron fluence rates, and (4) a magnetic record (3.5 inch diskette) containing a listing of only the fast neutron fluence rates, their assigned elevations and proper header identification of all monitor positions contained herein. The fluence rates reported are for the average power levels given in the table of power history and distribution. All ''H'' holder monitor wires for this cycle are 54 inches long. All ''SR'' holder monitor wires for this cycle are 55 inches long. This length allows measurement of the full core region and makes the first count elevation 24.73 inches above core midplane. Due to the safety rod problems in the west lobe, ''BR'' holders were used in the W-1, 2, 3, and 4 positions. All ''BR'' holder monitor wires for this cycle are 56.25 inches long. The distance from the end of the wires to the first count position was 4.25 inches for all wires counted from this cycle
Diamond Thermal Expansion Measurement Using Transmitted X-ray Back-diffraction.
Giles, Carlos; Adriano, Cris; Lubambo, Adriana Freire; Cusatis, Cesar; Mazzaro, Irineu; Hönnicke, Marcelo Goncalves
2015-01-01
The linear thermal expansion coefficient of diamond has been measured using forward-diffracted profiles in X-ray backscattering. This experimental technique is presented as an alternative way of measuring thermal expansion coefficients of solids in the high-resolution Bragg backscattering geometry without the intrinsic difficulty of detecting the reflected beam. The temperature dependence of the lattice parameter is obtained from the high sensitivity of the transmitted profiles to the Bragg a...
Ng, Maggie; Mok, Daniel K W; Lee, Edmond P F; Dyke, John M
2013-03-15
The minimum energy path (MEP) of the reaction, CF(3)CHFCF(3) + H → transition state (TS) → CF(3)CFCF(3) + H(2), has been computed at different ab initio levels and with density functional theory (DFT) using different functionals. The computed B3LYP/6-31++G**, BH&HLYP/cc-pVDZ, BMK/6-31++G**, M05/6-31+G**, M05-2X/6-31+G**, UMP2/6-31++G**, PUMP2/6-31++G**//UMP2/6-31++G**, RCCSD(T)/aug-cc-pVDZ//UMP2/6-31++G**, RCCSD(T)/aug-cc-pVTZ(spd,sp)//UMP2//6-31++G**, RCCSD(T)/CBS//M05/6-31+G**, and RCCSD(T)/CBS//UMP2/6-31++G** MEPs, and associated gradients and Hessians, were used in reaction rate coefficient calculations based on the transition state theory (TST). Reaction rate coefficients were computed between 300 and 1500 K at various levels of TST, which include conventional TST, canonical variational TST (CVT) and improved CVT (ICVT), and with different tunneling corrections, namely, Wigner, zero-curvature, and small-curvature (SCT). The computed rate coefficients obtained at different ab initio, DFT and TST levels are compared with experimental values available in the 1000-1200 K temperature range. Based on the rate coefficients computed at the ICVT/SCT level, the highest TST level used in this study, the BH&HLYP functional performs best among all the functionals used, while the RCCSD(T)/CBS//MP2/6-31++G** level is the best among all the ab initio levels used. Comparing computed reaction rate coefficients obtained at different levels of theory shows that, the computed barrier height has the strongest effect on the computed reaction rate coefficients as expected. Variational effects on the computed rate coefficients are found to be negligibly small. Although tunneling effects are relatively small at high temperatures (~1500 K), SCT corrections are significant at low temperatures (~300 K), and both barrier heights and the magnitudes of the imaginary frequencies affect SCT corrections. Copyright © 2012 Wiley Periodicals, Inc.
Calculating lattice thermal conductivity: a synopsis
Fugallo, Giorgia; Colombo, Luciano
2018-04-01
We provide a tutorial introduction to the modern theoretical and computational schemes available to calculate the lattice thermal conductivity in a crystalline dielectric material. While some important topics in thermal transport will not be covered (including thermal boundary resistance, electronic thermal conduction, and thermal rectification), we aim at: (i) framing the calculation of thermal conductivity within the general non-equilibrium thermodynamics theory of transport coefficients, (ii) presenting the microscopic theory of thermal conduction based on the phonon picture and the Boltzmann transport equation, and (iii) outlining the molecular dynamics schemes to calculate heat transport. A comparative and critical addressing of the merits and drawbacks of each approach will be discussed as well.
Development of thermal stress screening method. Application of green function method
International Nuclear Information System (INIS)
Furuhashi, Ichiro; Shibamoto, Hiroshi; Kasahara, Naoto
2004-01-01
This work was achieved for the development of the screening method of thermal transient stresses in FBR components. We proposed an approximation method for evaluations of thermal stress under variable heat transfer coefficients (non-linear problems) using the Green functions of thermal stresses with constant heat transfer coefficients (linear problems). Detailed thermal stress analyses provided Green functions for a skirt structure and a tube-sheet of Intermediate Heat Exchanger. The upper bound Green functions were obtained by the analyses using those upper bound heat transfer coefficients. The medium and the lower bound Green functions were got by the analyses of those under medium and the lower bound heat transfer coefficients. Conventional evaluations utilized the upper bound Green functions. On the other hand, we proposed a new evaluation method by using the upper bound, medium and the lower bound Green functions. The comparison of above results gave the results as follows. The conventional evaluations were conservative and appropriate for the cases under one fluid thermal transient structure such as the skirt. The conventional evaluations were generally conservative for the complicated structures under two or more fluids thermal transients such as the tube-sheet. But the danger locations could exists for the complicated structures under two or more fluids transients, namely the conventional evaluations were non-conservative. The proposed evaluations gave good estimations for these complicated structures. Though above results, we have made the basic documents of the screening method of thermal transient stresses using the conventional method and the new method. (author)
Determination of the reaction rate coefficient of sulphide mine tailings deposited under water.
Awoh, Akué Sylvette; Mbonimpa, Mamert; Bussière, Bruno
2013-10-15
The efficiency of a water cover to limit dissolved oxygen (DO) availability to underlying acid-generating mine tailings can be assessed by calculating the DO flux at the tailings-water interface. Fick's equations, which are generally used to calculate this flux, require knowing the effective DO diffusion coefficient (Dw) and the reaction (consumption) rate coefficient (Kr) of the tailings, or the DO concentration profile. Whereas Dw can be accurately estimated, few studies have measured the parameter Kr for submerged sulphide tailings. The objective of this study was to determine Kr for underwater sulphide tailings in a laboratory experiment. Samples of sulphide mine tailings (an approximately 6 cm layer) were placed in a cell under a water cover (approximately 2 cm) maintained at constant DO concentration. Two tailings were studied: TA1 with high sulphide content (83% pyrite) and TA2 with low sulphide content (2.8% pyrite). DO concentration was measured with a microelectrode at various depths above and below the tailings-water interface at 1 mm intervals. Results indicate that steady-state condition was rapidly attained. As expected, a diffusive boundary layer (DBL) was observed in all cases. An iterative back-calculation process using the numerical code POLLUTEv6 and taking the DBL into account provided the Kr values used to match calculated and experimental concentration profiles. Kr obtained for tailings TA1 and TA2 was about 80 d(-1) and 6.5 d(-1), respectively. For comparison purposes, Kr obtained from cell tests on tailings TA1 was lower than Kr calculated from the sulphate production rate obtained from shake-flask tests. Steady-state DO flux at the water-tailings interface was then calculated with POLLUTEv6 using tailings characteristics Dw and Kr. For the tested conditions, DO flux ranged from 608 to 758 mg O2/m(2)/d for tailings TA1 and from 177 to 221 mg O2/m(2)/d for tailings TA2. The impact of placing a protective layer of inert material over
Magneto-electronic, thermal, and thermoelectric properties of some Co-based quaternary alloys
Bhat, Tahir Mohiuddin; Gupta, Dinesh C.
2018-01-01
In this study, quaternary Heusler alloys CoFeCrZ (Z = Si, As, Sb) were investigated based on the modified Becke-Johnson exchange potential. The electronic structures demonstrated that CoFeCrZ (Z = Si, As, Sb) alloys are completely spin polarized with indirect bandgap and has an integer magnetic moment according to the Slater-Pauling rule. Pugh's and Poisson's ratios showed that these materials are highly ductile with high melting temperatures. The thermal properties comprising the thermal expansion coefficient, heat capacity, and Grüneisen parameter were evaluated at various pressures from 0 to 20 GPa. The Grüneisen parameter values indicated the strong anharmonicity of the lattice vibrations that predominated in these compounds. We also studied the dependency of the thermoelectric transport properties on the temperature, i.e., the thermal conductivity and Seebeck coefficient. These alloys exhibited low lattice thermal conductivity and good Seebeck coefficients at room temperature. The half-metallic structures of these compounds with large band gaps and adequate Seebeck coefficients mean that they are suitable for use in spintronic and thermoelectric device applications.
Thermal expansion of diamond at low temperatures.
Stoupin, Stanislav; Shvyd'ko, Yuri V
2010-02-26
Temperature variation of a lattice parameter of a synthetic diamond crystal (type IIa) was measured using high-energy-resolution x-ray Bragg diffraction in backscattering. A 2 order of magnitude improvement in the measurement accuracy allowed us to directly probe the linear thermal expansion coefficient at temperatures below 100 K. The lowest value measured was 2x10{-9} K-1. It was found that the coefficient deviates from the expected Debye law (T3) while no negative thermal expansion was observed. The anomalous behavior might be attributed to tunneling states due to low concentration impurities.
International Nuclear Information System (INIS)
De Vita, Armando; Maheshwari, Arpit; Destro, Matteo; Santarelli, Massimo; Carello, Massimiliana
2017-01-01
Highlights: •An experimental set-up is designed and developed for thermal characterization of a Li-ion battery. •Heat generation and internal resistance profile at various C-rates (1C, 2C, 5C and 8C) are studied. •Heat entropic coefficient and internal resistance determination with temperature dependence were performed. •A battery thermal model is developed and used in a CFD-3D software for cooling methods analysis. -- Abstract: This paper presents a computational modeling approach to characterize the internal temperature distribution within a Li-Ion battery pack. In the mathematical formulation both entropy-based and irreversible-based heat generation have been considered; combined with CFD software in order to simulate the temperature distribution and evolution in a battery pack. A prismatic Li-ion phosphate battery is tested under constant current discharge/charge rates of 1C, 2C, 5C and 8C. Model parameters (in particular, the entropic heat coefficient and the internal resistance) needed for the calibration of the model are determined using experimentation. The model is then used to simulate two different strategies for the thermal control of a battery pack in case of car application: an air-cooling and a liquid-cooling strategy. The simulation has highlighted the pros and cons of the two strategies, allowing a good understanding of the needs during the process of battery pack design and production.